Search results for "General method"

High Yield Syntheses of Stable, Singly Bonded Pd26+ Compounds

2006

A general method for the syntheses of dipalladium compounds having a singly bonded Pd26+ core and the formula R,S-cis-Pd2(C6H4PPh2)2(O2CR)2Cl2 is described. When the alkyl group in the carboxylate ligands is an electron donating group, the compounds are stable and the yields high. The Pd-Pd distances for the diamagnetic compounds with R = CF3 and CMe3 are 2.5434(4) and 2.5241(9) A, respectively. Calculations at the DFT level suggest that the electronic configuration is sigma2pi4delta2delta*2pi*4. These represent rare examples of palladium(III) compounds.

I(py)2BF4, a New Reagent in Organic Synthesis: General Method for the 1,2-Iodofunctionalization of Olefins

1985

Synthesis of Novel Triazolopyridylboronic Acids and Esters. Study of Potential Application to Suzuki-Type Reactions.

2004

This paper describes a general method for the synthesis of novel [1,2,3]triazolo[1,5-a]pyridylboronic acids and esters, and the first results on Suzuki cross-coupling reactions with these new compounds and [1,2,3]triazolo[5,1-a]isoquinolylboronic acid, reacting with a variety of aryl halides as a route to 7-aryltriazolopyridines and 5-aryltriazoloisoquinolines.

Synthesis of a new bridgehead nitrogen heterocyclic system. Pyrrolo [2,1-f]-1,2,4-triazine derivatives

1979

1-Ureidopyrroles of type 6a,b prepared by the general method previously described (2), readily cyclized under basic conditions giving pyrrolo [2,1-f]-1,2,4-triazine-2,4(1H, 3H)dione derivatives.

ChemInform Abstract: Efficient Synthesis of Quaternary and P-Stereogenic Phosphonium Triflates.

2010

An efficient and general method for the preparation of achiral and chiral phosphonium salts is reported. This synthesis is based on the quaternization of phosphines and their derivatives with arynes generated in situ from 2-(trimethylsilyl)aryl triflates. This methodology is successfully applied to the synthesis of new valuable P-stereogenic phosphonium triflates.

Euclid preparation : XXII. Selection of quiescent galaxies from mock photometry using machine learning

2023

The Euclid Space Telescope will provide deep imaging at optical and near-infrared wavelengths, along with slitless near-infrared spectroscopy, across ~15 000deg2 of the sky. Euclid is expected to detect ~12 billion astronomical sources, facilitating new insights into cosmology, galaxy evolution, and various other topics. In order to optimally exploit the expected very large dataset, appropriate methods and software tools need to be developed. Here we present a novel machine-learning-based methodology for the selection of quiescent galaxies using broadband Euclid IE, YE, JE, and HE photometry, in combination with multi-wavelength photometry from other large surveys (e.g. the Rubin LSST). The…