Search results for "DECOMPOSITION"
showing 10 items of 766 documents
ChemInform Abstract: 4-Fluoroanilines: Synthesis and Decomposition.
2010
Abstract Fourteen N- and/or 2-substituted 4-fluoroanilines were prepared (the series includes N–C2-bridged compounds). Some of them were found to be thermally unstable when dissolved in chloroform. Both 19 F NMR spectra and comparison of GIAO-DFT calculated and experimental 13 C chemical shifts were used to suggest decomposition products of 4-fluoroanilines.
Photocatalytic activity of binary and ternary SnO2–ZnO–ZnWO4 nanocomposites
2015
Binary and ternary SnO2-ZnO-ZnWO4 nanocomposites were prepared by a sol-gel route. The photocatalytic activity of the samples was evaluated through the decomposition of 4-nitrophenol and partial oxidation of 4-methoxybenzyl alcohol to p-anisaldehyde. All the mixed catalysts revealed higher photoactivity than bare ZnO, SnO2 or ZnWO4 and the best performances were exhibited by the binary nanocomposites. The high photocatalytic activity was explained by the presence of heterojunctions among different semiconductors that enhance the separation of the photogenerated electron-hole pairs, hindering their recombination. As a general consideration, an essential role was played by the electronic feat…
Precursor-Controlled Formation of Novel Carbon/Metal and Carbon/Metal Oxide Nanocomposites
2008
Carbonaceous materials have long been considered as a high-performance material due to their light weight, high thermal resistance, tunable porosity and strength, but also because of their exciting electronic properties. When hybridized with other metal nanoparticles to form carbon/ metal nanocomposites (CMCs), multifunctionality is achieved through the combination of carbon and metal, leading to interesting magnetic materials, catalysts, battery electrodes, or chemical sensors. Various methods for preparing CMCs have been developed. In most cases, metal cations deposited on carbonaceous materials were reduced chemically or physically to form CMCs. In these processes, heterogeneous dispersi…
Morphology, flexural, and thermal properties of sepiolite modified epoxy resins with different curing agents
2006
A bisphenol A-based epoxy resin was modified with 5 wt% organically modified sepiolite (Pangel B40) and thermally cured using two different curing agents: an aliphatic diamine (Jeffamine D230, D230) and a cycloaliphatic diamine (3DCM). The morphology of the cured materials was established by scanning and transmission electron microscopy analysis. The thermal stability, thermo-mechanical properties, and flexural behaviour of the sepiolite-modified matrices were evaluated and compared with the corresponding neat matrix. The initial thermal decomposition temperature did not change with the addition of sepiolite. The flexural modulus of the epoxy matrix slightly increases by the incorporation o…
Distributed multi-objective optimization methods for shape design using evolutionary algorithms and game strategies
2012
Corrigendum to ‘Automated detection and localization system of myocardial infarction in single-beat ECG using Dual-Q TQWT and wavelet packet tensor d…
2021
How do normalization schemes affect net spillovers? A replication of the Diebold and Yilmaz (2012) study
2019
Abstract This paper replicates the Diebold and Yilmaz (2012) study on the connectedness of the commodity market and three other financial markets: the stock market, the bond market, and the FX market, based on the Generalized Forecast Error Variance Decomposition, GEFVD. We show that the net spillover indices (of directional connectedness), used to assess the net contribution of one market to overall risk in the system, are sensitive to the normalization scheme applied to the GEFVD. We show that, considering data generating processes characterized by different degrees of persistence and covariance, a scalar-based normalization of the Generalized Forecast Error Variance Decomposition is pref…
Asymmetric semi-volatility spillover effects in EMU stock markets
2018
Abstract The aim of this paper is to quantify the strength and the direction of semi-volatility spillovers between five EMU stock markets over the 2000–2016 period. We use upside and downside semi-volatilities as proxies for downside risk and upside opportunities. In this way, we aim to complement the literature, which has focused mainly on the contemporaneous correlation between positive and negative returns, with the evidence of asymmetry also in semi-volatility transmission. For this purpose, we apply the Diebold and Yilmaz (2012) methodology, based on a generalized forecast error variance decomposition, to downside and upside realized semi-volatility series. While the analysis of Diebol…
Conversion electron Mössbauer study of vacuum and thermally treated vivianite
1990
Natural vivianite samples were studied by Mossbauer transmission and conversion electron spectroscopy. The intensities of ferrous doublets in vivianite and the widths of the resonance lines depend strongly on the origin of the samples, on their preparation history, and on exposures in vacuo as well as on thermal treatments. An additional ferrous doublet appearing in samples after vacuum treatment can be ascribed to a tetrahydrate phosphate phase appearing at the surface due to dehydration. Heating at 413 K in dry air for periods of 15–240 min causes a higher oxidation and decomposition rate at the surface region than in the bulk of vivianite. All results do not confirm the assumption publis…
Acute Type Refinements of Tetrahedral Partitions of Polyhedral Domains
2001
We present a new technique to perform refinements on acute type tetrahedral partitions of a polyhedral domain, provided that the center of the circumscribed sphere around each tetrahedron belongs to the tetrahedron. The resulting family of partitions is of acute type; thus, all the tetrahedra satisfy the maximum angle condition. Both these properties are highly desirable in finite element analysis.