Search results for "Diffraction"
showing 10 items of 1584 documents
Template-based synthesis of nickel oxide
2015
Nanocrystalline NiO has been produced using a facile template-based synthesis from nickel nitrate solutions using cellulose as a template. Thus obtained oxides were studied by scanning electron microscopy, x-ray diffraction, Raman scattering spectroscopy, photoluminescence spectroscopy and confocal spectromicroscopy. The filamentary/coral morphology of the samples has been evidenced and is built up of agglomerated nanocrystallites with a size in the range of about 26-36 nm. The presence of two-magnon contribution in Raman scattering spectra suggests the existence of antiferromagnetic ordering at room temperature. Finally, the observed near-infrared photoluminescence band at 850 nm has been …
The use of simulation methods to obtain the structure and conformation of 10-cyano-9,9′-bianthryl by electron diffraction and high-resolution imaging
1995
Abstract Experimental electron diffraction patterns and high-resolution images were used to determine the space group and unit cell dimensions of 10-cyano-9,9′-bianthryl. Subsequently the molecular conformation was calculated by semi-empirical quantum-mechanical methods. The molecule was then placed with the appropriate symmetry into the unit cell and the conformational as well as the packing energy deduced by an iterative procedure until good agreement was obtained between experiment and theory.
Anomalous pressure dependence of the Lamb-Mössbauerf-factor in the spin crossover system [Fe(2-pic-ND2)3]Cl2·EtOD
1987
The pressure dependence of the Lamb-Mossbauer factor of the spin crossover compound [Fe(2-pic-ND2)3]Cl2·EtOD(2-pic-ND2=2-picolylamine, deuterated at the−NH2 group) has been measured at pressures up to 1500 bar and at three temperatures (115.7, 146.7, 185.6 K) around the transition temperatureT t=135 K. The temperature dependence of the unit cell volume has been determined by X-ray diffraction. In the transition region (T=146.7 K), the pressure dependence of thef-factor shows an anomalous increase as compared to the dependence below and above the transition. The behaviour off(p, T), its anomaly and absolute value, can be consistently explained within a theoretical model which treats the comp…
New rotational levels in $^{186}$Re nucleus
2020
International audience; Excited levels of 186 Re have been studied using results of the single γ -ray spectra measurements following the thermal neutron capture reaction. Energies and intensities of more than 500 γ -transitions have been obtained with the high-resolution crystal diffraction spectrometer GAMS5 of ILL. Most of the obtained intense γ -transitions have been placed in the 186 Re level scheme. A number of new levels, as well as the depopulation for levels observed earlier in the 187 Re (p,d)186 Re reaction measurements have been proposed. Structure of 186 Re levels is interpreted in terms of two-quasiparticle plus rotor coupling model and compared with that of the neighbouring do…
Versuche zur Lichtbeugung an Ultraschall in Quarz
1967
Diffraction of a continuous laser beam (He-Ne) by standing ultrasonic waves of 260 Mcs/s in quartz has been investigated. Besides the principal maximum at exact Bragg-incidence, the variation of intensity of first order diffraction pattern with tilt angle shows up to 15 secondary maxima. The effective depth of sound field and the maximum variation of refractive index were determined by comparison with the theory ofBhatia andNoble.
Simultaneous IR and time-resolved X-ray diffraction measurements for studying self-sustained reactions.
1998
Self-propagating high-temperature synthesis provides an attractive practical method for producing advanced materials such as ceramics, composites and intermetallics. This kind of reaction has been investigated in situ using time-resolved X-ray diffraction, with an X-ray synchrotron beam (D43 beamline, LURE, Orsay) coupled to simultaneous IR thermography to study structural transformations and thermal evolution. With short acquisition times (30 ms per pattern) it has been possible to observe several steps before obtaining compounds. Two different compound formations have been described: (i) the different steps of reaction, aluminium melting, subsequent temperature increase and fast reaction …
Time-resolved X-ray powder diffraction on a three-way catalyst at the GILDA beamline
2003
Time-resolved X-ray diffraction experiments carried out at the beamline BM08-GILDA of ESRF allowed a study of the structural modifications taking place in a Pt/ceria-zirconia catalyst while the CO oxidation reaction was in progress. The capillary tube in which the sample is stored acts effectively as a chemical microreactor that ensures homogeneity of the sample treatments and minimization of diffusion effects. During the flowing of the reactant CO/He mixture, the investigated catalyst undergoes a fast Ce(IV)-Ce(III) partial reduction that involves the release of one O atom for every two reduced Ce cations. Because Ce(III) has a larger ionic radius than Ce(IV), the structural modification p…
Effect of gamma radiation on thermostimulated exoelectron emission from Gd2O3 films
2020
Abstract The effect of gamma irradiation on Gd2O3 films was studied using the thermostimulated exoelectron emission (TSEE) technique. The films were deposited on a glass and Si/SiO2 substrates using an extraction-pyrolytic method. Crystalline structure, chemical composition, film thickness and surface morphology were characterized by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The films were irradiated by 10 MeV gamma photons and TSEE was measured from the irradiated films. It was found that gamma irradiation decreases TSEE intensity and the area below TSEE spectral curves. A linear correlati…
X-ray study of the light-induced metastable state of a spin-crossover compound
2000
Iron(II) complexes exhibiting thermal spin crossover may be converted from the1A1low-spin (LS) state to the5T2high-spin (HS) state by irradiation with green light (light-induced excited spin-state trapping, LIESST). The lifetime of the metastable LIESST state may be sufficiently long for X-ray diffraction study. The lattice parameters of a single crystal of [Fe(ptz)6](BF4)2(ptz = propyltetrazole) were measured between 300 and 10 K, while the crystal changed from the HS to the LS state near 135 K. Using the green light (514 nm) of an argon-ion laser, the crystal was quantitatively converted to the metastable LIESST state at 10 K; its lattice parameters were measured up to 50 K, at which poin…
Levels of 188Re nucleus populated in thermal neutron capture reaction
2016
Abstract Levels of 188 Re populated in thermal neutron capture reaction with enriched 187 Re targets have been studied. Single γ -ray spectrum of 188 Re, measured with the high-resolution crystal diffraction spectrometer GAMS5, as well as γγ -coincidence experiments performed with high efficiency Ge detectors, allowed to develop model-independent level scheme of the doubly-odd 188 Re nucleus up to ∼ 1.5 MeV excitation energy. Analysis of the established 188 Re level scheme in terms of the quasiparticle-plus-rotor model indicates coexistence of axially-deformed and triaxial structures in the energy range above 400 keV.