Search results for "I+D+i"
showing 10 items of 26665 documents
Mono-DMSO ligated cobalt nitrophenylcorroles: electrochemical and spectral characterization
2018
Four mono-DMSO ligated cobalt corroles with one or three meso-nitrophenyl substituents on the macrocycle were synthesized and investigated as to their electrochemical and spectroscopic properties in CH2Cl2 and DMSO. Comparisons are made between redox reactions of the five-coordinate DMSO adducts in the current study and earlier examined five- and six-coordinate cobalt corroles with pyridine axial ligands which were characterized in a variety of nonaqueous electrochemical solvents. The binding of carbon monoxide (CO) is also investigated.
Two-photon absorption of BF2-carrying compounds: insights from theory and experiment
2017
This communication presents a structure–property study of a few novel pyridine-based difluoroborate compounds with a N–BF2–O core, which exhibit outstanding fluorescence properties. To exploit their potential for two-photon bioimaging, relationships between the two-photon action cross section and systematic structural modifications have been investigated and unravelled.
Theoretical study on the decomposition mechanism of bisphenol A polycarbonate induced by the combined effect of humidity and UV irradiation.
2020
Polycarbonate (PC) is a good material for covering and protecting cultural heritage sites because of its durability, mechanical properties, and transparency. When bisphenol A polycarbonate is subjected to weathering conditions this polymer shows several degradation processes depending on the irradiation wavelength, humidity and temperature. In particular, the combined effects of humidity and UV irradiation speed up the PC molecular weight reduction. In this work, the decomposition mechanisms associated to the hydrolysis process are scrutinized and the effects of UV irradiation on the hydrolysis process are evaluated throughout the Density Functional Theory (DFT) approach. It was found that …
Influence of Wind on Suspended Matter in the Water of the Albufera of Valencia (Spain)
2021
Wind is one of the factors that has a great influence on suspended matter in lakes, especially in shallow lagoons. In order to know how wind affects the water in Albufera of Valencia, a shallow coastal lagoon, the measured variables of turbidity and transparency have been correlated with the estimates by processing Sentinel-2 satellite images with the Sen2Cor processor. Data from four years of study show that most of them are light to gentle easterly breezes and moderate to fresh westerly breezes. The results obtained show significant correlations between the measured variables and those obtained from the satellite images for total suspended matter and water transparency and with the averag…
Analysis of directional effects on atmospheric correction
2013
Abstract Atmospheric correction in the Visible and Near Infrared (VNIR) spectral range of remotely sensed data is significantly simplified if we assume a Lambertian target. However, natural surfaces are anisotropic. Therefore, this assumption will introduce an error in surface directional reflectance estimates and consequently in the estimation of vegetation indexes such as the Normalized Difference Vegetation Index (NDVI) and the surface albedo retrieval. In this paper we evaluate the influence of directional effects on the atmospheric correction and its impact in the NDVI and albedo estimation. First, we derived the NDVI and surface albedo from data corrected assuming a Lambertian surface…
Record-breaking warming and extreme drought in the Amazon rainforest during the course of El Niño 2015–2016
2016
AbstractThe El Niño-Southern Oscillation (ENSO) is the main driver of interannual climate extremes in Amazonia and other tropical regions. The current 2015/2016 EN event was expected to be as strong as the EN of the century in 1997/98, with extreme heat and drought over most of Amazonian rainforests. Here we show that this protracted EN event, combined with the regional warming trend, was associated with unprecedented warming and a larger extent of extreme drought in Amazonia compared to the earlier strong EN events in 1982/83 and 1997/98. Typical EN-like drought conditions were observed only in eastern Amazonia, whilst in western Amazonia there was an unusual wetting. We attribute this wet…
Land Use Affects Carbon Sources to the Pelagic Food Web in a Small Boreal Lake
2016
Small humic forest lakes often have high contributions of methane-derived carbon in their food webs but little is known about the temporal stability of this carbon pathway and how it responds to environmental changes on longer time scales. We reconstructed past variations in the contribution of methanogenic carbon in the pelagic food web of a small boreal lake in Finland by analyzing the stable carbon isotopic composition (δ13C values) of chitinous fossils of planktivorous invertebrates in sediments from the lake. The δ13C values of zooplankton remains show several marked shifts (approx. 10 ‰), consistent with changes in the proportional contribution of carbon from methane-oxidizing bacteri…
A record of seafloor methane seepage across the last 150 million years
2020
<p>Methane seepage at the seafloor is a source of carbon in the marine environment and has long been recognized as an important window into the deep geo-, hydro-, and bio-spheres. However, the processes and temporal patterns of natural methane emission over multi-million-year time scales are still poorly understood. The microbially-mediated methane oxidation leads to the precipitation of authigenic carbonate minerals within subseafloor sediments, thus providing a potentially extensive record of past methane emission. In this study, we used data on methane-derived authigenic carbonates to build a proxy time series of seafloor methane emission over the last 150 My. We quantitat…
Ocean Acidification and the End-Permian Mass Extinction: To What Extent does Evidence Support Hypothesis?
2012
International audience; Ocean acidification in modern oceans is linked to rapid increase in atmospheric CO 2 , raising concern about marine diversity, food security and ecosystem services. Proxy evidence for acidification during past crises may help predict future change, but three issues limit confidence of comparisons between modern and ancient ocean acidification, illustrated from the end-Permian extinction, 252 million years ago: (1) problems with evidence for ocean acidification preserved in sedimentary rocks, where proposed marine dissolution surfaces may be subaerial. Sedimentary evidence that the extinction was partly due to ocean acidification is therefore inconclusive; (2) Fossils…
Understanding deep learning in land use classification based on Sentinel-2 time series
2020
AbstractThe use of deep learning (DL) approaches for the analysis of remote sensing (RS) data is rapidly increasing. DL techniques have provided excellent results in applications ranging from parameter estimation to image classification and anomaly detection. Although the vast majority of studies report precision indicators, there is a lack of studies dealing with the interpretability of the predictions. This shortcoming hampers a wider adoption of DL approaches by a wider users community, as model’s decisions are not accountable. In applications that involve the management of public budgets or policy compliance, a better interpretability of predictions is strictly required. This work aims …