Search results for "Native"

showing 10 items of 1727 documents

Cytotoxic Spirostane-Type Saponins from the Roots of Chlorophytum borivilianum

2009

Four new spirostane-type saponins named borivilianosides E-H (1-4) were isolated from an ethanol extract of the roots of Chlorophytum borivilianum together with two known steroid saponins (5 and 6). The structures of 1-4 were elucidated using mainly 2D NMR spectroscopic techniques and mass spectrometry. The cytotoxicity of borivilianosides F (2), G (3), and H (4) and three known compounds was evaluated using two human colon cancer cell lines (HT-29 and HCT 116).

Chemical structureIndiaPharmaceutical SciencePharmacologyPlant RootsAnalytical ChemistrySteroid SaponinsDrug DiscoverySpirostansHumansCytotoxic T cellMedicinal plantsCytotoxicityNuclear Magnetic Resonance BiomolecularAsparagaceaePharmacologyPlants MedicinalMolecular StructurebiologyTraditional medicineChemistryOrganic ChemistrySaponinsbiology.organism_classificationAntineoplastic Agents PhytogenicHuman colon cancerComplementary and alternative medicineChlorophytum borivilianumMolecular MedicineDrug Screening Assays AntitumorTwo-dimensional nuclear magnetic resonance spectroscopyJournal of Natural Products
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Studies on the mechanism of PMN activation. I. By dextran sulfates.

1982

Evidence is presented that enhanced reduction of the dye nitroblue-tetrazolium (NBT) by polymorphonuclear leukocytes (PMN) which are stimulated by dextran sulfates (DS) is not exclusively due to the phagocytosis of particles formed by NBT and DS. Not only the size of phagocytizable particles but the degree of substitution determines the acceleration of NBT-reduction. A likely cause of this acceleration is the triggering of the alternative pathway of the complement activation.

ChemistryNeutrophilsPhagocytosisNitroblue TetrazoliumComplement Pathway Alternativechemical and pharmacologic phenomenaDextransHematologyGeneral MedicineComplement systemchemistry.chemical_compoundDegree of substitutionDextranBiochemistryPhagocytosisAlternative complement pathwayBiophysicsHumansBlut
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Probing DNA conductivity with photoinduced electron transfer and scanning tunneling microscopy.

2012

Abstract The possibility that the stacked DNA bases can mediate vectorial electron transfer has been examined using two different approaches. Experiments on photoinduced electron transfer with intercalated donors and acceptors (either randomly bound or linked dyads of ruthenium complex and viologen) indicate that while DNA may be a better medium than acetonitrile for electron transfer over short distances (2-3-base pair, equivalent to 10-14Å centre-to-centre separation), it is a poor medium for transport over larger separations. Attempts to measure conductivity of individual DNA molecules using scanning tunneling microscopy to image mixed monolayers of mercaptohexanol (MCH) and 30-mer or 10…

ChemistryViologenElectronsGeneral MedicineDNAPhotochemistryElectron transport chainPhotoinduced electron transferIntercalating Agentslaw.inventionElectron TransportElectron transferStructural BiologylawMicroscopy Scanning TunnelingMonolayerMicroscopymedicineNative stateScanning tunneling microscopeMolecular BiologyOxidation-Reductionmedicine.drugJournal of biomolecular structuredynamics
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Drimane-type Sesquiterpene Coumarins from Ferula gummosa Fruits Enhance Doxorubicin Uptake in Doxorubicin-resistant Human Breast Cancer Cell Line

2014

ABSTRACT Multidrug resistance (MDR) is the main cause of failure in the chemotherapy of cancer patients. The present study aimed to evaluate the effects of sesquiterpene coumarins of Ferula gummosa fruits on P-glycoprotein (P-gp)–mediated MDR. Drimane-type sesquiterpene coumarins from the fruits of F. gummosa were extracted with dichloromethane and subjected to column chromatography. The effects of the isolated compounds on P-gp–mediated MDR were evaluated in the breast cancer cell line MCF-7 which shows high resistance to doxoribicin (MCF-7/Dox). Phytochemical investigation of dichloromethane extract of F. gummosa fruits resulted in three sesquiterpene coumarins including conferone (1), mo…

