Search results for "Optical"
showing 10 items of 7671 documents
Microstructured chalcogenide optical fibers from As2S3 glass: towards new IR broadband sources
2010
Made available in DSpace on 2013-08-28T14:12:29Z (GMT). No. of bitstreams: 1 WOS000285749500124.pdf: 1017839 bytes, checksum: f517fd8ef33fd56d66b9ccda9dc4d0f3 (MD5) Made available in DSpace on 2013-09-30T19:22:53Z (GMT). No. of bitstreams: 2 WOS000285749500124.pdf: 1017839 bytes, checksum: f517fd8ef33fd56d66b9ccda9dc4d0f3 (MD5) WOS000285749500124.pdf.txt: 33157 bytes, checksum: 1ca2ac713bf6024674249abf58520bcb (MD5) Previous issue date: 2010-12-06 Submitted by Vitor Silverio Rodrigues (vitorsrodrigues@reitoria.unesp.br) on 2014-05-20T15:34:00Z No. of bitstreams: 2 WOS000285749500124.pdf: 1017839 bytes, checksum: f517fd8ef33fd56d66b9ccda9dc4d0f3 (MD5) WOS000285749500124.pdf.txt: 33157 bytes,…
Strong infrared spectral broadening in low-loss As-S chalcogenide suspended core microstructured optical fibers
2010
Made available in DSpace on 2013-08-28T14:10:10Z (GMT). No. of bitstreams: 1 WOS000275454100017.pdf: 273411 bytes, checksum: da2aeaea61ab57013d39ecf2456466e3 (MD5) Made available in DSpace on 2013-09-30T19:22:36Z (GMT). No. of bitstreams: 2 WOS000275454100017.pdf: 273411 bytes, checksum: da2aeaea61ab57013d39ecf2456466e3 (MD5) WOS000275454100017.pdf.txt: 34647 bytes, checksum: b4efba760b21442eba43e7096f213b3e (MD5) Previous issue date: 2010-03-01 Submitted by Vitor Silverio Rodrigues (vitorsrodrigues@reitoria.unesp.br) on 2014-05-20T15:33:52Z No. of bitstreams: 2 WOS000275454100017.pdf: 273411 bytes, checksum: da2aeaea61ab57013d39ecf2456466e3 (MD5) WOS000275454100017.pdf.txt: 34647 bytes, ch…
Crystalline-state reaction with allosteric effect in spin-crossover, interpenetrated networks with magnetic and optical bistability.
2003
A net change: A fully reversible ligand substitution involving coordination/ uncoordination of gaseous water and pyrimidine induces the repetitive allosteric transformation of three interpenetrated nets into a single three-dimensional net. The transformation does not affect the crystallinity of the sample but alters significantly the spin-crossover transition; the compound shows magnetic and chromatic bistability (see picture).
Recent advances in the synthesis of functionalised monofluorinated compounds.
2018
Over the past few years, we have tackled the synthesis of interesting monofluorinated organic molecules, such as: dihydronaphthalene derivatives, β-fluoro sulfones and related carbonyl compounds, fluorohydrins and allylic alcohols. Overall, a wide range of modern synthetic techniques are covered in this feature article including transition-metal, photo- and organocatalysis, nucleophilic and electrophilic fluorinations, chiral auxiliaries and enantioselective catalysis.
γ-Silylboronates in the chiral Brønsted acid-catalysed allylboration of aldehydes.
2014
The use of functionalised allylboronic esters in the catalytic enantioselective allylboration of aldehydes is described for the first time. γ-Silylallyl pinacolate derivatives give rise to α-silyl homoallylic alcohols in high yields, with complete diastereoselectivities and high enantioselectivities, in most of the cases. The usefulness of such intermediates is showcased by their transformation into fluorinated allylic alcohols.
Optical measurements of ground-state properties of short-lived nuclei in resonance cells
1985
Hyperfine structure and isotope shift of radioactive Hg, Au and Cd isotopes have been determined by optical spectroscopy. In all cases the atoms were confined in a resonance cell. The various variants of the cell technique and alternative methods as the resonance ionization spectroscopy related to the investigation of short-lived nuclei are described, and some results are discussed.
Oxidation-driven changes of the in-plane magnetic surface anisotropies of the Fe(110)/Al interface
2003
Abstract Thin epitaxial iron films grown on W(1 1 0) were covered by ultrathin epitaxial aluminium layers of varying thicknesses from 0.2 to 0.6 nm and subsequently naturally oxidized in situ with oxygen exposures up to 150 L. Correlations between the oxidation states of the Al covers and changes of the in-plane magnetic anisotropies at the Fe(1 1 0)/Al interface were discussed on the basis of results from X-ray photoelectron spectroscopy and longitudinal magneto-optical Kerr magnetometry measurements. The Al coverage decreases the second-order in-plane surface anisotropy of the Fe(1 1 0) surface. Whereas for the thinnest Al covers, the second-order in-plane magnetic surface anisotropy decr…
The Effect of Electronic Properties of Anodized and Hard Anodized Ti and Ti6Al4V on Their Reactivity in Simulated Body Fluid
2022
The electronic properties of barrier and porous layers on Ti and Ti6Al4V were studied. Barrier anodic oxides grown to 40 V on Ti and on Ti6Al4V are both n-type semiconductors with a band gap of 3.3 eV and 3.4 eV respectively, in agreement with the formation of amorphous TiO2. Anodizing to 200 V at 20 mA cm−2 in calcium acetate and β-glycerol phosphate disodium pentahydrate leads to the formation of Ca and P containing porous films with a photoelectrochemical behaviour dependent on the metallic substrate. A band gap of 3.2 eV and the flat band potential of −0.5 V vs Ag/AgCl were measured for the porous oxide on Ti, while optical transitions at 2.15 eV and a significantly more positive flat b…
Gold catalyzed stereoselective tandem hydroamination–formal aza-Diels–Alder reaction of propargylic amino esters
2013
A gold-catalyzed tandem intramolecular hydroamination-formal aza-Diels-Alder reaction of propargylic amino esters is described. The overall process leads to the formation of a tetracyclic framework as a single diastereoisomer, with the creation of four bonds and five stereocenters.
Electrical resistivity of amorphous simple metals at moderately low temperatures
1999
Abstract The dependence of electrical resistivity ρ ( T ) on temperature T in a region of moderate temperatures is considered for amorphous simple metals. It is shown within the Faber–Ziman theory that the ratio [ ρ ( T )− ρ (0)]/ T 2 has a maximum in the temperature region 10 K⩽ T ⩽100 K The theory is illustrated by numerical calculations performed for hard-sphere models of amorphous Mg and Zn.