Search results for " Phase"
showing 10 items of 1862 documents
Extraction of polycyclic aromatic hydrocarbons from cookies: a comparative study of ultrasound and microwave-assisted procedures.
2008
The chromatographic determination of 15 polycyclic aromatic hydrocarbons (PAHs) in cookies has been improved in order to obtain a fast method with a low limit of detection through the combination of microwave-assisted extraction (MAE), oil saponification and solid-phase extraction clean-up before the injection of purified extracts in a C18 201TP52 (5 microm, 250 x 2.1 mm) column. Using acetonitrile-water as mobile phase, with a 50% to 95% w/w acetonitrile gradient for a fixed flow of 0.250 ml min(-1), 15 PAHs were separated in 45 min. The column temperature was maintained at 15 degrees C; and fluorimetric detection was made at a fixed excitation wavelength of 264 nm and emission measurement…
DNA adduct levels associated with p53 induction and delay of MCF-7 cells in S phase after exposure to benzo[g]chrysene dihydrodiol epoxide enantiomer…
1998
Optically active isomers of a mammary carcinogen, anti-benzo[g]chrysene 11, 12-dihydrodiol 13, 14-epoxide, react to different extents with DNA and generate DNA adducts that differ in their stereochemistry. In the study reported here, the effect of these two enantiomers on the progress of human breast carcinoma MCF-7 cells through the cell cycle was investigated. Each enantiomer caused the cells to accumulate in the S phase, but a higher dose of the benzo[g]chrysene 11S, 12R-dihydrodiol 13R, 14S-epoxide than of its enantiomer was required to induce this effect. Similarly, induction of p53 also required a higher dose of benzo[g]chrysene 11S, 12R-dihydrodiol 13R, 14S-epoxide. Postlabeling stud…
Instantaneous frequency measurement of dissipative soliton resonant light pulses
2016
Fil: Cuadrado-Laborde, Christian. Universidad de Valencia. Departamento de Física Aplicada y Electromagnetismo. Instituto Universitario de Ciencia de los Materiales; España Fil: Cuadrado-Laborde, Christian. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Física Rosario; Argentina Fil: Cuadrado-Laborde, Christian. Pontificia Universidad Católica Argentina. Facultad de Química e Ingeniería del Rosario; Argentina Fil: Armas Rivera, I. Benemérita Universidad Autónoma de Puebla. Facultad de Ciencias Físico Matemáticas; Mexico Fil: Carrascosa, A. Universidad de Valencia. Departamento de Física Aplicada y Electromagnetismo. Instituto Universitario de Ciencia de los Materia…
Genotoxicity of citrus wastewater in prokaryotic and eukaryotic cells and efficiency of heterogeneous photocatalysis by TiO(2).
2012
Abstract The presence of (±)α-pinene, (+)β-pinene, (+)3-carene, and R-(+)limonene terpenes in wastewater of a citrus transformation factory was detected and analyzed, in a previous study, by using Solid Phase Micro-extraction (SPME) followed by GC analyses. Purpose of that research was to compare the genotoxic responses of mixtures of terpenes with the genotoxicity of the individual compounds, and the biological effects of actual wastewater. Genotoxicity was evaluated in the Salmonella reversion assay (Ames test) and in V79 cells by Comet assay. Ames tests indicated that the four single terpenes did not induce an increase of revertants frequency. On the contrary, the mixtures of terpenes ca…
Positive solutions for singular double phase problems
2021
Abstract We study the existence of positive solutions for a class of double phase Dirichlet equations which have the combined effects of a singular term and of a parametric superlinear term. The differential operator of the equation is the sum of a p-Laplacian and of a weighted q-Laplacian ( q p ) with discontinuous weight. Using the Nehari method, we show that for all small values of the parameter λ > 0 , the equation has at least two positive solutions.
A Multiplicity result for a class of strongly indefinite asymptotically linear second order systems
2010
We prove a multiplicity result for a class of strongly indefinite nonlinear second order asymptotically linear systems with Dirichlet boundary conditions. The key idea for the proof is to bring together the classical shooting method and the Maslov index of the linear Hamiltonian systems associated to the asymptotic limits of the given nonlinearity.
Cloud point–dispersive μ-solid phase extraction of hydrophobic organic compounds onto highly hydrophobic core–shell Fe 2 O 3 @C magnetic nanoparticles
2012
Abstract A novel two-step extraction technique combining cloud point extraction (CPE) with dispersive micro-solid phase extraction (D-μ-SPE) is presented in this work for the first time. The method involves initial extraction of the target analytes by CPE in the micelles of a non-ionic surfactant medium; then highly hydrophobic polysiloxane-coated core–shell Fe 2 O 3 @C magnetic nanoparticles (MNPs) are used to retrieve the micellar phase. In that manner, the micellar phase containing the analytes is the target of the D-μ-SPE step rather than the analytes directly. MNPs are then collected by the application of an adscititious magnetic field overcoming the need for specific steps associated …
A Generalised RBF Finite Difference Approach to Solve Nonlinear Heat Conduction Problems on Unstructured Datasets
2011
Radial Basis Functions have traditionally been used to provide a continuous interpolation of scattered data sets. However, this interpolation also allows for the reconstruction of partial derivatives throughout the solution field, which can then be used to drive the solution of a partial differential equation. Since the interpolation takes place on a scattered dataset with no local connectivity, the solution is essentially meshless. RBF-based methods have been successfully used to solve a wide variety of PDEs in this fashion. Such full-domain RBF methods are highly flexible and can exhibit spectral convergence rates Madych & Nelson (1990). However, in their traditional implementation the fu…
Span programs for functions with constant-sized 1-certificates
2012
Besides the Hidden Subgroup Problem, the second large class of quantum speed-ups is for functions with constant-sized 1-certificates. This includes the OR function, solvable by the Grover algorithm, the element distinctness, the triangle and other problems. The usual way to solve them is by quantum walk on the Johnson graph. We propose a solution for the same problems using span programs. The span program is a computational model equivalent to the quantum query algorithm in its strength, and yet very different in its outfit. We prove the power of our approach by designing a quantum algorithm for the triangle problem with query complexity O(n35/27) that is better than O(n13/10) of the best p…
Enlarging the gap between quantum and classical query complexity of multifunctions
2013
Quantum computing aims to use quantum mechanical effects for the efficient performance of computational tasks. A popular research direction is enlarging the gap between classical and quantum algorithm complexity of the same computational problem. We present new results in quantum query algorithm design for multivalued functions that allow to achieve a large quantum versus classical complexity separation. To compute a basic finite multifunction in a quantum model only one query is enough while classically three queries are required. Then, we present two generalizations and a modification of the original algorithm, and obtain the following complexity gaps: Q UD (M′) ≤ N versus C UD (M′) ≥ 3N,…