Chemistrylcsh:RCancerlcsh:MedicineP-glycoprotein inhibitorPharmacologymedicine.diseaseSesquiterpeneMultiple drug resistanceOriginal Research Paperchemistry.chemical_compoundBreast cancerComplementary and alternative medicinePhytochemicalCancer cellmedicinePotencyDoxorubicinEffluxFerula gummosaSesquiterpene coumarinsmedicine.drugJournal of Traditional and Complementary Medicine
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Contribution to the flora of Asian and European countries : new national and regional vascular plant records, 9

2020

The paper presents new records for 39 vascular plant species from eight Eurasian countries. Aniselytron treutleri Poaceae , Hackelochloa granularis Poaceae , Melica kozlovii Poaceae and Melica nutans Poaceae are reported from China; Dichondra micrantha Convolvulaceae from Hungary; Orobanche serbica Orobanchaceae and Viscum album subsp. austriacum Santalaceae from Italy; Petrorhagia prolifera Caryophyllaceae , Puccinellia schischkinii and Stipa pulcherrima Poaceae from Kyrgyzstan; Megadenia speluncarum Brassicaceae , Phelipanche lavandulacea Orobanchaceae , Solanum physalifolium Solanaceae , Thymus lenensis Lamiaceae from Russia; Rubus phoenicolasius Rosaceae from Slovakia; Atraphaxis karata…

Chorologytaxonomynative speciesalien speciesAsiaEuropeRubus phoenicolasiusSolanum physalifoliumAsiabiologyMelicanative speciesalien speciesPlant Sciencebiology.organism_classificationMelica nutansAtraphaxisfood.foodDichondraEuropeOrobanchetaxonomyChorologyfoodBotanyRubuschorology
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The inner nuclear membrane protein Src1 associates with subtelomeric genes and alters their regulated gene expression

2008

Inner nuclear membrane proteins containing a LEM (LAP2, emerin, and MAN1) domain participate in different processes, including chromatin organization, gene expression, and nuclear envelope biogenesis. In this study, we identify a robust genetic interaction between transcription export (TREX) factors and yeast Src1, an integral inner nuclear membrane protein that is homologous to vertebrate LEM2. DNA macroarray analysis revealed that the expression of the phosphate-regulated genes PHO11, PHO12, and PHO84 is up-regulated in src1Δ cells. Notably, these PHO genes are located in subtelomeric regions of chromatin and exhibit a perinuclear location in vivo. Src1 spans the nuclear membrane twice an…

Chromatin ImmunoprecipitationSaccharomyces cerevisiae ProteinsGenes FungalSaccharomyces cerevisiaeProtein Sorting SignalsBiologyArticleGenètica molecularProton-Phosphate SymportersGene Expression Regulation FungalGene expressionmedicineExpressió genèticaInner membraneNuclear proteinNuclear poreNuclear membraneResearch ArticlesNucleoplasmMembrane ProteinsNuclear ProteinsCell BiologyTelomereMolecular biologyChromatinProtein Structure TertiaryChromatinAlternative SplicingGenòmicamedicine.anatomical_structureMultiprotein ComplexesNuclear lamina
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Labdane Diterpenes from Stachys plumosa

2000

Three new labdane diterpenoids were isolated from the aerial parts of Stachys plumosa. The first two (1, 2) were the dextrorotatory enantiomers of the known 6-deoxyandalusol and 13-epijabugodiol. Structures were determined using NMR and MS techniques. The absolute stereochemistry of the third compound (3) was not experimentally proved.

Chromatography GasMagnetic Resonance SpectroscopyOptical RotationStereochemistryPharmaceutical ScienceGas Chromatography-Mass SpectrometryAnalytical ChemistryDextrorotatoryLabdanechemistry.chemical_compoundBalkan peninsulaDrug DiscoveryOrganic chemistryPharmacologyLamiaceaePlant StemsChemistryOrganic ChemistryAbsolute configurationStachys plumosaTerpenoidPlant LeavesItalyComplementary and alternative medicineChromatography GelMolecular MedicineSpectrophotometry UltravioletEpimerDiterpenesDiterpeneJournal of Natural Products
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Biologically Active Triterpene Saponins from Callus Tissue of Polygala amarella

