Search results for "Microscale chemistry"
showing 10 items of 40 documents
Thermosetting composites based on bronze particles for archaeological and artistic metal heritage cloning
2018
peer-reviewed Artificial Metals are polymeric semi-metallic composites obtained by combining thermosetting resins with atomized metal powders in order to achieve composite materials capable of reproducing metals, even in a rusty or corroded condition. These composites provide a solution for the reproduction of archaeological artefacts, sculptures, and ornaments for the purpose of conservation. This work explores mechanical properties of three different resins bronze composites loaded with two different proportions of metal filler. The degree of conversion of the samples was measured by differential scanning calorimetry (DSC) and flexural tests were carried out to determine their mechanical …
Influence of Plastic Deformation on the Corrosion Behaviour of As-Cast AlMg2 and AlCu4Mg1 Aluminium Alloys in NaCl Solution
2015
The influence of plastic deformation on the corrosion behavior of as-cast AlMg2 and AlCu4Mg1 aluminum alloys was studied at the microscale using the Electrochemical Microcell Technique and surface microgauges. It was shown that large strain gradients develop locally. The corrosion behavior of both alloys was affected by plastic deformation. The most active sites contain large strain gradients in AlMg2 and cracks with damage in the matrix in AlCu4Mg1.
Surface-Wave Coupling to Single Phononic Subwavelength Resonators
2017
International audience; We propose to achieve manipulation of mechanical vibrations at the micron scale by exploiting the interaction of individual, isolated mechanical resonators with surface acoustic waves. We experimentally investigate a sample consisting of cylindrical pillars individually grown by focused-ion-beam-induced deposition on a piezoelectric substrate, exhibiting different geometrical parameters and excited by a long-wavelength surface elastic wave. The mechanical displacement is strongly confined in the resonators, as shown by field maps obtained by laser scanning interferometry. A tenfold displacement field enhancement compared to the vibration at the surface is obtained, r…
Simple Models for Wall Effect in Fiber Suspension Flows
2014
Jeffery's equation describes the dynamics of a non-inertial ellipsoidal particle immersed in a Stokes liquid and is used in various models of fiber suspension flow. However, it is not valid in close neighbourhood of a rigid wall. Geometrically impossible orientation states with the fiber penetrating the wall can result from this model. This paper proposes a modification of Jeffery's equation in close proximity to a wall so that the geometrical constraints are obeyed by the solution. A class of models differing in the distribution between the translational and rotational part of the response to the contact is derived. The model is upscaled to a Fokker–Planck equation. Another microscale mode…
Plasmon-based free-radical photopolymerization : effect of diffusion on nanolithography processes
2011
This Article interrogates the mechanisms responsible for nanoscale photopolymerization induced by confined and enhanced electromagnetic fields. Surface plasmon dipolar resonance of individual Ag nanoparticles was used as an optical near-field source to locally trigger the reaction of a photopolymerizable formulation. Laser excitation of the nanoparticles embedded in the formulation reproducibly generates polymer features with typical dimensions ranging from 2 nm to a few tens of nanometer. We have determined the physicochemical parameters and mechanisms controlling the spatial extent of the photopolymerization process. We found that the diffusion of the dye is the main process limiting the …
Validation of a Microscale Pollution Dispersal Model
1996
The three-dimensional numerical model MISCAM (Micro Scale Air Pollution Model) has been developed to study wind flow and pollutant dispersal in densely built-up urban areas (Eichhorn, 1989). The model has been successfully applied for planning purposes by a variety of institutions in Germany. MISCAM consists of the non-hydrostatic Eulerian equations of motion and a transport equation for pollutants. Turbulence closure is carried out by means of a k-e-model. To reduce numerical diffusion errors, Smolarkiewicz and Grabowski’s (1989) scheme may be used for the calculation of advective transport. Additionally, sedimentation and dry deposition of pollutants may be taken into account.
A selective microscale x-ray fluorescence analyzing method for determination of trace elements
1973
Abstract A new selective X-ray fluorescence analyzing method for trace element determination has been developed. In this method each trace element is measured independently. The excitation source is an X-ray tube that has a changeable anode and a variable high voltage. The exciting radiation is shaped with critical absorbers. The sample is viewed at backward angles through an absorber to reduce backscattered radiation. The estimated accuracy of this method is of the order of 10 per cent in thesub-ppm range of trace element concentration in organic samples. Measurement times are of the order of a few minutes.
Dynamics of a Ferromagnetic Particle Levitated Over a Superconductor
2018
Under conditions where the angular momentum of a ferromagnetic particle is dominated by intrinsic spin, applied torque is predicted to cause gyroscopic precession of the particle. If the particle is sufficiently isolated from the environment, a measurement of spin precession can potentially yield sensitivity to torque beyond the standard quantum limit. Levitation of a micron-scale ferromagnetic particle above a superconductor is a possible method of near frictionless suspension enabling observation of ferromagnetic particle precession and ultrasensitive torque measurements. We experimentally investigate the dynamics of a micron-scale ferromagnetic particle levitated above a superconducting …
Forming-Free and Self-Rectifying Resistive Switching Effect in Anodic Titanium Dioxide-Based Memristors
2018
The paper presents the resistive switching of electroforming-free Ti/anodic- TiO 2 /Cu memristors. Anodic TiO 2 thin films were prepared by anodizing Ti layers. Microscale devices were fabricated by direct laser-assisted photolithography. Experimental results showed a bipolar and self-rectifying behavior of the devices, which could be useful for crossbar array configurations. Moreover, a gradual resistive switching of the devices in both directions was observed, indicating the presence of multi-level resistance states.
Microscale magnesium distribution in shell of the Mediterranean mussel Mytilus galloprovincialis: An example of multiple factors controlling Mg/Ca in…
2019
Abstract Since magnesium concentration (Mg/Ca) in biogenic calcite is considered to reflect water temperature during precipitation, the magnesium-to‑calcium ratio has been examined as a proxy for water temperature in paleoclimate research, although factors other than temperature may also influence Mg/Ca in biogenic calcite, thereby introducing a potential bias in the relationship between Mg/Ca and temperature observed in inorganic systems. To better understand factors controlling Mg incorporation into the calcitic shells of bivalves, the distribution of Mg in the Mediterranean mussel Mytilus galloprovincialis was studied, being compared with ambient sea surface temperature (SST), shell grow…