Search results for " Movement"
showing 10 items of 1376 documents
Synthesis, structure and in vitro anticancer activity of Pd(II) complexes of mono- and bis-pyrazolyl-s-triazine ligands
2020
Abstract The square planar complexes [Pd(MPT)Cl2] (1) and [Pd(BPT)Cl]ClO4 (2) were synthesized by the reaction of the 4,4′-(6-(3,5-dimethyl-1H-pyrazol-1-yl)-1,3,5-triazine-2,4-diyl)dimorpholine (MPT) and N-methyl-N-phenyl-4,6-di(1H-pyrazol-1-yl)-1,3,5-triazin-2-amine (BPT) ligands with PdCl2 (1:1) in acetone under thermal conditions, respectively. In complex 1, the Pd(II) ion is coordinated with the MPT ligand as a bidentate NN-chelate, augmented with two chloride ligands in cis positions. In complex 2, the Pd(II) ion is coordinated with the BPT ligand as a tridentate N-chelate in a pincer fashion, together with one chloride ligand. Hirshfeld analysis indicated that complex 1 is packed with…
Synthesis and reactivity of an 2-azabutadiene-based π-conjugated dithioether: Formation of a N,S-ligated molybdenum chelate complex and C,N,S-pincer …
2005
Abstract Nucleophilic attack of sodium isopropylthiolate on 4,4-dichloro-1,1-diphenyl-2-azabuta-1,3-diene [Cl2C C(H)–N CPh2}] (1) affords the 2-azabutadiene derivative [(i-PrS)2C C(H)–N CPh2] (2). Upon irradiation of Mo(CO)6 in THF in the presence of 2, the chelate complex cis-[(OC)4Mo{(i-PrS)2C C(H)–N CPh2}] (3) is obtained. Coordination on Mo occurs through the imine nitrogen and a thioether group. Polydentate dithioether 2 acts as N,C,S-pincer ligand after orthometallation reaction with Pd(II) or Pt(II). The molecular structures of 2 and (C,N,S)-[(i-PrS)2C C(H)–N C(Ph)C6H4)PtCl] (4b) have been determined by X-ray diffraction studies.
Dermal dendritic cells, but not Langerhans cells, are critical in murine single epicutaneous sensitization
2014
A murine repeated protein-patch model has been established to study epicutaneous sensitization in atopic dermatitis. This model has shown a predominant Th2 and a weak Th1 response in both BALB/c and C57BL/6 mice. However, Th responses induced in the repeated model are not consistent with the generally accepted theory that BALB/c and C57BL/6 mice are Th2 and Th1 prone and are representatives of human atopy and non-atopy, respectively. In this study, a single protein-patch model was established, which showed in addition to the Th2 response, a remarkable Th1 response in C57BL/6 mice, but not in BALB/c mice. Moreover, using muLangerin-DTR mice, we demonstrated that dermal dendritic cells, but n…
Factores de rendimiento en el desplazamiento del tenista influenciados por el calzado.
2009
Los desplazamientos laterales son de gran importancia en el tenis. Sin embargo, no ha sido publicado ningún estudio sobre el efecto del calzado sobre el rendimiento en este tipo de movimientos. En el estudio participaron 5 jugadores habituales de tenis y se analizaron 10 calzados comerciales de tenis. El movimiento estudiado consistió en un desplazamiento lateral con parada y cambio de sentido, registrándose las fuerzas mediante una plataforma dinamométrica Dinascan-IBV y grabándose el movimiento con dos cámaras de vídeo S-VHS Panasonic WV-BL600. Los resultados de los ANOVAs realizados mostraron que algunas de las variables analizadas eran dependientes del calzado (p < 0.05). De éstas, dest…
Libertà di circolazione, divieto di discriminazioni fondate sulla nazionalità e norme sportive sulla cittadinanza
2018
This paper investigates the right of movement and residence of persons in the European Community and the prohibition of discrimination based on nationality, also in the framework of the relations between community law and sports law. In this perspective, after preliminary analysis of the european and domestic rules referred to the above mentioned right of movement, attention will be held to the important topic of Welfare tourism. The investigation proceeds with the examination of the “Sporting Exception” which allows that european rules on right of movement and prohibition of discrimination based on nationality yeld before the international and State’s sport technical rules.
Subjetivación y Feminismo: Análisis de un manifiesto político
2004
The theme of this article is the the Italian feminist movement of the 1980s. That movement was characterised by political transformation and a crtitique of identity. The article takes as its point of departure the inaugural speech of the movement, the manifesto "Piu donne che uomini" (1983). The analysis that we present is inspired in the work of Michel Foucault. It aims to show to that the production of new feministic subjectivities, when fighting the symbolic dimension of masculine domination, has an intrinsically political character. In the 1980s, in the Italian context and particularly in the feminist movement, the rules of the political game set up by the events of 1968 materialized. T…
Assonanze ritmiche tra movimento grafico e segno digitale
2015
L’accostamento di più lettere costruisce nuove parole, significanti e concetti. Quando a queste lettere si associa l’idea di suono si disegna la forma degli oggetti. Schopenhauer fondò la sua teoria dei colori sulla bipartizione dell’attività della retina, paragonandola alla scala musicale, in quanto i colori erano posti in un rapporto numerico razionale tra loro. Pierre Boulez, partendo dall’opera e dalle lezioni di Paul Klee al Bauhaus, sviluppa una riflessione sulla distribuzione e sul ritmo dello spazio musicale; infatti nella serie di incisioni o di quadri come Le città, la simmetria, più che un paesaggio urbano, evoca un rigo musicale con le linee disegnate dalle note distribuite sott…
Extensive migration of young neurons into the infant human frontal lobe
2016
Building the human brain As the brain develops, neurons migrate from zones of proliferation to their final locations, where they begin to build circuits. Paredes et al. have discovered that shortly after birth, a group of neurons that proliferates near the ventricles migrates in chains alongside circulatory vessels into the frontal lobes (see the Perspective by McKenzie and Fishell). Young neurons that migrate postnatally into the anterior cingulate cortex then develop features of inhibitory interneurons. The number of migratory cells decreases over the first 7 months of life, and by 2 years of age, migratory cells are not evident. Any damage during migration, such as hypoxia, may affect th…
Peroxisome proliferator-activated receptor γ ligands regulate neural stem cell proliferation and differentiation in vitro and in vivo.
2011
Peroxisome proliferator-activated receptor gamma (PPARγ) belongs to a family of ligand-activated nuclear receptors and its ligands are known to control many physiological and pathological situations. Its role in the central nervous system has been under intense analysis during the last years. Here we show a novel function for PPARγ in controlling stem cell expansion in the adult mammalian brain. Adult rats treated with pioglitazone, a specific ligand of PPARγ, had elevated numbers of proliferating progenitor cells in the subventricular zone and the rostral migratory stream. Electron microscopy analysis also showed important changes in the subventricular zone ultrastructure of pioglitazone-t…
Subventricular Zone-Derived Neuroblasts Migrate and Differentiate into Mature Neurons in the Post-Stroke Adult Striatum
2006
Recent studies have revealed that the adult mammalian brain has the capacity to regenerate some neurons after various insults. However, the precise mechanism of insult-induced neurogenesis has not been demonstrated. In the normal brain, GFAP-expressing cells in the subventricular zone (SVZ) of the lateral ventricles include a neurogenic cell population that gives rise to olfactory bulb neurons only. Herein, we report evidence that, after a stroke, these cells are capable of producing new neurons outside the olfactory bulbs. SVZ GFAP-expressing cells labeled by a cell-type-specific viral infection method were found to generate neuroblasts that migrated toward the injured striatum after middl…