Search results for "Engineering sciences"
showing 10 items of 2347 documents
An experimental and modeling study of the oxidation of 3-pentanol at high pressure
2019
International audience; High pressure oxidation of 3-pentanol is investigated in a jet-stirred reactor and in a shock tube. Experiments in the reactor were carried out at 10 atm, between 730 and 1180 K, for equivalence ratios of 0.35, 0.5, 1, 2, 4 and 1000 ppm fuel, at a constant residence time of 0.7 s. Reactant, product and intermediate species mole fractions were recorded using Fourier transform infrared spectroscopy (FTIR) and gas chromatography (GC). Ignition delay times were measured for 3-pentanol/O2 mixtures in argon in a shock tube at 20 and 40 bar, in a temperature range of 1000–1470 K and for equivalence ratios of 0.5, 1 and 2. The fuel did not show any low-temperature reactivity…
Agent-based model for the rescheduling of Individual and collective daily activities under uncertainties
2020
Daily activity schedule are popular for people duringdaily life. While, when executing the schedule on the real road network, there are always some disruptions disturbing the planned schedule. To deal with this problem, daily activity rescheduling is necessary. This thesis regards the disruptions from the activity schedule execution environment as unexpected events (uncertainties). It establishes agent-based models to simulate the activity rescheduling decision process from the aspects of individual activity rescheduling and joint trip renegotiating.For the individual activity rescheduling, the model in this thesis wants to explore the relationship between a pair of episodes (two connected …
Inducing Strong Non-Linearities in a Phonon Trapping Quartz Bulk Acoustic Wave Resonator Coupled to a Superconducting Quantum Interference Device
2018
International audience; A quartz Bulk Acoustic Wave resonator is designed to coherently trap phonons in such a way that they are well confined and immune to suspension losses so they exhibit extremely high acoustic Q-factors at low temperature, with Q × f products of order 10¹⁸ Hz. In this work we couple such a resonator to a Superconducting Quantum Interference Device (SQUID) amplifier and investigate effects in the strong signal regime. Both parallel and series connection topologies of the system are investigated. The study reveals significant non-Duffing response that is associated with the nonlinear characteristics of Josephson junctions. The nonlinearity provides quasi-periodic structu…
Formation Kinetics of Mixed Self-Assembled Monolayers of Alkanethiols on GaAs(100)
2017
International audience; We report on the formation kinetics of mixed self-assembled monolayers (SAMs) comprising 16-mercaptohexadecanoic acid (MHDA) and 11-mercapto-1-undecanol (MUDO) thiols on GaAs(100) substrates. These compounds were selected for their potential in constructing highly selective and efficient architectures for biosensing applications. The molecular composition and quality of one-compound and mixed SAMs were determined by the Fourier transform infrared absorption spectroscopy measurements. The formation of enhanced-quality mixed SAMs was investigated as a function of the molecular composition of the thiol mixture and the proportion of ethanol/water solvent used during thei…
Analysis of nonlinear coupling on the behavior of the sine-Gordon and Klein-Gordon models in bandwidth and forbidden bands
2017
In this thesis, we analyze the conditions of existence of the phenomenon of nonlinear supratransmission in two different models: a modified fifth-order Klein-Gordon system and a modified sine-Gordon system. The modified models considered here are those with mixed coupling, the pure linear coupling being associated with a nonlinear coupling. In particular, we quantify numerically the influence of the non-linear coupling coefficient on the threshold amplitude which triggers the phenomenon of non-linear supratransmission. Our main result shows that in both models, when the nonlinear coupling coefficient increases, the threshold amplitude triggering the phenomenon of nonlinear supratransmission…
Knowledge formalization and recommendation in computational design synthesis for 4D printing
2022
Coined in 2013, 4D printing is considered as a promising technology that combines additive manufacturing (AM) processes and smart materials (SMs). Through this technology objects can change over time in terms of functionalities, shape, or properties under the effect of energy stimulation. Although AM processes allow shape, hierarchical, functional, and materials complexities to the 3D objects, the conjunction with SMs provides much more freedom in designing adaptive/transformative structures. Over the last decade, a growing body of research with ad hoc proofs-of-concept have been proposed at the physical level (i.e., by using different AM processes with commercial or customized 3D printers …
Calibrating the effective scattering albedo in the SMOS algorithm: some first results
2016
International audience; This study focuses on the calibration of the effective scattering albedo (ω) of vegetation in the soil moisture (SM) retrieval at L-Band. Currently, in the SMOS Level 2 and 3 algorithms, the value of ω is set to 0 for low vegetation and ∼ 0.06 – 0.08 for forests. Different parameterizations of vegetation (in terms of ω values) were tested in this study. The possibility of combining soil roughness and vegetation contributions as a single parameter (“combined” method) leads to an important simplification in the algorithm and was also evaluated here. Following these assumptions, retrieved values of SMOS SM were compared with SM data measured over many in situ sites worl…
Analyzing the impact of using the SRP (Simplified roughness parameterization) method on soil moisture retrieval over different regions of the globe
2015
International audience; This paper focuses on a new approach to account for soil roughness effects in the retrieval of soil moisture (SM) at L-band in the framework of the SMOS (Soil Moisture and Ocean Salinity) mission: the Simplified Roughness Parameterization (SRP). While the classical retrieval approach considers SM and τ nad (vegetation optical depth) as retrieved parameters, this approach is based on the retrieval of SM and the TR parameter combining τ nad and soil roughness (TR τ nad + Hr /2). Different roughness parameterizations were tested to find the best correlation (R), bias and unbiased RMSE (ubRMSE) when comparing homogeneous retrievals of SM and in situ SM measurements carri…
Prussian Blue Analogues of Reduced Dimensionality
2012
Abstract: Mixed-valence polycyanides (Prussian Blue analogues) possess a rich palette of properties spanning from room-temperature ferromagnetism to zero thermal expansion, which can be tuned by chemical modifications or the application of external stimuli (temperature, pressure, light irradiation). While molecule-based materials can combine physical and chemical properties associated with molecular-scale building blocks, their successful integration into real devices depends primarily on higher-order properties such as crystal size, shape, morphology, and organization. Herein a study of a new reduced-dimensionality system based on Prussian Blue analogues (PBAs) is presented. The system is …
Measuring the differential scattering cross-section of gold nanoparticles - art. no. 70321E
2008
International audience; In this paper we present an experimental apparatus capable of measuring the differential scattering cross sections of individual nanoparticles and arrangement of nanoparticles. We show that the mapping a partial differential scattering cross section, qualitative information about the electromagnetic local density of states dominated by evanescent modes scattered by the structure can be obtained.