Search results for "CONST"
showing 10 items of 7706 documents
Preliminary Evaluation of Plasmix Compound from Plastics Packaging Waste for Reuse in Bituminous Pavements
2021
Finding an appropriate technical solution for reusing waste plastics is crucial for creating a circular plastic economy. Although mechanical recycling is the best option for recycling post-consumer plastics, some heterogeneous mixed plastics cannot be recycled to produce secondary material due to their very low properties. In this case, alternative routes should be considered in order to limit their disposal as much as possible. Therefore, in order to solve the environmental problems in the landfills of plastic waste recycling, and to improve the mechanical performance of bitumen for road pavement, the reuse of these post-consumer plastic wastes are preliminarily evaluated for the modificat…
Brief an Garlieb H. Merkel
1797
Ms. 930a, Nr. 5, Bl. 11r-14v Recke, Charlotte Elisabeth (Elisa) Constantia v. der. Brief an Garlieb H. Merkel, Pyrmont (?), d[en] 8. May 1797 Autora rokraksts / Autograph, vācu un franču val. / Deutsch und Französisch [8] lpp. / S. Attēlu numuri / Bildnummern: 930a-005-1 – 930a-005-8 Der Brief von Elisabeth von der Recke wurde wahrscheinlich in Pyrmont verfasst. Die Autorin bezieht sich auf einen Brief Merkels, auf den sie antwortet. Sie äußert ihre grundsätzliche Zustimmung zur Idee einer Befreiung der Bauern in Liv- und Kurland und kann als Besitzerin zweier Güter, die ihr von der Kaiserin Katharina II. übereignet wurden, als Adressatin von Merkels Forderungen, die er in „Die Letten“ form…
L’eterno ritorno del problema del metodo
2022
Fabio Ciaramelli’s book L’ordine simbolico della legge e il problema del metodo proposes a convincing methodological perspective for legal knowledge in contemporary constitutional democracies. The central claim is that a middle path between strong objectivism and absolute discretion exists. Ciaramelli thinks that the key concept for legal methodology is that of “symbolic order”. In this paper I deal with this notion and try to emphasize some features of it from a perspective slightly different from Ciaramelli’s one.
ChemInform Abstract: Assignment of the Absolute Configuration and Total Synthesis of (+)-Caripyrin.
2015
The antifungal secondary metabolite (+)-caripyrin was studied by vibrational circular dichroism spectroscopy. Analysis of the recorded data, with the Boltzmann weighted-average of the spectra calculated at the B3LYP/6-311G(d,p) level of theory for all relevant conformers, unequivocally proved the (R,R)-configuration for the dextrorotatory natural product. Based on this finding, a short enantioselective synthesis of (+)-caripyrin was developed.
A Domain Imbedding Method with Distributed Lagrange Multipliers for Acoustic Scattering Problems
2003
The numerical computation of acoustic scattering by bounded twodimensional obstacles is considered. A domain imbedding method with Lagrange multipliers is introduced for the solution of the Helmholtz equation with a second-order absorbing boundary condition. Distributed Lagrange multipliers are used to enforce the Dirichlet boundary condition on the scatterer. The saddle-point problem arising from the conforming finite element discretization is iteratively solved by the GMRES method with a block triangular preconditioner. Numerical experiments are performed with a disc and a semi-open cavity as scatterers.
Poincare Inequalities and Spectral Gap, Concentration Phenomenon for G-Measures
2002
We produce a new approach based upon inequalities of Poincare’s type for giving constructive estimates of the mixing rate for a family of mixing stationary processes continuously depending on their past called g-measures. We establish also exponential inequalities of Hoeffding’s type leading to a concentration phenomenon for a large class of observables; this last property permits in particular to give the typical behaviour of the n-orbits of a g-measure.
The Radon-Wigner Transform and Its Application to First-order Optical Systems
2009
The Radon-Wigner transform is presented as a tool for the description of 1st-order optical systems. The input/output relationships for this phase-space representation are obtained and their application in analysis and design tasks is pointed out.
Constant inner potential DFT for modelling electrochemical systems under constant potential and bias
2021
Electrochemical interfaces and reactions play a decisive role in e.g. clean energy conversion but understanding their complex chemistry remains an outstanding challenge. Constant potential or grand canonical ensemble (GCE) simulations are indispensable for unraveling the properties of electrochemical processes as a function of the electrode potential. Currently, constant electrode potential calculations at the density functional theory (DFT) level are carried out by fixing the Fermi level of the simulation cell. However, the Fermi level from DFT calculations does does not always reflect the experimentally controlled electrode potential or describe the thermodynamic independent variable in G…
A novel approach to nonlinear variable-order fractional viscoelasticity.
2020
This paper addresses nonlinear viscoelastic behaviour of fractional systems with variable time-dependent fractional order. In this case, the main challenge is that the Boltzmann linear superposition principle, i.e. the theoretical basis on which linear viscoelastic fractional operators are formulated, does not apply in standard form because the fractional order is not constant with time. Moving from this consideration, the paper proposes a novel approach where the system response is derived by a consistent application of the Boltzmann principle to an equivalent system, built at every time instant based on the fractional order at that instant and the response at all the previous ones. The ap…
Second harmonic ac polarography of strongly adsorbed electroactive species
1981
Abstract The second harmonic ac current is calculated for the case of a quasi-reversible surface redox system: both species are strongly adsorbed according to a Langmuir isotherm and the kinetics of the process are controlled by the electron transfer. The current is measured with a phase-sensitive detector and the variation of the in-phase and quadrature components vs. the frequency leads to the surface rate constant ks. The experimental results obtained for benzo-(c)cinnoline are in good agreement with the theoretical predictions and with the results of impedance measurements. The advantages of the two methods are compared.