Search results for " polar"
showing 10 items of 1091 documents
Gas chromatography of homologous esters
1984
Abstract The gas chromatographic retention behaviour of the propanoyl and monochloropropanoyl esters of saturated C3C5 branched-chain and unsaturated C3C6 alcohols on SE-30 and OV-351 capillary columns at several temperatures is reported. Retention index increments at 80 and 120°C show the effect of branching in the alkyl chain and also the effect of unsaturation and of its position in the chain with chlorination at the two possible positions in the acyl chain. The various incremental effects are discussed and compared with the behaviour of the corresponding n-alkyl esters.
Valence Topological Charge-Transfer Indices for Reflecting Polarity: Correction for Heteromolecules
2005
Valence topological charge-transfer (CT) indices are applied to the calculation of dipole moments mu. The mu calculated by algebraic and vector semisums of the CT indices are defined. The model is generalized for molecules with heteroatoms and corrected for sp(3)-heteromolecules. The ability of the indices for the description of the molecular charge distribution is established by comparing them with mu of the valence-isoelectronic series of cyclopentadiene, benzene and styrene. Two CT indices, mu(vec) (vector semisum of vertex-pair mu) and mu(vec)V (valence mu(vec)) are proposed. The mu(vec) behaviour is intermediate between mu(vec) and mu(experiment). The correction is produced in the corr…
Flavour Separation of Helicity Distributions from Deep Inelastic Muon-Deuteron Scattering
2009
We present a LO evaluation of helicity densities of valence, \Delta u_v+\Delta d_v, non-strange sea, \Delta\bar{u}+\Delta\bar{d}, and strange quarks, \Delta s (assumed to be equal to \Delta\bar{s}). They have been obtained from the inclusive asymmetry A_{3,d} and the semi-inclusive asymmetries A^{\pi+}_{1,d}, A^{\pi-}_{1,d}, A^{K+}_{1,d}, A^{K-}_{1,d} measured in polarised deep inelastic muon-deuteron scattering. The full deuteron statistics of COMPASS (years 2002-2004 and 2006) has been used. The data cover the range Q^2 > 1 (GeV/c)^2 and 0.004<x<0.3. Both non-strange densities are found to be in a good agreement with previous measurements. The distribution of \Delta s(x) is compatible wit…
A premodern legacy: the "easy" criminalization of homosexual acts between women in the Finnish Penal Code of 1889.
1998
Homosexual acts between women were criminalized in Finland in the 1889 Penal Code which also criminalized men's homosexual acts for the first time explicitly in Finnish legislation. The inclusion of women in the Penal Code took place without much ado. In the article it is argued that the uncomplicated juxtaposing of men and women was due to the legacy of a cultural pattern where man and woman, as categories, were not in an all-pervasive polarity to each other, for example, in sexual subjectivity. A cultural pattern of low gender polarization was typical of preindustrial rural culture, and it can help us apprehend also certain other features in contemporary Finnish social and political life,…
APPLICATION OF UNMANNED AERIAL VEHICLES FOR GLACIER RESEARCH IN THE ARCTIC AND ANTARCTIC
2019
Unmanned aerial vehicles or drones are nowadays widely used in a broad field of scientific and commercial applications. Despite this, it is quite a new method for glacier mapping in polar regions and has a lot of advantages, as well as disadvantages over more classical remote sensing instruments. Here we examine the main issues associated with the application of drones for glacier research from our experience in Iceland, Greenland and the Antarctic. We use DJI Phantom series drones for the obtaining of aerial photographs and produce digital surface models (resolution of 8 – 16 cm) and orthomosaics (resolution of 2 – 4 cm) for glacier mapping. Several issues related to the ground control poi…
Crystal Structure of Heusler Compounds
2013
Heusler compounds are promising materials in many fields of contemporary research. The spectrum of their possible applications ranges from magnetic and magneto-mechanical materials over semiconductors and thermoelectrics to superconductors. An important feature of the Heusler compounds is the possibility of controlling the valence electron concentration by partial substitution of elements. On the other hand, the properties also depend on the degree of ordering of the crystal structure. In general, Heusler compounds crystallize in the Cu2MnAl-type structure but in many cases certain types of disorder are observed. In this chapter, a detailed description of the crystal structure as well as di…
Heavy-fermion superconductivity induced by antiferromagnetic spin fluctuations
2007
Superconductivity is caused by an attractive interaction between electrons at the Fermi level that induces the pairing of time-reversed electron states to Cooper pairs. Conventionally this attractive interaction is mediated by phonons. Theoretically, non-phonon mediated coupling seems to be likely for heavy-fermion superconductors whose low-temperature dynamics is dominated by antiferromagnetic spin correlations. However, evidence for spin-fluctuation coupling has not yet been experimentally observed. One of the most direct methods of investigation of the superconducting state is tunneling spectroscopy. We prepared cross-type tunneling junctions composed of the heavy-fermion superconductor …
Towards a full Heusler alloy showing room temperature half-metallicity at the surface
2007
In this article we investigate the surface spin polarization in a 100 nm Co2Cr0.6Fe0.4Al (CCFA) film grown ex situ epitaxially on MgO(100) with a 10 nm Fe buffer layer by means of spin resolved photoemission. We show that a careful in situ preparation of the sample surface leads to values for the room temperature spin polarization up to 45% at the Fermi level. To our knowledge, this is the highest value measured so far at the surface region of a full Heusler alloy at room temperature.
Against Expectations: Unassisted RNA Adsorption onto Negatively Charged Lipid Bilayers
2019
The composition and physicochemical properties of biological membranes can be altered by diverse membrane integral and peripheral proteins as well as by small molecules, natural and synthetic. Diverse oligonucleotides have been shown to electrostatically interact with cationic and bivalent ion loaded zwitterionic liposomes, leading to the formation of oligonucleotide-liposome aggregates. However, interaction of RNAs with other membrane surfaces remains ill understood. We used the nonnatural RNA10 to investigate RNA binding to anionic and net-uncharged membrane surfaces. RNA10 had initially been selected in a screen for nonnatural RNA motives that bind to phosphatidylcholine liposomes in the…
Relationship between vegetation microwave optical depth and cross-polarized backscatter from multiyear Aquarius observations
2017
Soil moisture retrieval algorithms based on passive microwave remote sensing observations need to account for vegetation attenuation and emission, which is generally parameterized as vegetation optical depth (VOD). This multisensor study tests a new method to retrieve VOD from cross-polarized radar backscattering coefficients. Three years of Aquarius/SAC-D data were used to establish a relationship between the cross-polarized backscattering coefficient σ HV and VOD derived from a multitemporal passive dual-channel algorithm (VODMT). The dependence of the correspondence is analyzed for different land use classes. There are no systematic differences in the slope for woody versus nonwoody vege…