Search results for "CHIRALITY"

Novel stripe textures in nonchiral hexatic liquid-crystal films

1992

A novel macroscopic stripe texture has been observed in freely suspended films of nonchiral liquid crystal, uniform stripes of alternating molecular orientation form spontaneously at the smectic-C--to--surface-hexatic phase transition and broaden with decreasing temperature. The stripes are identified as splay domains whose formation is attributed to the polar symmetry of the hexatic surface layers. Transverse (director bend) walls, which lead to an additional modulation of the basic one-dimensional pattern, are manifested inside thick circular islands as twelve-armed star defects.

4,4,4′,4′,7,7′-Hexamethyl-2,2′-spirobichroman

2000

The title compound, C23H28O2, was obtained from the reaction of acetone with meta-cresol. The molecular structure consists of two identical subunits which are nearly perpendicular to each other. The oxygen-containing rings are not planar and the molecule is chiral. The crystal structure consists of chains of molecules of the same chirality arranged along the [010] axis.

Optically active titanium complexes containing a tridentate linked amido-cyclopentadienyl ligand

2000

Optically active titanium complexes Ti{η5:η1-C5R4SiMe2NC6H10 (OCH2Ph)-2}Cl2 (R = H, Me), containing a cyclopentadienyl ligand linked to the chiral trans-2-benzyloxycyclohexylamido group, were synthesized and characterized in both enantiomerically pure forms. A single crystal X-ray structure analysis of (−)-(R,R)-Ti{η5:η1-C5H4SiMe2NC6H10(OCH2Ph)-2}Cl2 shows a structure in which the benzyloxy group in the amido sidechain is not interacting with the titanium center. Upon activation with n-butyllithium, these complexes hydrogenate acetophenone N-benzylimine with low enantioselectivity. Chirality 12:472–475, 2000. © 2000 Wiley-Liss, Inc.

Cooperative supramolecular polymerization and amplification of chirality in C3-symmetrical OPE-based trisamides.

2011

Sergeants-and-soldiers experiments demonstrate the amplification of chirality that transforms the racemic mixture of helical columns formed from OPE-based trisamides into enantiomerically enriched helical structures (see scheme).The cooperative supramolecular polymerization of the trisamides is investigated by theoretical calculations and temperature-dependent UV/Vis and CD experiments. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

What Contributes to the Measured Chiral Optical Response of the Glutathione-Protected Au25 Nanocluster?

2023

The water-soluble glutathione-protected [Au25(GSH)18]−1 nanocluster was investigated by integrating several methodologies such as molecular dynamics simulations, essential dynamics analysis, and state-of-the-art time-dependent density functional theory calculations. Fundamental aspects such as conformational, weak interactions and solvent effects, especially hydrogen-bonds, were included and found to play a fundamental role in assessing the optical response of this system. Our analysis demonstrated not only that the electronic circular dichroism is extremely sensitive to the solvent presence but also that the solvent itself plays an active role in the optical activity of such system, formin…

The Ξ(1620) and Ξ(1690) molecular states from S = −2 meson-baryon interaction up to next-to-leading order

2023

We have studied the meson-baryon interaction in the neutral $S=-2$ sector using an extended Unitarized Chiral Perturbation Theory, which takes into account not only the leading Weinberg-Tomozawa term (as all the previous studies in $S=-2$ sector), but also the Born terms and next-to-leading order contribution. Based on the SU(3) symmetry of the chiral Lagrangian we took most of the model parameters from the BCN model \cite{Feijoo:2018den}, where these were fitted to a large amount of experimental data in the neutral $S=-1$ sector. We have shown that our approach is able to generate dynamically both $\Xi(1620)$ and $\Xi(1690)$ states in very reasonable agreement with the data, and can natura…

Influence of chirality on the structure of phospholipid monolayers.

1993

2019

A unique series of six biaryl natural products displaying four different coupling types (5,1′, 7,1′, 7,8′, and 5,8′) were isolated from the roots of the West African liana Ancistrocladus abbreviatus (Ancistrocladaceae). Although at first sight structurally diverse, these secondary metabolites all have in common that they belong to the rare group of naphthylisoquinoline alkaloids with a fully dehydrogenated isoquinoline portion. Among the African Ancistrocladus species, A. abbreviatus is so far only the second one that was found to produce compounds with such a molecular entity. Here, we report on four new representatives, named ancistrobreveines A–D (12–14, and 6). They were identified alon…

Topologically Protected Twist Edge States for a Resonant Mechanical Laser-Beam Scanner

2019

We design a one-dimensional chain of two different alternating three-dimensional elastic chiral unit cells. The chain’s topological band gap, a result of the alternation of unit cells combined with their chirality and an effective mirror symmetry, guarantees a protected edge state, corresponding to a localized twist mode with an eigenfrequency inside the one-dimensional band gap. A small axial modulation at the one end of the beam can excite this resonant twist mode at the other end of the beam, via evanescent modes in the gap. The topological robustness of the edge state allows us to add a micromirror to the other end of the beam, turning the arrangement into a resonant mechanical laser-be…

Vergleichende dimerisierung der enantiomere von Oct-1-in-3-ol mit chiralen rhodium-phosphan-komplexen

1996

Abstract Three optically active phosphanes ([(S)-2-methylbutyl]3−nP[phenyl]n(n = 0, 1, 2), were tested as ligands in rhodium(I) complexes to form catalysts for the enantioselective dimerisation of (R)- and (S)-oct-1-yn-3-ol. The catalytic reaction provides enantioselectivity for this type of CC bond formation. For reactions at 45–75°C and depending on the P-ligand used the rates vary for both enantiomers from 6:1 to 50:1 in favour of the (S)-octynol.