Search results for " concentration"

showing 10 items of 1684 documents

Scientific approach for ozone absorption in blood during systemic indirect endovenous ozonetherapy

2018

Introduction.
 Reading reference ozone books from Dra. Menendez, Dra. Viebhan, Dra. Borrelli and Dr. Bocci, proper timing for mixing ozone in blood during autohemotherapy is not calculated in a scientific way, having only an estimation of it based on changes in the blood color, more related to oxygen absorption than on ozone itself.
 
 Material and methods.
 We decided to reproduce a reduced model of great autohemotherapy or recently renamed as systemic indirect endovenous ozonotherapy (SIEVO) by the World Federation of Ozone Therapy – WFOT, using syringes to simplify the experiment. Our model consisted of a 20 mL syringe filled with 10 mL of blood withdrawn from healthy…

ChromatographyOzoneOzone concentrationOzone therapy:CIENCIAS MÉDICAS [UNESCO]Reduced modelAutohemotherapychemistry.chemical_compoundchemistryUNESCO::CIENCIAS MÉDICASHealthy volunteersOxygen absorptionEnvironmental scienceAbsorption (electromagnetic radiation)
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Spectrophotometric Determination of Hydralazine with 2-Hydroxy-1-naphthaldehyde in Pharmaceuticals

1991

Abstract A new extraction-spectrophotometric method for the determination of hydralazine, based on its reaction with 2-hydroxy-1-naphthaldehyde at 25 °C, is described. The calibration curve was linear between 0.4 and 6 mg/mL of hydralazine. The molar absorbtivity of the product at 408 nm is 40 900 L · mol − 1 · cm − 1 . The method described was applied to the analysis of hydralazine in pharmaceutical preparations containing reserpine, hydrochlorothiazide, bendrofluorthiazine, propranolol, and other substances. The agreement with the U.S.P. XXI method was satisfactory for tablets and injections, but not for pellets.

ChromatographySpectrophotometry Infraredmedicine.diagnostic_testChemistryCalibration curveTemperaturePharmaceutical SciencePropranololHydrogen-Ion ConcentrationNaphthalenesReserpineHydralazineHydralazineDosage formHydrochlorothiazideSpectrophotometrySolventsmedicineIndicators and ReagentsSpectrophotometry Ultravioletmedicine.drugJournal of Pharmaceutical Sciences
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Electron paramagnetic resonance (EPR) spin trapping of biological nitric oxide

2007

Nitric oxide (NO) is a free radical species with multiple physiological functions. Because of low concentrations and short half-life of NO, its direct measurement in living tissues remains a difficult task. Electron paramagnetic resonance (EPR) spin trapping is probably one of the best suitable platforms for development of new methods for quantification of biological NO. The most reliable EPR-based approaches developed so far are based on the reaction of NO with various iron complexes, both intrinsic and exogenously applied. This review is focused on the current state and perspectives of EPR spin trapping for experimental and clinical NO biology.

ChromatographySpin trappingIronClinical BiochemistryElectron Spin Resonance SpectroscopyCell BiologyGeneral MedicineNitric OxidePhotochemistryBiochemistryAnalytical ChemistryNitric oxidelaw.inventionchemistry.chemical_compoundEpr spin trappingNuclear magnetic resonancechemistryThiocarbamateslawAnimalsHumansElectron paramagnetic resonanceSpin TrappingVolume concentrationJournal of Chromatography B
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Staining mitochondria in Saccharomyces cerevisiae.

1969

After testing various procedures (amidoblack 10B, acid fuchsin-methyl blue, Luxol fast blue MBS-phloxine, toluidine blue O, Jams green B and pinacyanol), three stains can be recommended for staining both types of mitochondria (globose and threadlike) in the cells of Saccharomyces cerevisiae: (1) 0.1% solution of amidoblack 10B in citrate buffer (pH 3.0) for 10 min; (2) 0.01% solution of toluidine blue O in phosphate buffer (pH 6.0) for 30 min; (3) 0.01% solution of Janus green B in distilled water (pH 5.6) for 30 min. The latter stain is most specific because its staining reaction depends upon the action of the mitochondrial enzyme cytochrome c oxidase. Yet, low concentrations and short inc…

ChromatographyTime FactorsStaining and LabelingJanus Green BSaccharomyces cerevisiaeBiologyBuffersHydrogen-Ion Concentrationbiology.organism_classificationStainLuxol fast blue stainStainingMitochondriaElectron Transport Complex IVchemistry.chemical_compoundSaccharomyceschemistryBiochemistryDistilled waterbiology.proteinMethodsCytochrome c oxidaseAnatomyColoring AgentsIncubationStain technology
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Chemical reduction of the mycotoxin beauvericin using allyl isothiocyanate.

