Search results for "Isotropy"
showing 10 items of 1099 documents
Local structure of copper nitride revealed by EXAFS spectroscopy and a reverse Monte Carlo/evolutionary algorithm approach
2016
Physica scripta 91(5), 054003 (2016). doi:10.1088/0031-8949/91/5/054003
Molecular dynamics and reverse Monte Carlo modeling of scheelite-type AWO4(A = Ca, Sr, Ba) WL3-edge EXAFS spectra
2016
Classical molecular dynamics (MD) and reverse Monte Carlo methods coupled with ab initio multiple-scattering extended x-ray absorption fine structure (EXAFS) calculations were used for modeling of scheelite-type AWO4 (A = Ca, Sr, Ba) W L 3-edge EXAFS spectra. The two theoretical approaches are complementary and allowed us to perform analysis of full EXAFS spectra. Both methods reproduce well the structure and dynamics of tungstates in the outer coordination shells, however the classical MD simulations underestimate the W–O bond MSRD due to a neglect of quantum zero-point-motion. The thermal vibration amplitudes, correlation effects and anisotropy of the tungstate structure were also estimat…
Elastoplastic Damaging Model for Adhesive Anchor Systems. I: Theoretical Formulation and Numerical Implementation
2011
In this and in the companion paper, the mechanical response of adhesive anchor systems is theoretically and numerically predicted and experimentally observed. The theoretical prediction is on the basis of an elastoplastic damaging model formulated to predict the structural response associated with the development of a fracture in adhesive anchor systems. This part describes the analytical model developed in the framework of a thermodynamically consistent theory, which assumes adhesion where the structure is sound, and friction in correspondence with the fracture. Isotropic damage is considered. The model can predict the structural behavior at the interface between two surfaces of ductile, b…
Magnetic resonance study of bulk and thin film EuTiO3
2017
Magnetic resonance spectra of EuTiO3 in both bulk and thin film form were taken at temperatures from 3-350 K and microwave frequencies from 9.2-9.8 and 34 GHz. In the paramagnetic phase, magnetic resonance spectra are determined by magnetic dipole and exchange interactions between Eu2+ spins. In the film, a large contribution arises from the demagnetization field. From detailed analysis of the linewidth and its temperature dependence, the parameters of spin-spin interactions were determined: the exchange frequency is 15-15.5 GHz and the estimated critical exponent of the spin correlation length is ~ 0.5. In the bulk samples, the spectra exhibited a distinct minimum in the linewidth at the N…
Optimal ferromagnetically-coated carbon nanotube tips for ultra-high resolution magnetic force microscopy
2013
Using single-walled carbon nanotubes homogeneously coated with ferromagnetic metal as ultra-high resolution magnetic force microscopy probes, we investigate the key image formation parameters and their dependence on coating thickness. The crucial step of introducing molecular beam epitaxy for deposition of the magnetic coating allows highly controlled fabrication of tips with small magnetic volume, while retaining high magnetic anisotropy and prolonged lifetime characteristics. Calculating the interaction between the tips and a magnetic sample, including hitherto neglected thermal noise effects, we show that optimal imaging is achieved for a finite, intermediate-thickness magnetic coating, …
Elastomeric Electrospun Polyurethane Scaffolds: The Interrelationship Between Fabrication Conditions, Fiber Topology, and Mechanical Properties
2010
Electrospinning has been gaining increasing popularity in the fabrication of engineered tissue scaffolds due to its ability to produce nano to micro scale fibrous sheets. Many investigators have attempted to apply various degrees of control to this process in order to produce fiber meshes with more predictable patterns. These attempts have largely been limited to controlling fiber alignment and have fallen into two categories: physical manipulation of the fibers by pulling them into alignment using a rapidly spinning mandrel[1–3] or manipulation of the electric field during fabrication.[4, 5]
Orientational dynamics of colloidal ribbons self-assembled from microscopic magnetic ellipsoids
2016
We combine experiments and theory to investigate the orientational dynamics of dipolar ellipsoids, which self-assemble into elongated ribbon-like structures due to the presence of a permanent magnetic moment, perpendicular to the long axis in each particle. Monodisperse hematite ellipsoids are synthesized via the sol-gel technique and arrange into ribbons in the presence of static or time-dependent magnetic fields. We find that under an oscillating field, the ribbons reorient perpendicular to the field direction, in contrast with the behaviour observed under a static field. This observation is explained theoretically by treating a chain of interacting ellipsoids as a single particle with or…
Osmotic compression of droplets of hard rods: a computer simulation study
2009
By means of computer simulations, we study how droplets of hard, rodlike particles optimize their shape and internal structure under the influence of the osmotic compression caused by the presence of spherical particles that act as depletion agents. At sufficiently high osmotic pressures, the rods that make up the drops spontaneously align to turn them into uniaxial nematic liquid-crystalline droplets. The nematic droplets or "tactoids" that are formed this way are not spherical but elongated, resulting from the competition between the anisotropic surface tension and the elastic deformation of the director field. In agreement with recent theoretical predictions, we find that sufficiently sm…
Nonstationary heat conduction in a stator
1996
In this chapter we describe a method for computing the 3d nonstationary temperature field in the lamination pack of a stator of a synchronous or asynchronous (induction) motor with a centrifugal, meander or chamber ventilation (see [Křižek, Preiningerova]). The stator of a motor has quite a complicated geometrical form. Moreover, it consists of anisotropic materials which have very different heat conductivities, e.g., 332.8 [W/mK] for copper wires and 0.2 [W/mK] for their insulations. This causes big jumps in coefficients of the appropriate heat conduction equation, and is the main source of numerical difficulties in practical calculations.
Finite-size effects on liquid-solid phase coexistence and the estimation of crystal nucleation barriers.
2015
A fluid in equilibrium in a finite volume $V$ with particle number $N$ at a density $\rho = N/V$ exceeding the onset density $\rho_f $ of freezing may exhibit phase coexistence between a crystalline nucleus and surrounding fluid. Using a method suitable for the estimation of the chemical potential of dense fluids we obtain the excess free energy due to the surface of the crystalline nucleus. There is neither a need to precisely locate the interface nor to compute the (anisotropic) interfacial tension. As a test case, a soft version of the Asakura-Oosawa model for colloid polymer-mixtures is treated. While our analysis is appropriate for crystal nuclei of arbitrary shape, we find the nucleat…