Search results for "Mass spectrum"
showing 10 items of 302 documents
Chromatographic and mass spectrometric characteristics of 20-dihydroaldosterone.
1992
The 20 alpha-reduced derivative of aldosterone, 20 alpha-dihydroaldosterone, was needed as reference compound in order to continue the studies on 18-hydroxylation in the Y-1 adrenal cell line. It was obtained by reduction of aldosterone with sodium borohydride. Analysis of the products of the reaction as methoxime trimethylsilyl (MO-TMS) derivatives by gas chromatography (GC) and GC-mass spectrometry (GC-MS) showed three possible forms of the compound. Their identification was confirmed by comparison with the products obtained by stereospecific reduction of aldosterone using 3 alpha,20 beta-hydroxysteroid dehydrogenase. Chromatographic behavior and mass spectra are given for the three forms…
Entzündungshemmende Wirkstoffe, 10. Mitt.1). 1-(4-Chlorphenyl)-2-pyrazolin-5-on-Derivate
1986
Aus der durch s-Triazin (1) initiierten Aminomethinylierung des 1-(4-Chlorphenyl)-3-methyl-2-pyrazolin-5-ons (2) geht das 4-Aminomethylen-1(4-chlorphenyl)-3-methyl-2-pyrazolin-5-on (4) hervor, das einerseits zur C-Rubazonsaure 5, andererseits in Gegenwart sekundarer Amine 6 zu den Dehydro-C-Mannich-Basen 7 weiterreagieren kann. Antiinflammatory Agents, X: 1-(4-Chlorophenyl)-2-pyrazolin-5-one Derivatives Aminomethynylation of 1-(4-chlorophenyl)-3-methyl-2-pyrazolin-5-one (2) initiated by s-triazine (1) yields 4-aminomethylene-1-(4-chlorophenyl)-3-methyl-2-pyrazolin-5-one (4). This, in turn, may form the C-rubazonic acid 5 or, in the presence of secondary amines 6, the dehydro-C-Mannich bases…
Expressing forest origins in the chemical composition of cooperage oak woods and corresponding wines by using FTICR-MS.
2008
A non-targeted, ultra-high-resolution mass spectrometric, direct analysis of oak-wood extracts from two species (Quercus robur L. and Quercus petraea Liebl.) from three French forests, and of a wine aged in barrels derived therefrom has been performed to identify families of metabolites that could discriminate both the species and the geographical origin of woods. From 12 T ultra-high-resolution Fourier transform ion cyclotron resonance mass spectra of wood extracts, hundreds of mass signals were identified as possible significant biomarkers of the two species, with phenolic and carbohydrate moieties leading the differentiation between Q. robur and Q. petraea, respectively, as corroborated …
The two-photon decay of X(6900) from light-by-light scattering at the LHC
2022
The LHCb Collaboration has recently discovered a structure around 6.9 GeV in the double-$J/\psi$ mass distribution, possibly a first fully-charmed tetraquark state $X(6900)$. Based on vector-meson dominance (VMD) such a state should have a significant branching ratio for decaying into two photons. We show that the recorded LHC data for the light-by-light scattering may indeed accommodate for such a state, with a $\gamma \gamma$ branching ratio of order of $10^{-4}$, which is larger even than the value inferred by the VMD. The spin-parity assignment $0^{-+}$ is in better agreement with the VMD prediction than $0^{++}$, albeit not significantly at the current precision. Further light-by-light…
Identification of volatile compounds of fruit juice by head space (HSSE) and immersion stir bar sorptive extraction (SBSE) and thermal desorption-cry…
2015
Identification of volatile compounds of fruit juice by head space (HSSE) and immersion stir bar sorptive extraction (SBSE) and thermal desorption-cryogenic focusing-gas chromatography mass spectrometry. 16. International Symposium on Olfaction and Electronic Noses (ISOEN 2015)
Gas sensors arrays (electronic noses) : a study about the speed/accuracy ratio
2000
Abstract New Fingerprint Mass Spectra (FMS) systems claim for a higher precision, a reduced analysis time, and a lower drift, compared with Gas Sensors Arrays ‘Electronic Noses’. We demonstrated in this study that metal oxide gas sensors may have highly improved performances for both accuracy and run time, when used in optimum conditions. The different noise components were quantified referring to popular words (equivalent of ethanol concentration) using the transfer function of the sensor. It was pointed out that sample surrounding greatly affects the noise level, and that the signal-to-noise ratio may be dramatically increased, reducing the distortion generally assessed between sensor and…
Observation of Higgs boson production in association with a top quark pair at the LHC with the ATLAS detector
2018
Physics letters / B 784, 173 - 191 (2018). doi:10.1016/j.physletb.2018.07.035
Measurement of light-by-light scattering and search for axion-like particles with 2.2 nb−1 of Pb+Pb data with the ATLAS detector
2021
We thank CERN for the very successful operation of the LHC, as well as the support staff from our institutions without whom ATLAS could not be operated efficiently. We acknowledge the support of ANPCyT, Argentina; YerPhI, Armenia; ARC, Australia; BMWFW and FWF, Austria; ANAS, Azerbaijan; SSTC, Belarus; CNPq and FAPESP, Brazil; NSERC, NRC and CFI, Canada; CERN; ANID, Chile; CAS, MOST and NSFC, China; COLCIENCIAS, Colombia; MSMT CR, MPO CR and VSC CR, Czech Republic; DNRF and DNSRC, Denmark; IN2P3-CNRS and CEA-DRF/IRFU, France; SRNSFG, Georgia; BMBF, HGF and MPG, Germany; GSRT, Greece; RGC and Hong Kong SAR, China; ISF and Benoziyo Center, Israel; INFN, Italy; MEXT and JSPS, Japan; CNRST, Mor…
New Porphycene Ligands: Octaethyl- and Etioporphycene(OEPc and EtioPc)—Tetra- and Pentacoordinated Zinc Complexes of OEPc
1993
One-step synthesis of resorcarene dimers composed of two tetra-benzoxazine units
1998
Abstract The condensation of resorcarene 1 with ethylenediamine and an excess of formaldehyde gives, under high dilution conditions, in up to 15% yield the octa-benzoxazine dimer 2 in which two molecules of 1 are connected by four bridges. The structure of 2 has been confirmed by 1 H NMR spectra and MALDI-TOF mass spectra and by hydrolysis of the oxazine rings yielding the secondary amine 3 .