2011

Abstract Beauvericin (BEA) is a bioactive compound produced by the secondary metabolism of several Fusarium strains and known to have various biological activities. This study investigated the reduction of BEA present in the concentration of 25 mg/kg on a solution model (phosphate buffer saline at pH 4 and 7) and in wheat flour using allyl isothiocyanate (AITC) as a reactant. The concentration of the mycotoxin studied was evaluated using liquid chromatography coupled to the diode array detector (LC-DAD), whereas adducts formed between the BEA and AITC were examined by liquid chromatography coupled to mass spectrometry-linear ion trap (LC-MS-LIT). In solution, BEA reduction ranged from 20% t…

ChromatographyWheat flourfood and beveragesGeneral MedicineHydrogen-Ion ConcentrationToxicologyAllyl isothiocyanateBeauvericinBioactive compoundMass SpectrometryAdductchemistry.chemical_compoundchemistryChromatography detectorIsothiocyanatesDepsipeptidesIon trapMycotoxinChromatography High Pressure LiquidFood ScienceFood and chemical toxicology : an international journal published for the British Industrial Biological Research Association
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High Submicellar Liquid Chromatography

2013

Surfactant addition above the critical micellar concentration (CMC), in reversed-phase liquid chromatography (RPLC), was proposed as a way to modify the selectivity and analysis time, giving rise to a chromatographic mode called micellar liquid chromatography (MLC). However, solutions containing only surfactant are too weak and yield poor peak shape. This was remediated by the addition of a small amount of organic solvent. To preserve the existence of micelles, in MLC high contents of organic solvent are avoided. Nevertheless, there is no reason to neglect the potentiality of mobile phases containing a surfactant above its CMC in water and a high organic solvent content (without micelles). …

Chromatographycolumn interactionsElutionChemistryHydrophilic interaction chromatographyAnalytical chemistryFiltration and Separationmacromolecular substancesReversed-phase chromatographyMicelleAnalytical Chemistryreversed-phase liquid chromatographyCountercurrent chromatographyPulmonary surfactantMicellar liquid chromatographyCritical micelle concentrationchromatographic performancesubmicellar liquid chromatographySeparation & Purification Reviews
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The chemistry of Cr(VI) adsorption on to poly(p-phenylenediamine) adsorbent

2019

Abstract Water pollution due to industrial processes has necessitated and spurred robust research into the development of adsorbent materials for remediation. Polyphenylenediamines (PPD) have attracted significant attention because of their dual cationic and redox properties. They are able to reduce Cr(VI) to Cr(III) in solution. Interrogation of the chemical processes involved in the Cr(VI) adsorption on para-PPD was primarily by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR) spectroscopy. It was confirmed that the underlying oxidation of the amino groups to imines during the reduction of Cr(VI) to Cr(III) was irreversible. This process occurred at both acidi…

ChromiumEnvironmental Engineering02 engineering and technologyPhenylenediamines010402 general chemistry01 natural sciencesRedoxWater PurificationAdsorptionX-ray photoelectron spectroscopySpectroscopy Fourier Transform InfraredChelationSpectroscopyWater Science and Technologychemistry.chemical_classificationAqueous solutionCationic polymerizationPolymerHydrogen-Ion Concentration021001 nanoscience & nanotechnology0104 chemical scienceschemistryAdsorption0210 nano-technologyWater Pollutants ChemicalNuclear chemistryWater Science and Technology
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Effects of temperature on the acute toxicity of heavy metals (Cr, Cd, and Hg) to the freshwater crayfish, Procambarus clarkii (Girard).

