Search results for " Magnetic materials"
showing 10 items of 4666 documents
Design and simulation of QCA-based 3-bit binary to gray and vice versa code converter in reversible and non-reversible mode
2022
The current Very Large-Scale Integration (VLSI) technology has reached its peak due to the fundamental physical limits of Complementary Metal-Oxide-Semiconductor (CMOS). Quantum-dot Cellular Automata (QCA) is considered a proper alternative to CMOS technology in digital circuit design. QCA has features like low power, small area, and high speed in nanoscale digital circuit design. A code converter is a circuit that converts a determined code to another one. Code converters such as Binary to Gray, Gray to Binary, and Binary to BCD converters have a crucial role in fast signal processing in digital systems. Also, code converters are used as a base unit for data transmission into the Arithmeti…
When the Grafting of Double Decker Phthalocyanines on Si(100)-2 × 1 Partly Affects the Molecular Electronic Structure
2016
International audience; A combined X-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM), and density functional theory (DFT) study has been performed to characterize the adsorbate interaction of lutetium biphthalocyanine (LuPc2) molecules on the Si(100)-2 × 1 surface. Large molecule–substrate adsorption energies are computed and are found to compete with the molecule–molecule interactions of the double decker molecules. A particularly good matching between STM images and computed ones confirms the deformation of the molecule upon the absorption process. The comparison between DFT calculations and XP spectra reveals that the electronic distribution in the two plateaus …
Single-molecule magnet properties of a monometallic dysprosium pentalene complex
2018
The pentalene-ligated dysprosium complex [(η8-Pn†)Dy(Cp*)] (1Dy) (Pn† = [1,4-(iPr3Si)2C8H4]2−) and its magnetically dilute analogue are single-molecule magnets, with energy barriers of 245 cm−1. Whilst the [Cp*]− ligand in 1Dy provides a strong axial crystal field, the overall axiality of this system is attenuated by the unusual folded structure of the [Pn†]2− ligand. peerReviewed
Chiral Magneto-Electrochemistry
2018
Magneto-electrochemistry (MEC) is a unique paradigm in science, where electrochemical experiments are carried out as a function of an applied magnetic field, creating a new horizon of potential scientific interest and technological applications. Over time, detailed understanding of this research domain was developed to identify and rationalize the possible effects exerted by a magnetic field on the various microscopic processes occurring in an electrochemical system. Notably, until a few years ago, the role of spin was not taken into account in the field of magneto-electrochemistry. Remarkably, recent experimental studies reveal that electron transmission through chiral molecules is spin se…
Modeling optical constants from the absorption of organic thin films using a modified Lorentz oscillator model
2022
Optical constants of organic thin films can be evaluated using the Lorentz oscillator model (LOM) which fails to fit inhomogeneously broadened absorption of highly concentrated molecular films. In modified LOM (MLOM), the inhomogeneous broadening is implemented through a frequency-dependent adjustable broadening function. In this work, we evaluate the optical constants of rhodamine 6G doped poly-vinyl alcohol thin films with varying doping concentration (including also extensively high concentrations) using MLOM, which outperforms LOM by showing a better agreement with the experimental results. Our proposed method provides a way to accurately determine optical constants of isotropic organic…
Molecular dynamics simulations of heavy ion induced defects in SiC Schottky diodes
2018
Heavy ion irradiation increases the leakage current in reverse-biased SiC Schottky diodes. This letter demonstrates, via molecular dynamics simulations, that a combination of bias and ion-deposited energy is required to produce the degradation. Peer reviewed
Rhombi-chain Bose-Hubbard model: Geometric frustration and interactions
2018
We explore the effects of geometric frustration within a one-dimensional Bose-Hubbard model using a chain of rhombi subject to a magnetic flux. The competition of tunnelling, self-interaction and magnetic flux gives rise to the emergence of a pair-superfluid (pair-Luttinger liquid) phase besides the more conventional Mott-insulator and superfluid (Luttinger liquid) phases. We compute the complete phase diagram of the model by identifying characteristic properties of the pair-Luttinger liquid phase such as pair correlation functions and structure factors and find that the pair-Luttinger liquid phase is very sensitive to changes away from perfect frustration (half-flux). We provide some propo…
Influence of Grain Size, Oxygen Stoichiometry, and Synthesis Conditions on the γ-Fe2O3 Vacancies Ordering and Lattice Parameters
2002
The soft chemistry method has been used to synthesize γ-Fe2O3 nanoparticles: various synthesis temperature were applied to obtain nanometric powders with crystallite size in the 9–14 nm range. Powders were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectrophotometry, surface area measurements, and electron microscopy (TEM, SEM). It is clearly shown that these nanometric powders are very well crystallized as indicated by XRD and IR spectra which present substructural bands attributed to vacancies ordering (P4132). Based on these model materials and in the crystallite size range studied here, cell parameter appears to be not linked to crystallite size. It rat…
Asymptotic modeling of electrochemical signaling: Testing Zn in urine for non-invasive bladder cancer diagnosis
2021
Abstract A theoretical model on chemical signaling for diagnosis based on the combination of signals for marker and inert and/or interfering metabolites is described. The model yields asymptotic relationships between the intensities of the signals representative of marker and accompanying metabolites compensating concentration fluctuations. The model fits well with voltammetric features associated to the oxidation of different urine metabolites and Zn(II) reduction in the same urine samples after alkaline digestion. As a result, a non-invasive electrochemical detection of urothelial carcinoma (bladder cancer, BC) is reported. Different diagnostic criteria are described all displaying high s…
NeXt for neuro-radiosurgery: A fully automatic approach for necrosis extraction in brain tumor MRI using an unsupervised machine learning technique
2017
Stereotactic neuro-radiosurgery is a well-established therapy for intracranial diseases, especially brain metastases and highly invasive cancers that are difficult to treat with conventional surgery or radiotherapy. Nowadays, magnetic resonance imaging (MRI) is the most used modality in radiation therapy for soft-tissue anatomical districts, allowing for an accurate gross tumor volume (GTV) segmentation. Investigating also necrotic material within the whole tumor has significant clinical value in treatment planning and cancer progression assessment. These pathological necrotic regions are generally characterized by hypoxia, which is implicated in several aspects of tumor development and gro…