Search results for "Derivative"

Thermolysis of 3-(carbazol-3-yl)-2-azidopropenoates

2000

Abstract Thermal cyclisation of 2-azido-3-(carbazol-3-yl)propenoic esters produces the 1,6-dihydropyrrolo[3,2- c ]carbazole and not the 1,9-dihydropyrrolo[2,3- b ]carbazole whereas, in the case of the 4-methylcarbazolyl derivative, the 1,9-dihydropyrrolo[2,3- b ]-carbazole is formed in preference to the alternative pyrido[4,3- c ]carbazole.

Control of the Transmission Ratio Derivative in Passenger Car Powertrain with CVT

2001

Covalently linked multi-calixarenes

1998

Abstract ipso-Nitration of t-butyl calix[4]arene tetraethers and subsequent hydrogenation provides an easy access to monoamino calix[4]arenes. Reaction with di- and triacid chlorides leads to various double- and triple-calix[4]arenes. With tetraacid chlorides derived from calix[4]arenes in the cone- or 1,3-alternate-conformations penta-calix[4]arenes are available as molecularly uniform species, which may be regarded as the first generation of calix[4]arene based dendrimers. The structure of the mononitro tetraester derivative, which may serve as a general building block has been confirmed by single crystal X-ray analysis.

Zur Reaktion von ?Pyrazolonblau? mit Diazomethan

1989

About the Reaction of „Pyrazolone Blue” with Diazomethane The reaction of “pyrazolone blue” with diazomethane was investigated. A pyridazinone derivative 3, a heterocyclic spiro-cyclopropyl product 4 and a compound 7, which contains three pyrazolone and two diazomethane entities, are formed. 3 reacts with an excess of diazomethane to the methoxy derivative 6. The spiro-cyclopropyl compound 4 is not stable and isomerizes to the corresponding 4,4′-methylidene-bispyrazolone 5. The structures of the products were established by spectroscopic methods and X-ray analysis.

ChemInform Abstract: Intramolecular Cyclization of Chloral Allyl Hemiacetal under the Action of the Fe(CO)5-DMF System.

2010

Chloral allyl hemiacetal undergoes cyclization in the presence of the Fe(CO)5-DMF system to form 3,3,5-trichloro-2-hydroxytetrahydropyran rather than a butyrolactone derivative.

ChemInform Abstract: Total Synthesis of (-)-Hymenosetin.

2016

Hymenosetin (I) and its N-methyl analogue are prepared in 11 and 8 steps, respectively, from citronellal employing an intramolecular Diels-Alder reaction as the key step.

Synthese und biochemische Eigenschaften substituierter Phenoxy- und Anilino-1,3,5-triazine

1983

Die nucleophile Substitution eines Chloratoms in 2,4-Dichlor-6-diethylamino-1,3,5-triazin (1) durch die Hydroxyacetophenone 2a–c fuhrt zu den 2-Acetylphenoxy-4-chlor-6-diethylamino-1,3,5-triazinen 3a–c. Analog geht aus der Umsetzung von 1 mit 4-Fluoranilin (4a) das Monoanilinoderivat 5a hervor; dagegen bildet sich unter den gleichen Reaktionsbedingungen aus 1 und 2-Fluoranilin (4b) das Dianilinoderivat 5b. Strukturtyp 3 zeichnet sich durch antimykotische und Antiprotozoenwirksamkeit aus, wahrend 5 herbizide Wirkungen auszulosen vermag. Synthesis and Biochemical Properties of Substituted Phenoxy- and Anilino-1,3,5-triazines The nucleophilic substitution of one chlorine atom in 2,4-dichloro-6…

ChemInform Abstract: Modular One-Pot Synthesis of Tetrasubstituted Pyrroles from α-(Alkylideneamino)nitriles.

2008

2,3,4,5-Tetrasubstituted pyrroles have been prepared with high regioselectivity by a formal cycloaddition of α-(alkylideneamino)nitriles and nitroolefins followed by elimination of HCN and HNO2. The reaction allows the convergent construction of the pyrrole ring in four steps from a nitroalkane and three aldehydes.

Coordinative Stabilization ofCyclo-Tetratellurium as[Te4{Cr(CO)5}4]: The First Organometallic Derivative of a Tellurium Allotrope

1997

ChemInform Abstract: Synthesis of the New Ring System Pyrrolizino[2,3-b]indol-4(5H)-one.

2011

A variety of pyrrolizinoindolones (VIII) is synthesized as demonstrated for derivative (VIIIa).