Search results for "Diss"
showing 10 items of 2500 documents
Multicollision-induced dissociation of multiply charged gold clusters, Aun2+, n = 7–35, and Aun3+, n = 19–35
2000
Abstract Multicollision-induced dissociation (MCID) has been applied to gold clusters, Au n 2+ (n = 7–35) and Au n 3+ (n = 19–35) stored in a Penning trap. By application of ion cyclotron resonance excitation and pulses of argon collision gas, fragmentation yields have been measured as a function of the clusters’ kinetic energy. The corresponding dissociation energies have been determined by use of the impulsive collision theory and the quantum Rice–Ramsperger–Kassel (RRK) model for the energy transfer to internal cluster modes and for delayed dissociation, respectively. As compared to earlier measurements of singly charged gold clusters the variation of the stability as a function of clust…
Studies in organic mass spectrometry. Part 17—Formation of phenol radical ions by rearrangement of the molecular ions of someN-arylthiophenecarboxami…
1995
It has been shown by exact mass measurements and collision-induced dissociation mass-analysed ion kinetic energy spectra that the structure of the m/z 124 ion observed in the mass spectra of N-(4-methoxyphenyl)thiophene-2-carboxamide, N-(4-methoxyphenyl)thiophene-3-carboxamide, N-(4-methoxyphenyl)-5-nitrothiophene-3-carboxamide and N-(4-methoxyphenyl)benzamide is identical with that of the molecular ion of 4-methoxyphenol. This ion becomes abundant in metastable energy window reactions. A probable mechanism for its formation is discussed.
Unveiling anion-induced folding in tripodal imidazolium receptors by ion-mobility mass spectrometry.
2021
The anion-induced folding of tripodal imidazolium receptors has been investigated by NMR spectroscopy, electrospray ionization ion mobility mass spectrometry and DFT calculations. Such folding can be switched by anion release upon collision induced dissociation.
Dissipative operators and differential equations on Banach spaces
1991
If we consider the initial value problem Inline Equation $$x'(t) = f(t,x(t)),{\text{ }}x(0) = {x_0}$$ on the real line, it is well known that one—sided bounds like Inline Equation $$\left[ {f(t,x) - f\left( {t,y} \right)} \right]\left( {x - {\text{y}}} \right) \leqslant \omega {\left( {x - y} \right)^2}$$ give much better information about the behaviour of solutions than the Lipschitz- type estimates Inline Equation $$ \left| {f\left( {t,x} \right) - f\left( {t,y} \right)} \right| \leqslant L\left| {x - y} \right|,$$ because ω, unlike L, may be negative.
A cross-cultural analysis of organizational dissent and workplace freedom in five European economies.
2014
Individuals in five European countries—Finland, France, Germany, Spain, and the United Kingdom (n = 1184)—completed a survey exploring the relationship between organizational dissent and workplace freedom of speech. Results revealed workplace freedom of speech is positively correlated with dissent among the entire sample in France and in Germany. Results in Spain were nonsignificant. In the United Kingdom, there was a negative relationship between workplace freedom of speech and dissent. There was a negative relationship between workplace freedom of speech and articulated dissent and a positive relationship with latent dissent in Finland. Moreover, MANCOVA testing showed nationality to have…
Mode of interaction of different polyanions with the first (), the second (C2) and the fourth (C4) component of complement—II
1976
Abstract Dextran sulfate, polyvinyl sulfate, liquoid, heparin and Sp 54, ∗ (a pentosanpoly-sulfoester) prevented the uptake of C2 by EAC4b. In contrast to EAC 4 b 2 a , treatment of EAC4b2 with polyanions led to dissociation into EAC4b and C2. The inhibition of C2 uptake by polyanions could be reduced by increasing magnesium concentration to levels which are normally inhibitory, suggesting that Mg ++ ions are sequestered by these sulfated polyanions.
Completeness and timeliness: Cancer registries could/should improve their performance.
2015
Abstract Cancer registries must provide complete and reliable incidence information with the shortest possible delay for use in studies such as comparability, clustering, cancer in the elderly and adequacy of cancer surveillance. Methods of varying complexity are available to registries for monitoring completeness and timeliness. We wished to know which methods are currently in use among cancer registries, and to compare the results of our findings to those of a survey carried out in 2006. Methods In the framework of the EUROCOURSE project, and to prepare cancer registries for participation in the ERA-net scheme, we launched a survey on the methods used to assess completeness, and also on t…
Numerical and Experimental Analysis of the Frictional Effects on 4ENF Delamination Tests Performed on Unidirectional CFRP
2015
Abstract Progressive delamination in composite materials under static or fatigue loading condition are, in many structures, one of the predominant cause of failure. In the paper, an accurate study of quasi-static delamination growth under mode II loading condition is conducted. Several experimental tests are performed on composite laminates consisting of unidirectional carbon/epoxy layers. Four-point end-notched flexure (4ENF) test is employed in order to characterize the mode II interlaminar fracture toughness. The R-curve is obtained by means of optical and numerical determination of crack tip position. The energy release rate and the crack length are calculated through experimental deter…
The effect of geometrical parameters on the discharge capacity of meandering compound channels
2008
A number of methods and formulae has been proposed in the literature to estimate the discharge capacity of compound channels. When the main channel has a meandering pattern, a reduction in the conveyance capacity for a given stage is observed, which is due to the energy dissipations caused by the development of strong secondary currents and to the decrease of the main channel bed slope with respect to the valley bed slope. The discharges in meandering compound channels are usually assessed applying, with some adjustments, the same methods used in the straight compound channels. Specifically, the sinuosity of the main channel is frequently introduced to account for its meandering pattern, al…
The partition sum of methane at high temperature
2008
11 pages, 4 Tables, 3 Figures Computer code on line at http://icb.u-bourgogne.fr/JSP/TIPS.jsp; International audience; The total internal partition function of methane is revisited to provide reliable values at high temperature. A multi-resolution approach is used to perform a direct summation over all the rovibrational energy levels up to the dissociation limit. A computer code is executable on line at the URL : http://icb.u-bourgogne.fr/JSP/TIPS.jsp to allow the calculation of the partition sum of methane at temperatures up to 3000 K. It also provides detailed information on the density of states in the relevant spectral ranges. The recommended values include uncertainty estimates. It is …