1987

Chromium, an essential trace element for humans and animals is involved in normal carbohydrate metabolism; however, it is toxic at high concentrations. There is no evidence that cadmium and mercury are biologically essential but their toxicity for organisms is well known. Both cause toxic effects at low concentrations to most organisms, especially in combination with other environmental variables such as temperature. Lake Albufera and the surrounding rice field waters are subjected to very heavy loads of sewage and toxic industrial residues (including heavy metals) from the many urban and waste waters in this area. In 1978, the American red crayfish Procambarus clarkii appeared in lake Albu…

ChromiumHealth Toxicology and Mutagenesischemistry.chemical_elementAstacoideaToxicologyLethal Dose 50EcotoxicologyAnimalsWater PollutantsWater pollutionProcambarus clarkiiCadmiumbiologyTemperatureGeneral MedicineMercuryHydrogen-Ion Concentrationbiology.organism_classificationCrayfishPollutionAcute toxicityMercury (element)OxygenchemistryMetalsEnvironmental chemistryChromium toxicityWater Pollutants ChemicalCadmiumBulletin of environmental contamination and toxicology
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Atropine-resistant effects of the muscarinic agonists McN-A-343 and AHR 602 on cardiac performance and the release of noradrenaline from sympathetic …

1974

Abstract 1 The effects of 4-(m-chlorophenylcarbamoyloxy)-2-butynyltrimethylammonium chloride (McN-A-343) and N-benzyl-3-pyrrolidyl acetate methobromide (AHR 602) on cardiac performance and noradrenaline release from terminal sympathetic fibres were measured in isolated perfused hearts of rabbits. 2 In the presence of sufficient atropine to block muscarinic receptors, high concentrations of McN-A-343 and AHR 602 caused no cardiac stimulation and there was no increase in the resting output of noradrenaline into the perfusates. 3 McN-A-343 and AHR 602 increased both the mechanical responses and the transmitter overflow evoked by electrical stimulation of the sympathetic nerves (SNS) but inhibi…

ChronotropicAtropineMalemedicine.medical_specialtyPyrrolidinesSympathetic Nervous SystemStimulationAutopharmacologyHexamethonium CompoundsPharmacologyIn Vitro TechniquesPiperazinesHexamethonium compoundchemistry.chemical_compoundNorepinephrineCocaineInternal medicineDesipramineMuscarinic acetylcholine receptorBenzyl CompoundsmedicineAnimalsPharmacologyNeuronsHeartHydrogen-Ion ConcentrationAcetylcholineElectric StimulationPerfusionQuaternary Ammonium CompoundsAtropineEndocrinologychemistryParasympathomimeticsHexamethoniumFemaleCarbamatesRabbitsDimethylphenylpiperazinium IodideAcetylcholinemedicine.drug
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Enantiomeric separation of chiral phenoxy acid herbicides by electrokinetic chromatography. Application to the determination of analyte-selector appa…

2001

The enantiomeric resolution of chiral phenoxy acid herbicides was performed by electrokinetic chromatography using a cyclodextrin as chiral pseudophase (CD-EKC). A systematic evaluation of several neutral and charged cyclodextrins was made. Among the cyclodextrins tested, (2-hydroxy)propyl beta-cyclodextrin (HP-beta-CD) was found to be the most appropriate for the enantioseparation of phenoxy acids. The influence of some experimental conditions, such as nature and pH of the background electrolyte, chiral selector concentration, and temperature, on the enantiomeric separation of phenoxy acids was also studied. The use of a 50 mM electrolyte solution in ammonium formate at pH 5 and a temperat…

CienciaAnalyteElectrokinetic chromatographyResolution (mass spectrometry)ScienceChemistry analytic and technicalClinical BiochemistryElectrolytePhenoxy acid herbicidesBiochemistryAnalytical ChemistryElectrolyteschemistry.chemical_compoundElectrokinetic phenomenaTwo temperatureCIENCIAAmmonium formateOrganic chemistrychemistry.chemical_classificationChromatographyCyclodextrinsChromatographyCyclodextrinHerbicidesChemistryPhenyl Ethersbeta-CyclodextrinsTemperatureStereoisomerismQuímica analítica e industrialSCIENCEHydrogen-Ion Concentration2-Hydroxypropyl-beta-cyclodextrinSolutionsPropionatesEnantiomerELECTROPHORESIS
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