Search results for "Composite"
showing 10 items of 4584 documents
Is the special pair structure a good strategy for the kinetics during the last step of the energy transfer with the nearest antenna? A chemical model…
2013
A cofacial bis(Mg(II)porphyrin)-C(6)H(4)-free base ([Mg(2)]-bridge-FB) dyad shows S(1) energy transfer in both directions and much slower rates than similar monoporphyrin systems are observed.
Structure of the 5′ untranslated region in SARS-CoV-2 genome and its specific recognition by innate immune systemviathe human oligoadenylate synthase…
2022
2′-5′-Oligoadenylate synthetase 1 (OAS1) is one of the key enzymes driving the innate immune system response to SARS-CoV-2 infection whose activity has been related to COVID-19 severity. OAS1 is a sensor of endogenous RNA that triggers the 2′-5′-oligoadenylate/RNase L pathway. Upon SARS-CoV-2 infection, OAS1 is responsible for the recognition of viral RNA and has been shown to possess a particularly high sensitivity for the 5′-untranslated (5′-UTR) RNA region, which is organized in a double-strand stem loop motif (SL1). Here we report the structure of the SL1/OAS1 complex also rationalizing the high affinity for OAS1.
Boolean operations mediated by an ion-pair receptor of a multi-readout molecular logic gate
2013
A heteroditopic BODIPY dye that performs all basic Boolean operations with a cation (K+) and an anion (F-) as inputs and absorption, transmission and fluorescence as outputs is described. The molecular logic gate can also act as a digital comparator between the inputs.
A pH-triggered bistable copper(II) metallacycle as a reversible emulsion switch for biphasic processes.
2013
A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.
Shear viscosity of polybutyleneterephthalate/liquid crystal polymer blends
1989
Viscosity measurements have been carried out on blends of polybuty-leneterephthalate (PBT) and a liquid crystalline copolyesteramide (LCP). The flow curves of the blends with LCP content larger than 20%, show a behavior similar to that of the pure LCP, with a rapid rise of the viscosity at low shear rates. The viscosity-composition curves exhibit a deep minimum at low LCP content which may be mainly attributed to the lack of interactions between the two phases.
Touching the upper limit for ferromagnetic interactions in hetero-bridged dinuclear [Cu-2(II)] complexes using a novel N-5-dinucleating ligand bearin…
2012
A novel N-5-dinucleating ligand 4-amino-3,5-bis(bipyridine-2-yl)-1,2,4-triazole allows the preparation for the first time, and under mild conditions, of single and mixed amido(R-NH-)-bridged copper(II) complexes, the latter exhibiting very strong ferromagnetic coupling.
Morphology Study of the Porosity of the GaP Surface Layer Formed on the Surface of a Single Crystal by Electrochemical Etching
2021
The article analyzes the morphological characteristics of a porous GaP surface layer formed on the surface of monocrystalline gallium phosphide by electrochemical etching. The correlations between the etching time and the appropriate size, shape and density of pores have been established and studied in detail.
A highly selective, Hg2+ triggered hydrogelation: modulation of morphology by chemical stimuli
2013
We report the first Hg(2+) selective hydrogelation by 4'-[4-(4-aminophenyl)phenyl]-2,2':6',2''-terpyridine. The gel showed remarkable response towards specific chemical agents such as benzo-18-crown-6 ether and K(+) which enabled extensive modulation of the gel morphology.
Development of crystal morphology during unitaxial growth in a progressively widening vein: II. Numerical simulations of the evolution of antitaxial …
2001
The development of fibrous morphology and capability of fibres for tracking the opening trajectory were investigated using numerical simulations of a natural antitaxial fibrous vein. Starting from a non-unique best case, variation of fracture opening velocity, grain size, wall roughness, growth anisotropy and crystal growth velocity shows that these parameters differ in importance for crystal morphology and tracking capability. Fibrous veins can be simulated using crack–seal opening of the fracture. Grain boundaries track the opening trajectory if the wall roughness is high, opening increments are small and crystals touch the wall before the next crack increment starts.
Effect of Elongational Flow and Polarity of Organomodified Clay on Morphology and Mechanical Properties of a PLA Based Nanobiocomposite
2016
Abstract In biodegradable polymer world nanobiocomposites represent a new group of materials filled with inert nanoparticles that shows very interesting properties and the biodegradability of the matrix. In this work we have studied the effect of the polarity of the organomodified montmorillonite and of the elongational flow on the morphology and the rheological and mechanical properties of a new nanobiocomposite with a matrix of biodegradable PLA based blend. The elastic modulus enhances in presence of the nanofiller and this increase is larger and larger with the increment of the orientation. The tensile strength does not show any significant change at the same level of orientation. Moreo…