Search results for "Ordination"
showing 10 items of 1367 documents
Crystal structure of a mixed-valence μ-oxide Sn12 cluster
2014
The mixed-valence μ-oxide Sn12cluster, decacarbonyltetra-μ4-oxido-hexa-μ3-oxido-tetrakis[μ-2,2′-(pyridine-2,6-diyl)bis(1,1-diphenylethanolato)]decatin(II)ditin(IV)dimolybdenum(O)(2Mo—Sn) toluene heptasolvate, [Mo2Sn12(C33H27NO2)4O10(CO)10]·7C7H8, has a crystallographically imposed inversion centre. The asymmetric unit also contains three and a half toluene solvent molecules, one of which is disordered about a centre of symmetry. The complex molecule comprises six distinct Sn atom species with four different coordination numbers, namely 3, 4, 5, and 6. The SnIIatoms forming the central Sn10O10core adopt distorted trigonal–pyramidal, square-pyramidal and octahedral coordination geometries pro…
Selective formation of a unique diphosphonium-diphosphine from a tetraphosphine double protonation induced by zirconium salts
2008
A mixed ferrocenyl diphosphonium-diphosphine cation, associated with two [ZrCl(5).thf](-) anions, is obtained from a ferrocenyl tetraphosphine, as a unique didentate ionic metalloligand in a perfectly selective reaction induced by ZrCl(4) in THF.
Tetrakis(dimethoxyboryl)methane
2016
The title compound, tetrakis(dimethoxyboryl)methane (systematic name: octamethyl methanetetrayltetraboronate), C9H24B4O8or C[B(OMe)2]4, is a useful synthetic intermediate. Crystals of this compound at 102 K conform to the orthorhombic space groupPbcn. The molecules, which reside on sites of crystallographic twofold symmetry, have idealized -4 point symmetry like most other CX4molecules in which eachXgroup bears two non-H substituents at the 1-position. The central C atom has a slightly distorted tetrahedral coordination geometry, with C—B bond lengths of 1.5876 (16) and 1.5905 (16) Å. One of the methoxy groups is disordered over two sets of sites; the major component has an occupancy factor…
Synthesis, spectroscopic study, and crystal structure of a new organotin(IV) selenate derivative
2018
Abstract The polymeric organotin(IV) selenate complex [(Me3Sn)3(SeO4)(OH)]n (1) has been isolated as single crystals from the reaction of [(Me2NH2)2SeO4] and Me3SnCl in methanol. In the solid state, compound 1 was characterized by X-ray diffraction analysis, Fourier transform-infrared spectroscopy, and elemental analysis. 1 crystallizes in the orthorhombic system space group Pbca with a=11.0231(2) Å, b=16.3461(3) Å, c=20.9945(4) Å, α=β=γ=90°, V=3782.89(12) Å3, and Z=8. Its structure can be described as a polymeric zigzag chain based on Me3Sn moieties linked by tridentate selenate anions. Pendant (Me3Sn)2OH groups are also connected to the chain, according to a syndiotactic organization, and…
Tris(1,10-phenanthroline-κ2N,N′)nickel(II) bis(hexafluoridophosphate)
2018
The asymmetric unit of the title compound, [Ni(C36H24N6)3](PF6)2, contains one and a half nickel(II) complex dications and three hexafluoridophosphate anions, one of the dications having crystallographic twofold rotational symmetry. Each NiIIatom displays a distorted octahedral coordination geometry provided by the six N atoms of three bidentate 1,10-phenanthroline ligands with bite angles of 79.68 (11)–80.76 (12)°. In the crystal, C—H...F hydrogen bonds link the anions and dications into a three-dimensional supramolecular framework. Within the framework complex dications with twofold rotational symmetry are linked by weak π–π stacking interactions [centroid-to-centroid distances = 3.712 (2…
Crystal structure, spectroscopic characterization and Hirshfeld surface analysis of trans-diaqua[2,5-bis(pyridin-4-yl)-1,3,4-oxadiazole]dithioc…
2019
The NiII atom in the mononuclear title complex has an almost regular octahedral N4O2 coordination geometry. In the crystal, the complex molecules are linked in a three-dimensional network through strong O—H⋯N hydrogen bonds.
Algorytmy — nowy wymiar nadzoru i kontroli nad świadczącym pracę
2020
Autor wskazuje, że algorytmy stają się kluczową technologią władzy nad świadczącym pracę. Pozwalają na sformatowanie zarówno samych pracowników, jak i wzajemnych oddziaływań między nimi zasadniczo w jednym celu — optymalizacji procesów pracy służących zwiększeniu wydajności. Z tej perspektywy pracownik jest cyfrowym modelem zbudowanym z danych i informacji. Oznacza to, że wszelkie jego ekspresje ujawniane w środowisku pracy będą mogły być mierzalne, i to na rożne sposoby. Algorytmy rzucają również nowe światło na zagadnienie podporządkowania w zatrudnieniu. A wszystko dzięki ,,wtapianiu się” ich w środowisko danych biometrycznych osób świadczących pracę. W pewien sposób przejmują one własno…
Zgoda pracownika na pobieranie i przetwarzanie danych biometrycznych a brak równowagi stron stosunku pracy
2016
Zagadnienie, czy brak równowagi stron stosunku pracy faktycznie może stawiać pod znakiem zapytania dobrowolność w wyrażeniu przez pracownika zgody na pobieranie i przetwarzanie danych biometrycznych, a w konsekwencji czy „zależność pracownika od pracodawcy” jest stanem, który ex definitione stale zakłóca przejawy woli pracownika, budzi ciągłe kontrowersje, jak i rozbieżności interpretacyjne. Zdaniem autora zgoda pracownika na pobieranie i przetwarzanie dotyczących go danych biometrycznych dotyczy sfery, w której pracownicze podporządkowanie nie odgrywa jakiejkolwiek roli, sfery, w której wzajemne relacje stron stosunku pracy są oparte na pełnej ich równości wobec siebie, w ramach której z u…
On the syntax of dependency in late sixteenth-century Europe
2023
The need for studies on the history of dependency linguistics has been recently pointed out, aiming at tracing back to the origin of hierarchical grammatical relations and dependency-oriented approaches before the advent of the most renowned Tesnière’s model (Imrényi/Mazziotta 2020a). This study investigates on the emergence of the concept of syntactic dependency in missionary linguistics, focusing on the role of Jesuit grammarians on the development of the notion of subordination. In particular, the analysis concentrates on the first grammar of the indigenous South American language of Aymara, written by the Italian missionary Ludovico Bertonio at the end of the sixteenth century. I will f…
Verifying the effect of distributed generators on voltage profile, power losses and protection system in radial distribution networks
2013
In the recent years the electrical power networks are undergoing rapid restructuring and developing process worldwide. Advancement in technologies and concern about the environmental impacts have led to increase interconnection of renewable energy based distributed generations (DGs) in distribution networks. The DGs have significant impacts on the distribution systems; these impacts may be either positively or negatively depending on the modified interconnected DG distribution network structure. It will be necessary to consider many issues concerning these impacts. In this paper, an investigation of DGs impacts on voltage profile, power losses, and protection system in radial distribution n…