1999

A new bioactive saponin (1), together with a known saponin (polygalasaponin XXVIII) has been isolated from the callus tissue culture of Polygala amarella. Based on spectroscopic data, especially direct and long-range heteronuclear 2D NMR analysis and on chemical transformations, the structure of 1 was elucidated as 3-O-beta-D-glucopyranosyl presenegenin-28-O-beta-D-galactopyranosyl-(1 --> 3)-beta-D-xylopyranosyl-(1 --> 4)-alpha-L-rhamnopyranosyl-(1 --> 2)-[beta-D-glucopyranosyl-(1 --> 3)]-beta-D-fucopyranoside. Both saponins showed significant immunological properties based on the enhancement of granulocyte phagocytosis in vitro.

Chromatography GasMagnetic Resonance SpectroscopySpectrophotometry InfraredStereochemistryMolecular Sequence DataSaponinPharmaceutical ScienceIn Vitro TechniquesSpectrometry Mass Fast Atom BombardmentAnalytical ChemistryTissue cultureAdjuvants ImmunologicPhagocytosisTriterpeneDrug DiscoveryHumansOleanolic AcidPharmacologychemistry.chemical_classificationPlants MedicinalbiologyChemistryHydrolysisOrganic ChemistryGlycosideSaponinsmusculoskeletal systembiology.organism_classificationTerpenoidEuropecarbohydrates (lipids)Polygala amarellaCarbohydrate SequenceComplementary and alternative medicineBiochemistryCallusSeedsMolecular MedicineSpectrophotometry UltravioletPolygalaceaeGranulocytesJournal of Natural Products
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Taxane analysis by high performance liquid chromatography-Nuclear magnetic resonance spectroscopy ofTaxus species

1998

High performance liquid chromatography–nuclear magnetic resonance spectroscopic analyses of taxane diterpenoids from three Taxus species were carried out employing a stopped-flow technique. Several taxanes have been identified from 500 mg leaf samples without prior isolation. © 1998 John Wiley & Sons, Ltd.

ChromatographyTaxanebiologyChemistryTaxus speciesTaxus × mediaPlant ScienceGeneral MedicineNuclear magnetic resonance spectroscopybiology.organism_classificationBiochemistryHigh-performance liquid chromatographyAnalytical ChemistryComplementary and alternative medicineDrug DiscoveryMagnetic resonance spectroscopicTaxus canadensisMolecular MedicineTaxaceaeFood SciencePhytochemical Analysis
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Induction of Secondary Metabolites from the Marine-Derived Fungus Aspergillus versicolor through Co-cultivation with Bacillus subtilis

2019

AbstractA new cyclic pentapeptide, cotteslosin C (1), a new aflaquinolone, 22-epi-aflaquinolone B (3), and two new anthraquinones (9 and 10), along with thirty known compounds (2, 4 – 8, 11 – 34) were isolated from a co-culture of the sponge-associated fungus Aspergillus versicolor with Bacillus subtilis. The new metabolites were only detected in the co-culture extract, but not when the fungus was grown under axenic conditions. Furthermore, the co-culture extract exhibited an enhanced accumulation of the known constituents versicolorin B (14), averufin (16), and sterigmatocyctin (19) by factors of 1.5, 2.0, and 4.7, respectively, compared to the axenic fungal culture. The structures of the …

Circular dichroismMagnetic Resonance SpectroscopyStereochemistryPharmaceutical ScienceAnthraquinonesMicrobial Sensitivity TestsBacillus subtilisQuinolonesGram-Positive BacteriaPeptides CyclicMass SpectrometryAnalytical ChemistryMicechemistry.chemical_compoundTermészettudományokCell Line TumorDrug DiscoveryAnthraquinonesAnimalsKémiai tudományokAxenicPharmacologyDose-Response Relationship DrugbiologyCytotoxinsChemistryCircular DichroismOrganic ChemistryAbsolute configurationbiology.organism_classificationCoculture TechniquesAnti-Bacterial AgentsAspergillusComplementary and alternative medicineMolecular MedicineAspergillus versicolorAntibacterial activityBacteriaBacillus subtilisPlanta Medica
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