Search results for " chimie"
showing 10 items of 50 documents
Tuning the Pseudospin Polarization of Graphene by a Pseudomagnetic Field.
2016
One of the intriguing characteristics of honeycomb lattices is the appearance of a pseudo-magnetic field as a result of mechanical deformation. In the case of graphene, the Landau quantization resulting from this pseudo-magnetic field has been measured using scanning tunneling microscopy. Here we show that a signature of the pseudo-magnetic field is a local sublattice symmetry breaking observable as a redistribution of the local density of states. This can be interpreted as a polarization of graphene's pseudospin due to a strain induced pseudo-magnetic field, in analogy to the alignment of a real spin in a magnetic field. We reveal this sublattice symmetry breaking by tunably straining grap…
Importance des récentes variations pluviométriques à Djibouti et besoins de quantification de leurs impacts
2014
Ces dernières décennies, l’Afrique de l’Est souffre d’une longue et lente détérioration pluviométrique. De 2007 à 2011, la ville de Djibouti a enregistré un déficit de 73% des précipitations moyennes annuelles par rapport à la moyenne de 30 ans (1981-2010). Pour caractériser la sécheresse actuelle, nous analysons une série pluviométrique reconstruite pour Djibouti-Ville de 1901 à 2013, les données de terrain permettant d’illustrer les impacts de ces variations pluviométriques. Les précipitations enregistrées à Djibouti ne présentent aucune tendance sur le long terme (1901-2013). Par contre, ces dernières années montrent une très grande variabilité: le suivi de la moyenne pluviométrique sur …
Evaluation agroécologique de systèmes de culture en zone tropicale humide : Cas de la mise en valeur agricole d'une savane herbacée acide (Plaine des…
2013
Dans les régions tropicales humides, concilier intensification agricole et protection des ressources naturelles est un défi majeur et difficile à relever. Dans les savanes acides du nord-est laotien, des systèmes de culture de semis direct sur couverture végétale (SCV), basés sur les trois principes du non-labour, d’une couverture permanente du sol, et sur la pratique de rotations culturales diversifiées, sont proposés comme alternative technique à l’intensification agricole conventionnelle basée sur le labour. Si ces systèmes ont connu une diffusion importante et rapide dans les grandes agricultures mécanisées, leur diffusion reste néanmoins à ce jour limitée en contexte de petite agricult…
Typology of exogenous organic matters based on chemical and biochemical composition to predict potential nitrogen mineralization
2010
Our aim was to develop a typology predicting potential N availability of exogenous organic matters (EOMs) in soil based on their chemical characteristics. A database of 273 EOMs was constructed including analytical data of biochemical fractionation, organic C and N, and results of N mineralization during incubation of soil–EOM mixtures in controlled conditions. Multiple factor analysis and hierarchical classification were performed to gather EOMs with similar composition and N mineralization behavior. A typology was then defined using composition criteria to predict potential N mineralization. Six classes of EOM potential N mineralization in soil were defined, from high potential N minerali…
Contribution à la caractérisation objective de l'arôme de vins de champagne par des méthodes sensorielles et physico-chimiques
1997
*INRA Laboratoire de recherches sur les arômes BP 86510 21065 Dijon cedex (FRA) Diffusion du document : INRA Laboratoire de recherches sur les arômes BP 86510 21065 Dijon cedex (FRA) Diplôme : Dr. d'Université
Excitons in few-layer hexagonal boron nitride: Davydov splitting and surface localization
2018
Hexagonal boron nitride (hBN) has been attracting great attention because of its strong excitonic effects. Taking into account few-layer systems, we investigate theoretically the effects of the number of layers on quasiparticle energies, absorption spectra, and excitonic states, placing particular focus on the Davydov splitting of the lowest bound excitons. We describe how the inter-layer interaction as well as the variation in electronic screening as a function of layer number $N$ affects the electronic and optical properties. Using both \textit{ab initio} simulations and a tight-binding model for an effective Hamiltonian describing the excitons, we characterize in detail the symmetry of t…
Time-dependent screening explains the ultrafast excitonic signal rise in 2D semiconductors
2020
We calculate the time evolution of the transient reflection signal in an MoS$_2$ monolayer on a SiO$_2$/Si substrate using first-principles out-of-equilibrium real-time methods. Our simulations provide a simple and intuitive physical picture for the delayed, yet ultrafast, evolution of the signal whose rise time depends on the excess energy of the pump laser: at laser energies above the A- and B-exciton, the pump pulse excites electrons and holes far away from the K valleys in the first Brillouin zone. Electron-phonon and hole-phonon scattering lead to a gradual relaxation of the carriers towards small $\textit{Active Excitonic Regions}$ around K, enhancing the dielectric screening. The acc…
Dynamic tuning of the director field in liquid crystal shells using block copolymers
2020
When an orientationally ordered system, like a nematic liquid crystal (LC), is confined on a self-closing spherical shell, topological constraints arise with intriguing consequences that depend critically on how the LC is aligned in the shell. We demonstrate reversible dynamic tuning of the alignment, and thereby the topology, of nematic LC shells stabilized by the nonionic amphiphilic block copolymer Pluronic F127. Deep in the nematic phase, the director (the average molecule orientation) is tangential to the interface, but upon approaching the temperature TNI of the nematic– isotropic transition, the director realigns to normal. We link this to a delicate interplay between an interfacial …
Controllable morphology of flux avalanches in microstructured superconductors
2014
The morphology of abrupt bursts of magnetic flux into superconducting films with engineered periodic pinning centers (antidots) has been investigated. Guided flux avalanches of thermomagnetic origin develop a tree-like structure, with the main trunk perpendicular to the borders of the sample, while secondary branches follow well-defi ned directions determined by the geometrical details of the underlying periodic pinning landscape. Strikingly, we demonstrate that in a superconductor with relatively weak random pinning, the morphology of such flux avalanches can be fully controlled by proper combinations of lattice symmetry and antidot geometry. Moreover, the resulting flux patterns can be re…
Acoustic wave guides as infinite-dimensional dynamical systems
2015
We prove the unique solvability, passivity/conservativity and some regularity results of two mathematical models for acoustic wave propagation in curved, variable diameter tubular structures of finite length. The first of the models is the generalised Webster's model that includes dissipation and curvature of the 1D waveguide. The second model is the scattering passive, boundary controlled wave equation on 3D waveguides. The two models are treated in an unified fashion so that the results on the wave equation reduce to the corresponding results of approximating Webster's model at the limit of vanishing waveguide intersection.