Search results for " hysteresis"
showing 10 items of 98 documents
Single-molecule magnetic behavior in a neutral terbium(III) complex of a picolinate-based nitronyl nitroxide free radical
2011
The terdentate anionic picolinate-based nitronyl nitroxide (picNN) free radical forms neutral and robust homoleptic complexes with rare earth-metal ions. The nonacoordinated Tb3+ complex Tb(picNN)3• 6H2O is a single-molecule magnet with an activation energy barrier Δ = 22.8 ± 0.5 K and preexponential factor τ0 = (5.5 ± 1.1) × 10-9 s. It shows magnetic hysteresis below 1 K. © 2011 American Chemical Society.
Elastic torsion effects in magnetic nanoparticle diblock-copolymer structures
2011
Magnetic properties of thin composite films, consisting of non-interacting polystyrene-coated γ-Fe(2)O(3) (maghemite) nanoparticles embedded into polystyrene-block-polyisoprene P(S-b-I) diblock-copolymer films are investigated. Different particle concentrations, ranging from 0.7 to 43 wt%, have been used. The magnetization measured as a function of external field and temperature shows typical features of anisotropic superparamagnets including a hysteresis at low temperatures and blocking phenomena. However, the data cannot be reconciled with the unmodified Stoner-Wohlfarth-Néel theory. Applying an appropriate generalization we find evidence for either an elastic torque being exerted on the …
Complex Dynamics in a Harmonically Excited Lennard-Jones Oscillator: Microcantilever-Sample Interaction in Scanning Probe Microscopes1
1998
In this paper we model the microcantilever-sample interaction in an atomic force microscope (AFM) via a Lennard-Jones potential and consider the dynamical behavior of a harmonically forced system. Using nonlinear analysis techniques on attracting limit sets, we numerically verify the presence of chaotic invariant sets. The chaotic behavior appears to be generated via a cascade of period doubling, whose occurrence has been studied as a function of the system parameters. As expected, the chaotic attractors are obtained for values of parameters predicted by Melnikov theory. Moreover, the numerical analysis can be fruitfully employed to analyze the region of the parameter space where no theoret…
Effect of Electromechanical Loading on the Dielectric Properties of PLZT−x/65/35 Ceramics (x = 8 and 8.5)
2011
The influence of uniaxial pressure (0-800 bars) applied parallel to the ac electric field on the dielectric properties of La−modified lead–zirconate−titanate ceramics with the Zr/Ti ratio of 65/35 was investigated. Applying uniaxial pressure leads to the reduction of the peak intensity of the electric permittivity (ϵ), of the frequency dispersion as well as of the dielectric hysteresis. The peak intensity of ϵ becomes diffuse and shifts with increasing the pressure. Our results show that applying uniaxial pressure induces similar effects as increasing the Ti−ion concentration in PZT system. We interpreted our results based on domain switching processes under the action of combined electrome…
Analytical solution of 1D Ising-like systems modified by weak long range interaction
1999
It is well-known that 1D systems with only nearest neighbour interaction exhibit no phase transition. It is shown that the presence of a small long range interaction treated by the mean field approximation in addition to strong nearest neighbour interaction gives rise to hysteresis curves of large width. This situation is believed to exist in spin crossover systems where by the deformation of the spin changing molecules, an elastic coupling leads to a long range interaction, and strong bonding between the molecules in a chain compound leads to large values for nearest neighbour interaction constants. For this interaction scheme an analytical solution has been derived and the interplay betwe…
Phase Transitions in Li, K and Ag Modified Na1/2Bi1/2TiO3-SrTiO3-PbTiO3Solid Solutions
2012
Influence of moderate substitution of Na by monovalent metals Li, K and Ag on structure, phase transitions and dielectric properties of 0.4Na1/2Bi1/2TiO3-0.4SrTiO3-0.2PbTiO3 is studied. Substitution by Li increases, while substitution by K and Ag decreases tetragonality of unit cell. Li increases, Ag decreases while K weakly influences phase transition temperature. The characteristic for the parent phase relaxor state with Tt approaching Tm in case of substitution by K and Li transfers into diffused phase transition without Tm dependence on frequency and extended region of thermal hysteresis.
Nucleation and Collapse of the Superconducting Phase in Type-I Superconducting Films
2005
The phase transition between the intermediate and normal states in type-I superconducting films is investigated using magneto-optical imaging. Magnetic hysteresis with different transition fields for collapse and nucleation of superconducting domains is found. This is accompanied by topological hysteresis characterized by the collapse of circular domains and the appearance of lamellar domains. Magnetic hysteresis is shown to arise from supercooled and superheated states. Domain-shape instability resulting from long-range magnetic interaction accounts well for topological hysteresis. Connection with similar effects in systems with long-range magnetic interactions is emphasized.
Approach to rotor-shaft hysteretic whirl using Krylov-Bogoliubov techniques
2013
The internal friction associated with the shaft hysteresis or with the possible release of some shrink-fit coupling exerts a destabilizing effect on the over-critical rotor running, but may be efficiently counteracted by other external dissipative sources or by a proper anisotropic configuration of the support stiffness. The present analysis considers a symmetric rotor-shaft system on viscous-flexible supports with different stiffness on two orthogonal planes containing the bearing axis. The internal friction of the shaft is described either by a linear hysteretic model or by a nonlinear Coulombian force contrasting the rotor motion relative to the shaft ends. The nonlinear equations of mo…
In Silico Molecular Engineering of Dysprosocenium-Based Complexes to Decouple Spin Energy Levels from Molecular Vibrations
2019
Molecular nanomagnets hold great promise for spintronics and quantum technologies, provided that their spin memory can be preserved above liquid-nitrogen temperatures. In the past few years, the magnetic hysteresis records observed for two related dysprosocenium-type complexes have highlighted the potential of molecular engineering to decouple vibrational excitations from spin states and thereby enhance magnetic memory. Herein, we study the spin-vibrational coupling in [(CpiPr5)Dy(Cp*)]+ (CpiPr5 = pentaisopropylcyclopentadienyl, Cp* = pentamethylcyclopentadienyl), which currently holds the hysteresis record (80 K), by means of a computationally affordable methodology that combines first-pri…
KRYLOV-BOGOLIUBOV APPROACH TO NON-LINEAR HYSTERETIC INSTABILITY IN ROTORDYNAMICS
2012
The internal friction due to the shaft hysteresis or the shrink fitting release exerts a destabilizing effect on the overcritical rotor whirl, but may be counteracted by other external dissipative sources and/or by proper anisotropy of the support stiffness. The internal friction effect may be treated by either dry or viscous models, obtaining similar results in the hypothesis of small dissipation levels, provided that proper equivalence criteria are defined between the two approaches. The equivalence is here stated by imposing the same energy dissipation over a large number of shaft revolutions. Approximate closed-form autonomous solutions for a symmetric rotor arrangement subject to Coulo…