Search results for "Dopant"
showing 10 items of 162 documents
Influence of annealing conditions on the photoelectrocatalytic performance of WO3 nanostructures
2020
[EN] Nanostructured WO3 photoanodes have been synthesized by electrochemical anodization under controlled hydrodynamic conditions in acidic media in the presence of 0.05 M H2O2. Subsequently, samples have been subjected to a thermal treatment (annealing) at different temperatures (400 degrees C, 500 degrees C and 600 degrees C) and under different gaseous atmospheres (air, N-2, Ar). The influence of these annealing conditions on the morphology, crystallinity, photoelectrochemical behavior and dopant chemistry of the different photoanodes has been investigated through Electronic Microscopy, Raman Spectroscopy, Photoelectrochemical Impedance Spectroscopy and Mott-Schottky analysis. In general…
Time-Dependent Density Functional Theory Calculations of N- and S-Doped TiO2 Nanotube for Water-Splitting Applications
2021
This research was funded by the Latvian Council of Science grant LZP-2018/2-0083. Institute of Solid State Physics, University of Latvia, as the Center of Excellence, has received funding from the European Union?s Horizon 2020 Framework Program H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under Grant Agreement No. 739508, project CAMART2.
Ab initio calculations of doped TiO2 anatase (101) nanotubes for photocatalytical water splitting applications
2016
Abstract TiO 2 (titania) is one of the promising materials for photocatalytic applications. In this paper we report on recently obtained theoretical results for N and S doped, as well as N+S co-doped 6-layer (101) anatase nanotube (NT). First principles calculations in our study have been performed using a modified B3LYP hybrid exchange-correlation functional within density functional theory (DFT). Here we discuss the energy of defect formation mechanism and electronic band structure for nanotubes under study. We also report on influence of dopant concentration on the NT's band structure and discuss the defect–defect interactions.
First principles modeling of 3d-metal doped three-layer fluorite-structured TiO2 (4,4) nanotube to be used for photocatalytic hydrogen production
2017
This study has been supported by the EC ERA.Net RUS Plus project No. 237 WATERSPLIT, Russian Basic Research Foundation No. 16-53-76019, and additionally by the IMIS2 Program (Latvia). The authors are also indebted to R. A. Evarestov and O. Lisovski for stimulating discussions as well as to A. Chesnokov for technical assistance.
Transient Radiation Responses of Optical Fibers: Influence of MCVD Process Parameters
2012
International audience; A dedicated set of fibers elaborated via the Modified Chemical Vapor Deposition (MCVD) technique is used to study the influence of composition and drawing parameters on their responses to an X-ray pulse representative of the radiation environments associated with Megajoule class lasers. These canonical fibers were designed to highlight the impact of these parameters on the amplitude and kinetics of the transient pulsed X-ray Radiation Induced Attenuation (RIA) at room temperature. From preforms differing by their core composition, three optical fibers were elaborated by varying the tension and speed during the drawing process. No or only slight RIA change results fro…
Optical storage in doped microstructures of alkali halides
2002
Peculiarities of colour centres production and their recombination in photostimulated processes in doped alkali halide microstructures were examined in connection with their practical use as active photostimulable media in miniaturised optoelectronic and photonic devices. The specific interaction of unrelaxed H-centres and electrons with the dopants in different valence and electronic states open a way for widening the scope of multifunctional (logical and mathematical) optical data processing and transfer.
Light absorption and conversion in solar cell based on Si:O alloy
2013
Thin film Si:O alloys have been grown by plasma enhanced chemical vapor deposition, as intrinsic or highly doped (1 to 5 at. % of B or P dopant) layers. UV-visible/near-infrared spectroscopy revealed a great dependence of the absorption coefficient and of the optical gap (Eg) on the dopant type and concentration, as Eg decreases from 2.1 to 1.9 eV, for the intrinsic or highly p-doped sample, respectively. Thermal annealing up to 400 °C induces a huge H out-diffusion which causes a dramatic absorption increase and a reduction of Eg, down to less than 1.8 eV. A prototypal solar cell has been fabricated using a 400 nm thick, p-i-n structure made of Si:O alloy embedded within flat transparent c…
Recent Developments in Cladding-Pumped Doped Fiber Amplifiers for Telecommunications Systems
2020
This paper aims to review recent developments in the field of doped fiber-based optical amplifiers and serve as a reference for promising optical signal amplification techniques that may be useful for practical implementation in high-capacity and cost-efficient telecommunications systems. The main focus is put on different rare-earth dopant elements, double-clad fibers, and optical couplers for cladding-pumping technique. It is found that codoped double-clad fiber-based amplifiers currently have attained the main research interest and show possible application also in multichannel fiber optical transmission systems. Additionally, we have compared different free space and waveguide construct…
All-Optical Tuning of WGMs in Microspheres Made of Er/Yb Codoped Optical Fiber
2014
All-optical, pump-assisted, thermal tuning of high-Q whispering-gallery mode (WGM) resonances of microspheres is demonstrated. The microspheres were made of an Er/Yb codoped single-mode silica optical fiber. The pump light absorbed by the active ions heats the microsphere, which leads to the shift of the resonances. A tuning range in excess of 2 nm in the C-band is achieved. The presence of active ions is restricted to the core of the microsphere. The WGM fields, which are confined in a region close to the surface of the microsphere, do not overlap with the dopant. Thus, high-Q resonances (>10 7 ) are achieved, as in pure silica microspheres, even at optical wavelengths within the absorptio…
Sputtered cuprous oxide thin films and nitrogen doping by ion implantation
2016
Abstract The structural, optical and electrical properties of sputtered cuprous oxide thin films have been optimized through post-deposition thermal treatments. Moreover we have studied the effects of nitrogen doping introduced by ion implantation followed by the optimized oxidant thermal annealing. Three concentrations have been used, 0.6 N%, 1.2 N%, and 2.5 N%. Along with the preservation of the Cu 2 O phase, a slight optical band gap narrowing and a significant conductivity enhancement has been observed with respect to the undoped samples. These results can be justified by the absence of further oxygen vacancies promoted by dopant introduction and by the substitution of O atoms by N ones…