Search results for "Ms analysis"
showing 10 items of 56 documents
An integrated approach based on Life Cycle Assessment and Thermoeconomics: Application to a water-cooled chiller for an air conditioning plant
2018
Abstract A large number of methods for energy systems analysis were developed in the last decades, aimed at acquiring an in-depth understanding of plant performances and enabling analysts to identify optimal design and operating conditions. In this work an integrated approach based on Life Cycle Assessment and Thermoeconomics is proposed as a method for assessing the exergo-environmental profile of energy systems. The procedure combines the capabilities of these two techniques, to account simultaneously for aspects related to thermodynamics of energy conversion processes and to the overall impacts along the plant life cycle related to other phases, i.e. from raw material extraction to the d…
Advanced Sample Preparation Techniques for MS Analysis
2015
Suzuki polycondensation with a hairpin monomer.
2009
Two straight monomers were subjected to an AA/BB-type Suzuki polycondensation with a hairpin-shaped 1,8-anthrylene monomer as the counterpart leading to a novel polyarylene which should have the preferred conformation of a folded chain. The molar masses were determined by gel permeation chromatography and dynamic light scattering and found to be M(w) = 14,000 and M(n) = 7,000. MALDI-TOF MS analysis of a fraction provides a fingerprint of the step-growth nature of this polymerization.
Parameter subset selection for the dynamic calibration of activated sludge models (ASMs): experience versus systems analysis.
2007
In this work we address the issue of parameter subset selection within the scope of activated sludge model calibration. To this end, we evaluate two approaches: (i) systems analysis and (ii) experience-based approach. The evaluation has been carried out using a dynamic model (ASM2d) calibrated to describe nitrogen and phosphorus removal in the Haaren WWTP (The Netherlands). The parameter significance ranking shows that the temperature correction coefficients are among the most influential parameters on the model output. This outcome confronts the previous identifiability studies and the experience based approaches which excluded them from their analysis. Systems analysis reveals that parame…
Oxidation of diclofenac in the presence of iron(II) octacarboxyphthalocyanine
2021
Abstract This paper presents the results of the research on the influence of catalytic activity of iron(II) octacarboxyphthalocyanines (FePcOC) on the transformation of diclofenac (DCF) which is the most popular anti-inflammatory analgesic. Diclofenac poses a serious threat to the natural environment. The paper demonstrates that diclofenac, in the presence a monomeric form of iron octacarboxyphthalocyanine and hydroxyl radicals (HO•) (from H2O2), undergoes a transformation into diclofenac-2,5-iminoquinone (DCF-2,5-IQ), causing distinct changes in the UV–Vis absorption spectrum. In the presence of iron octacarboxyphthalocyanine and H2O2, the previously colourless diclofenac solution becomes …
LC-ESI/HRMS analysis of glucosinolates, oxylipins and phenols in Italian rocket salad (Diplotaxis erucoides subsp. erucoides (L.) DC.) and evaluation…
2021
BACKGROUND: This study investigated the chemical profile and biological activity of Diplotaxis erucoides subsp. erucoides (L.) DC. (Brassicaceae) collected in Sicily (Italy). RESULTS: Liquid chromatography coupled with electrospray ionization and high-resolution mass spectrometry (LC-ESI/HRMS) analysis of the ethanol extract revealed the presence of 42 compounds – glucosinolates, hydroxycinnamic acids, flavonoids, and oxylipins. The extract was tested for its antioxidant activity using 2,2-diphenyl-1-picrylhydrazyl (DPPH), 2,2′-azinobis(3-ethylbenzothiazoline-6-sulfonic) acid (ABTS), ferric reducing ability power (FRAP), and β-carotene bleaching tests. Promising protection from lipid peroxi…
Revisited BIA-MS combination: Entire "on-a-chip" processing leading to the proteins identification at low femtomole to sub-femtomole levels
2008
International audience; We present the results of a study in which biomolecular interaction analysis (BIA, Biacore 2000) was combined with mass spectrometry (MS) using entire "on-a-chip" procedure. Most BIA-MS studies included an elution step of the analyte prior MS analysis. Here, we report a low-cost approach combining Biacore analysis with homemade chips and MS in situ identification onto the chips without elution step. First experiments have been made with rat serum albumin to determine the sensitivity and validation of the concept has been obtained with an antibody/antigen couple. Our "on-a-chip" procedure allowed complete analysis by MS-MS of the biochip leading to protein identificat…
An Analysis Of The Work System Framework For Examining Information Exchange In A Healthcare Setting
2016
Employee shirking and overworking: modelling the unintended consequences of work organisation
2020
Underworking (i.e. shirking) and overworking of employees can have detrimental effects for the individual and the organisation. We develop a computational model to investigate how work structure, specifically the way in which managers distribute work tasks amongst employees, impacts work intensity and working time. The model draws on theories from economics, psychology and management, and on empirical observations. The simulations show that when managers correctly estimate task difficulty, but undervalue the employee’s competence, opportunities for shirking are provided due to longer deadlines. Similarly, if managers overvalue the employee’s competence, they set tighter deadlines leading to…
Characterisation of the essential oil of Nepeta glomerata Montbret et Aucher ex Bentham from Lebanon and its biological activities.
2011
The essential oil of Nepeta glomerata from Lebanon was studied by means of GC and GC/MS analysis; 70 compounds were identified. The oil was constituted mainly by monoterpenes and the most abundant components were α-pinene, spathulenol and carvacrol. Nepeta glomerata oil showed antibacterial activity, particularly towards Gram-positive bacteria, and also inhibited LPS-induced NO production in macrophage cell line RAW 264.7, with an IC(50) value of 78.1 µg mL(-1). Furthermore, an in vitro cytotoxic assay showed that the oil was more active on a renal adenocarcinoma cell line (48% of inhibition of proliferation at 100 µg mL(-1)) in comparison to an amelanotic melanoma.