Search results for "CEM"
showing 10 items of 3487 documents
Synthesis and structural properties of hexaaza[5]helicene containing two [1,2,3]triazolo[1,5-a]pyridine moieties
2013
Abstract We have synthesized a novel hexaaza[5]helicene in a straightforward way from neocuproine. The crystal structure has been elucidated with direct-space strategy TALP which demonstrates the power of the powder X-ray diffraction technique. In this crystal structure it is possible to see an interplanar angle of 33(1)° between the two triazolopyridine rings. The centrosymmetric crystal structure is a racemic mixture, but the resolution was not possible due to a ring-chain isomerization in a solution that produces a dynamic racemization.
Impact of basin burial and exhumation on Jurassic carbonates diagenesis on both sides of a thick clay barrier (Paris Basin, NE France).
2014
27 pages; International audience; Several diagenetic models have been proposed for Middle and Upper Jurassic carbonates of the eastern Paris Basin. The paragenetic sequences are compared in both aquifers to propose a diagenetic model for the Middle and Late Jurassic deposits as a whole. Petrographic (optical and cathodoluminescence microscopy), structural (fracture orientations) and geochemical (δ18O, δ13C, REE) studies were conducted to characterize diagenetic cements, with a focus on blocky calcite cements, and their connection with fracturation events. Four generations of blocky calcite (Cal1-Cal4) are identified. Cal1 and Cal2 are widespread in the dominantly grain-supported facies of t…
Reactive transport modelling of carbonate cementation in a deep saline aquifer, the Middle Jurassic Oolithe Blanche Formation, Paris Basin, France.
2016
10 pages; International audience; The Oolithe Blanche Formation (Bathonian, Middle Jurassic) is one of the deep saline aquifers of the Paris Basin in France. The spatial distribution of its reservoir properties (porosity, permeability, tortuosity, etc.) is now better known with relatively homogeneous properties, except for some levels in the central part of the basin, where permeability exhibits higher values. This spatial distribution has been correlated with diagenetic events (variability of cementation) and palaeo-fluid flow circulation phases leading to variable cementation. In this paper, numerical simulations of reactive transport are performed. They provide a preliminary quantitative…
Toward a Comprehensive Dam Monitoring: On-Site and Remote-Retrieved Forcing Factors and Resulting Displacements (GNSS and PS–InSAR)
2021
Many factors can influence the displacements of a dam, including water level variability and environmental temperatures, in addition to the dam composition. In this work, optical-based classification, thermal diachronic analysis, and a quasi-PS (Persistent Scatter) Interferometric SAR technique have been applied to determine both forcing factors and resulting displacements of the crest of the Castello dam (South Italy) over a one-year time period. The dataset includes Sentinel-1A images acquired in Interferometric Wide swath mode using the Terrain Observation with Progressive Scans SAR (TOPSAR); Landsat 8 Thermal Infrared Sensor (TIRS) thermal images, and Global Navigation Satellite System …
Acoustic properties of ancient shallow-marine carbonates: effects of depositional environments and diagenetic processes (Middle Jurassic, Paris Basin…
2010
17 pages; International audience; Examination of petrophysical properties (acoustic velocity, porosity, permeability, and density) and petrographical characteristics (texture, facies composition, and diagenesis) of more than 250 core plugs from the Middle Jurassic carbonates of the eastern Paris Basin provides insights into the parameters controlling acoustic velocities in relatively low-porosity carbonate rocks ({Phi} < 20%). The pore-type observations reveal distinct acoustic velocities in samples with intergranular macropores and samples with micropores in subhedral micrite, such that velocities in microporous mudstone–wackestone (lagoonal) deposits are greater than in macroporous grains…
Numerical modelling of magma dynamics coupled to tectonic deformation of lithosphere and crust
2013
Many unresolved questions in geodynamics revolve around the physical behaviour of the two-phase system of a silicate melt percolating through and interacting with a tectonically deforming host rock. Well-accepted equations exist to describe the physics of such systems and several previous studies have successfully implemented various forms of these equations in numerical models. To date, most such models of magma dynamics have focused on mantle flow problems and therefore employed viscous creep rheologies suitable to describe the deformation properties of mantle rock under high temperatures and pressures. However, the use of such rheologies is not appropriate to model melt extraction above …
Aseismic strain episodes at Campi Flegrei Caldera, Italy
2021
Since 2004 a research project has been developed to monitor subsurface deformation of Italian volcanoes using borehole strainmeters and long-baseline tiltmeters. Six Sacks-Evertson dilatometers were installed around Campi Flegrei caldera and Vesuvius during 2004–2005 (Scarpa et al., 2007), and in 2008 these instruments were supplemented by two arrays of 28–280 m long water-tube tiltmeters in underground tunnels. Relevant strainmeter and tiltmeter data have been collected and analysed from the instruments installed near Campi Flegrei caldera during the recent unrest episodes. In the period 2004–2005 strain, tilt and GPS data from Campi Flegrei indicate the onset of surface deformation that a…
COMMENT TO LEHRMANN ET AL. NEW SECTIONS AND OBSERVATIONS FROM THE NANPANJIANG BASIN, SOUTH CHINA
2016
In the study of Earth-surface environmental processes during the events associated with the Permian–Triassic boundary, a key issue is the nature of the latest Permian pre-extinction surface in shallow marine limestones in numerous sites, principally within the Tethyan realm. Sediments below this surface pre-date the extinction event, so that the limestones comprising these latest Permian facies contain diverse fossil remains of organisms that lived just before the extinction. At all reported sites, this surface is disconformably overlain by post-extinction sediments, which contain microbialites in many places, particularly in Tethys. The nature of the youngest pre-extinction surface remains…
Muridae from the late Miocene site of Venta del Moro (Eastern Spain)
2016
AbstractMurids are usually the dominant faunas of the late Miocene and early Pliocene micromammal assemblages. The present work deals with the murid faunas of the well-known late Miocene locality of Venta del Moro, comprising over 2700 molars ascribed to the taxa Apodemus gorafensis, Occitanomys alcalai, Paraethomys meini and Stephanomys dubari. This list differs from those of previous studies by the presence of A. gorafensis instead of A. gudrunae. The presence of A. gudrunae in younger localities than Venta del Moro implies that both species, considered ancestor and descendant, coexisted for some time. In addition, the analysis of such an extensive collection has allowed us to check the v…
Lipid Nanoparticles as Potential Gene Therapeutic Delivery Systems for Oral Administration.
2017
Background Gene therapy has experimented an increasing attention in the last decades, due to its enormous potential applications in the medical field. It can be defined as the use of genes or genetic material (DNA, RNA, oligonucleotides) to treat or prevent a disease state, generally a geneticbased one. Application Other applications, like treating viral, bacterial or parasite infections or development of vaccines are gaining also interest. Efficient gene therapy is mainly dependent on the ability of the highly labile genetic material to reach the therapeutic target. For this purpose, different delivery systems have been designed and extensively investigated. Nanoparticles offer a broad ran…