Search results for "Metallurgy"
showing 10 items of 1419 documents
Oxidative degradation properties of Co-based catalysts in the presence of ozone
2007
Four series of cobalt-based catalysts, such as bare Co3O4 and CoO, CoOx-CeO2 mixed oxides, CoOx supported over alumina and alumina-baria and CoMgAl and CoNiAl hydrotalcites have been synthesized and investigated for the oxidative degradation of phenol in the presence of ozone. Characterizations were obtained by several techniques in order to investigate the nature of cobalt species and their morphological properties, depending on the system. Analyses by XRD, BET, TPR, UV-visible diffuse reflectance spectroscopy and TG/DT were performed. The CoNiAl hydrotalcite exhibits, after 4 h of reaction, the highest phenol ozonation activity followed by Co(3 wt%)/Al2O3-BaO and CoMgAl. The samples Co(1 …
Control of Oxygen Nonstoichiometry and Magnetic Property of MnCo2O4 Thin Films Grown by Atomic Layer Deposition
2010
Spinel-structured (Mn,Co)3O4 thin films were reproducibly fabricated by atomic layer deposition (ALD) using Mn(thd)3, Co(thd)2, and ozone as precursors. A full control of the cation ratio was achieved in the temperature interval 140−160 °C within which also the growth rate remained constant. Precise control of the oxygen content of as-deposited MnCo2O4+δ films was achieved through postdeposition heat treatments at prefixed temperatures in air and N2 atmospheres, as evidenced from the monotonous increases of both the unit cell volume and the Curie temperature (TC) with increasing annealing temperature/decreasing oxygen partial pressure. The TC value varied from 92 K for the as-deposited MnCo…
Effect of ozone concentration on silicon surface passivation by atomic layer deposited Al2O3
2015
Abstract We study the impact of ozone-based Al2O3 Atomic Layer Deposition (ALD) on the surface passivation quality of crystalline silicon. We show that the passivation quality strongly depends on the ozone concentration: the higher ozone concentration results in lower interface defect density and thereby improved passivation. In contrast to previous studies, our results reveal that too high interface hydrogen content can be detrimental to the passivation. The interface hydrogen concentration can be optimized by the ozone-based process; however, the use of pure ozone increases the harmful carbon concentration in the film. Here we demonstrate that low carbon and optimal hydrogen concentration…
Effect of Composition on the Photoelectrochemical Behavior of Anodic Oxides on Binary Aluminum Alloys
2006
The photoelectrochemical behavior of anodic films on Al alloys, containing titanium, tantalum, and tungsten (valve metals), has been studied as a function of alloy composition and anodizing conditions. Photocurrent spectroscopy has been used to get information on bandgap and the flatband potential values of different mixed oxides. Both insulator-like and semiconducting behavior has been observed for anodic oxides grown on Al-W and Al-Ti alloys dependent on alloy initial composition. Optical bandgap values, E opt g , of different oxides are in accordance with predictions based on the correlation between E opt g and the difference of electronegativities of the oxide constituents, indicating p…
Formation and evolution of self-organized Au nanorings on indium-tin-oxide surface
2011
This work reports on the formation of Au nanoclusters and on their evolution in nanoring structures on indium-tin-oxide surface by sputtering deposition and annealing processes. The quantification of the characteristics of the nanorings (surface density, depth, height, and width) is performed by atomic force microscopy. The possibility to control these characteristics by tuning annealing temperature and time is demonstrated establishing relations which allow to set the process parameters to obtain nanostructures of desired morphological properties for various technological applications. © 2011 American Institute of Physics.
Multi-PeV Signals from a New Astrophysical Neutrino Flux beyond the Glashow Resonance.
2016
The IceCube neutrino discovery was punctuated by three showers with $E_\nu$ ~ 1-2 PeV. Interest is intense in possible fluxes at higher energies, though a marked deficit of $E_\nu$ ~ 6 PeV Glashow resonance events implies a spectrum that is soft and/or cutoff below ~few PeV. However, IceCube recently reported a through-going track event depositing 2.6 $\pm$ 0.3 PeV. A muon depositing so much energy can imply $E_{\nu_\mu} \gtrsim$ 10 PeV. We show that extending the soft $E_\nu^{-2.6}$ spectral fit from TeV-PeV data is unlikely to yield such an event. Alternatively, a tau can deposit this much energy, though requiring $E_{\nu_\tau}$ ~10x higher. We find that either scenario hints at a new flu…
Analytical study by SEM/EDX and metallographic techniques of materials used in the iron production process during the iberian period
2002
Abstract This work is the archaeometric study of different types of materials used in iron production in the Iberian Period (6th–2nd century b.c.). The materials were recovered in several archaeological digs (which makes it possible to date the archaeological remains) on different sites in the Levante area of the Iberian Peninsula. The samples selected for this study belong to different materials used in the ancient iron production process such as ores, slags, finished objects, etc. The use of scanning electron microscopy (SEM) is proposed to observe surface images of the samples to determine their morphological, microstructural and topographic characteristics to obtain valuable information…
Electrical transport in carbon black-epoxy resin composites at different temperatures
2013
Citation: J. Appl. Phys. 114, 033707 (2013); doi: 10.1063/1.4815870 (Received 3 May 2013; accepted 27 June 2013; published online 17 July 2013) Results of broadband electric/dielectric properties of different surface area—carbon black/epoxy resin composites above the percolation threshold are reported in a wide temperature range (25–500 K). At higher temperatures (above 400 K), the electrical conductivity of composites is governed by electrical transport in polymer matrix and current carriers tunneling from carbon black clusters to polymer matrix. The activation energy of such processes decreases when the carrier concentration increases, i.e., with the increase of carbon black concentration…
Tuning the dielectric properties of hafnium silicate films
2007
The influence of Si concentration in hafnium silicate dielectrics on thermal stability and dielectric permittivity was analyzed. A phase diagram was developed using GIXRD and FTIR measurement. The stabilization of the ''higher-k'' cubic/tetragonal phase for annealing temperatures up to 1000^oC with a steady increase in capacitance was demonstrated for Hf"0"."9"4Si"0"."0"6O"2 films. It was also shown that the stabilization of nano-crystalline Hf"0"."8"0Si"0"."2"0O"2 films can be realized for annealing temperatures up to 900^oC. The influence of TiN electrodes on the dielectric constant and the leakage current characteristic was also investigated. A permittivity increase for annealing tempera…
Uniaxial stress dependence of the dielectric and ferroelectric properties of the Na0.5K0.5NbO3and Na0.5K0.5NbO3 + 0.5 mol%MnO2ceramics
2013
Na0.5K0.5NbO3 and Na0.5K0.5NbO3 + 0.5 mol%MnO2 lead-free ceramics have been produced by solid phase hot pressing sintering process at 1120–1145°C. The results of the X-ray diffraction measurements showed that the obtained samples possessed a perovskite structure. The micrograph of the fractured surface showed a dense ceramic structure, in compliance with 93% relative density determined by the Archimedes method. The dependence of dielectric and ferroelectric properties on the uniaxial compressive stress (0–3000 bar) of the Na0.5K0.5NbO3 and Na0.5K0.5NbO3 + 0.5 mol%MnO2 ceramics was investigated. Significant influence of the external stress on these properties was revealed. It includes a shif…