Search results for "Degenerate energy levels"
showing 10 items of 221 documents
Identification of spatially confined states in two-dimensional quasiperiodic lattices.
1995
We study the electronic eigenstates on several two-dimensional quasiperiodic lattices, such as the Penrose lattice and random-tiling lattices, using a tight-binding Hamiltonian in the vertex model. The infinitely degenerate states at E=0 are especially investigated. We present a systematic procedure which allows us to identify numerically the spatially strongly localized so-called confined states.
Kinetic exchange Hamiltonian for orbitally degenerate ions
1998
Abstract A new approach to the problem of the kinetic exchange for orbitally degenerate ions is developed. The highly anisotropic effective Hamiltonian is expressed in terms of unit irreducible tensor operators and spin operators. All parameters of the exchange Hamiltonian are expressed through relevant transfer integrals, crystal field and Racah parameters for the metal ions. As an example the edge-shared ( D 2 h ) bioctahedral cluster is discussed and some comments on the considerations of Anderson, Goodenough and Kanamori and McConnell are given.
Magnetic Exchange between Orbitally Degenerate Ions: A New Development for the Effective Hamiltonian
1998
A new approach to the problem of the kinetic exchange for orbitally degenerate ions is developed. The constituent multielectron metal ions are assumed to be octahedrally coordinated, and strong crystal field scheme is employed, making it possible to take full advantage from the symmetry properties of the fermionic operators and collective electronic states. In the framework of the microscopic approach, the highly anisotropic effective Hamiltonian of the kinetic exchange is constructed in terms of spin operators and standard orbital operators (matrices of the unit cubic irreducible tensors). As distinguished from previous considerations, the effective Hamiltonian is derived for a most genera…
Optical Frequency Combs Generated in Silica Microspheres in the Telecommunication C-, U-, and E-Bands
2021
Optical frequency combs (OFCs) generated in microresonators with whispering gallery modes are demanded for different applications including telecommunications. Extending operating spectral ranges is an important problem for wavelength-division multiplexing systems based on microresonators. We demonstrate experimentally three spectrally separated OFCs in the C-, U-, and E-bands in silica microspheres which, in principle, can be used for telecommunication applications. For qualitative explanation of the OFC generation in the sidebands, we calculated gain coefficients and gain bandwidths for degenerate four-wave mixing (FWM) processes. We also attained a regime when the pump frequency was in t…
Matrix algebras with degenerate traces and trace identities
2022
In this paper we study matrix algebras with a degenerate trace in the framework of the theory of polynomial identities. The first part is devoted to the study of the algebra $D_n$ of $n \times n$ diagonal matrices. We prove that, in case of a degenerate trace, all its trace identities follow by the commutativity law and by pure trace identities. Moreover we relate the trace identities of $D_{n+1}$ endowed with a degenerate trace, to those of $D_n$ with the corresponding trace. This allows us to determine the generators of the trace T-ideal of $D_3$. In the second part we study commutative subalgebras of $M_k(F)$, denoted by $C_k$ of the type $F + J$ that can be endowed with the so-called st…
Relativistic coupled-cluster calculations on XeF6: Delicate interplay between electron-correlation and basis-set effects
2015
A systematic relativistic coupled-cluster study is reported on the harmonic vibrational frequencies of the O(h), C(3v), and C(2v) conformers of XeF6, with scalar-relativistic effects efficiently treated using the spin-free exact two-component theory in its one-electron variant (SFX2C-1e). Atomic natural orbital type basis sets recontracted for the SFX2C-1e scheme have been shown to provide rapid basis-set convergence for the vibrational frequencies. SFX2C-1e as well as complementary pseudopotential based computations consistently predicts that both O(h) and C(3v) structures are local minima on the potential energy surface, while the C(2v) structure is a transition state. Qualitative disagre…
Boundary Regularity for the Porous Medium Equation
2018
We study the boundary regularity of solutions to the porous medium equation $u_t = \Delta u^m$ in the degenerate range $m>1$. In particular, we show that in cylinders the Dirichlet problem with positive continuous boundary data on the parabolic boundary has a solution which attains the boundary values, provided that the spatial domain satisfies the elliptic Wiener criterion. This condition is known to be optimal, and it is a consequence of our main theorem which establishes a barrier characterization of regular boundary points for general -- not necessarily cylindrical -- domains in ${\bf R}^{n+1}$. One of our fundamental tools is a new strict comparison principle between sub- and superpara…
Reversible normal forms of degenerate cusps for planar diffeomorphisms
1998
Resume Dans cet article on donne des formes normales de germes a l'origine de diffeomorphismes reversibles du plan dont la partie lineaire est unipotente a valeurs propres positives. Le calcul de ces formes normales est base sur des algorithmes de geometrie algebrique effective. On etudie aussi des deformations generiques a k parametres (1 ≤ k ≤ 6).
Existence and uniqueness for a degenerate parabolic equation with 𝐿¹-data
1999
In this paper we study existence and uniqueness of solutions for the boundary-value problem, with initial datum in L 1 ( Ω ) L^{1}(\Omega ) , u t = d i v a ( x , D u ) in ( 0 , ∞ ) × Ω , \begin{equation*}u_{t} = \mathrm {div} \mathbf {a} (x,Du) \quad \text {in } (0, \infty ) \times \Omega , \end{equation*} − ∂ u ∂ η a ∈ β ( u ) on ( 0 , ∞ ) × ∂ Ω , \begin{equation*}-{\frac {{\partial u} }{{\partial \eta _{a}}}} \in \beta (u) \quad \text {on } (0, \infty ) \times \partial \Omega ,\end{equation*} u ( x , 0 ) = u 0 ( x ) in Ω , \begin{equation*}u(x, 0) = u_{0}(x) \quad \text {in }\Omega ,\end{equation*} where a is a Carathéodory function satisfying the classical Leray-Lions hypothesis, ∂ / …
Doubly nonlinear periodic problems with unbounded operators
2004
Abstract The solvability of the evolution system v ′( t )+ B ( t ) u ( t )∋ f ( t ), v ( t )∈ A ( t ) u ( t ), 0 t T , with the periodic condition v (0)= v ( T ) is investigated in the case where A (t) are bounded, possibly degenerate, subdifferentials and B (t) are unbounded subdifferentials.