Search results for " Small"
showing 10 items of 806 documents
A new method for data evaluation of small angle neutron scattering experiments and its application to amorphous polycarbonate
1981
The conformation of single chains in bulk polymer materials can be evaluated from coherent neutron scattering on mixtures of normal and deuterated polymers. It is shown that the single-chain structure factor can be also obtained from measurements of highly concentrated mixtures and the procedure of evaluation is described. The application to amorphous polycarbonate demonstrates the advantages of the method.
A synchrotron radiation X-ray scattering study of aqueous solutions of native DNA
1999
Synchrotron radiation small-angle X-ray scattering (SAXS) was used to investigate solutions of native DNA at different ionic strengths and temperatures. The mass per unit length, radius of gyration of the cross-section of DNA and apparent second virial coefficient (A2) were obtained from Zimm plots in the rodlike particle approximation. The values of A2 obtained in this way are positive and almost constant indicating that the repulsive interactions still influence the scattering patterns at resolutions as high as 5-8 nm. SAXS measurements in continuous temperature scans indicate that the rod approximation is valid over a wide temperature range during DNA melting and confirm that the rodlike…
Advances in contrast variation for macromolecular structure determination by polarized neutron scattering and anomalous dispersion of synchrotron X-r…
1988
Contrast variation for macromolecular structure determination is usually achieved by isomorphous replacement of 1-H by 2-H (D) using small-angle neutron scattering (SANS). This is particularly easy in aqueous solvents. By adding heavy water the contrast of dissolved proteins, nucleic acids and membranes changes drastically. It is the region inaccesible to solvent molecules, which acts as a label. Measurements of the scattering intensity at three different scattering densities of a solvent yields the three basic scattering functions. The contrast dependence of the radius of gyration receives particular interest. More recently smaller labels have been used. Their dimensions are smaller than t…
Light transport in hetero-opal photonic crystals
2005
The effect of photonic bandgap interface upon the light scattering was studied in hetero-opals consisting of two opal thin films with different lattice constant. It is shown that the weak scattering regime is preserved in thin hetero-opal films. By comparing scattering spectra of single and hetero-opal films recorded under reversing angles of light incidence and detection it was demonstrated that the interface scatters stronger the light at oblique incident angles. Squeezing of the scattering diagram of hetero-opals compared to single opal films is also assigned to the interface scattering.
Renormalization of the effective theory for heavy quarks at small velocity
1995
The slope of the Isgur-Wise function at the normalization point, $\xi^{(1)}(1)$,is one of the basic parameters for the extraction of the $CKM$ matrix element $V_{cb}$ from exclusive semileptonic decay data. A method for measuring this parameter on the lattice is the effective theory for heavy quarks at small velocity $v$. This theory is a variant of the heavy quark effective theory in which the motion of the quark is treated as a perturbation. In this work we study the lattice renormalization of the slow heavy quark effective theory. We show that the renormalization of $\xi^{(1)}(1)$ is not affected by ultraviolet power divergences, implying no need of difficult non-perturbative subtraction…
Second-order Raman scattering in CuO
2013
Polarized second-order Raman scattering spectra of CuO single crystals are reported. It is shown that for some scattering geometries the second-order processes dominate the inelastic light scattering spectra. Group-theoretical symmetry analysis of the selection rules for the first- and second-order scattering processes is performed and phonon dispersion relations are calculated within density functional theory. The main spectral features of the two-phonon spectra are assigned to overtones of the vibrational branches at various special points across the Brillouin zone.
Experimental studies of the liquid-glass transition in trimethylheptane
2000
The molecular glass former trimethylheptane was studied by calorimetric, dielectric, ultrasonic, neutron scattering, Brillouin scattering, and depolarized light-scattering techniques. The molecular structure appears to be nearly spherical optically as indicated by the low depolarization ratio and dielectric susceptibility values. A preliminary mode-coupling theory (MCT) analysis of the light-scattering and neutron-scattering data indicates that ${T}_{C}\ensuremath{\gtrsim}150 \mathrm{K},$ at least 25 K above ${T}_{G}.$ The susceptibility minima were analyzed with the MCT interpolation equation, and disagreement between the light and neutron results was observed despite the apparent isotropy…
Studies of structure and dynamics of solid polymers by elastic and inelastic neutron scattering
1978
Abstract Neutron scattering methods can be applied to solid polymers in order to investigate the structure of the bulk material as well as the nature of the molecular motion. A review of some recently performed studies is presented. Diffusional motion in crystals of chain molecules has been studied by means of quasielastic scattering for the case of n-C33H68 as an example for the relationship between structure and molecular motion. It can be shown that below the so-called rotational transition the paraffin crystals exhibit two types of molecular motion: a translational jump (τt = 0.5 10-8s) and a 180°-rotational jump (τr = 2.5 10-8s). The low frequency vibrations in n-alkanes as models of p…
Residential Exposure to Outdoor Air Pollution during Pregnancy and Anthropometric Measures at Birth in a Multicenter Cohort in Spain
2011
Background: A growing body of research suggests that prenatal exposure to air pollution may be harmful to fetal development. We assessed the association between exposure to air pollution during pregnancy and anthropometric measures at birth in four areas within the Spanish Children’s Health and Environment (INMA) mother and child cohort study. Methods: Exposure to ambient nitrogen dioxide (NO2) and benzene was estimated for the residence of each woman (n = 2,337) for each trimester and for the entire pregnancy. Outcomes included birth weight, length, and head circumference. The association between residential outdoor air pollution exposure and birth outcomes was assessed with linear regress…
Pseudouridine: Still mysterious, but never a fake (uridine)!
2014
International audience; Pseudouridine () is the most abundant of >150 nucleoside modifications in RNA. Although was discovered as the first modified nucleoside more than half a century ago, neither the enzymatic mechanism of its formation, nor the function of this modification are fully elucidated. We present the consistent picture of synthases, their substrates and their substrate positions in model organisms of all domains of life as it has emerged to date and point out the challenges that remain concerning higher eukaryotes and the elucidation of the enzymatic mechanism.