Search results for "PSO."

Thermostability of polymeric langmuir-blodgett films

1991

A user's guide to ellipsometry. By Harland G. Tompkins, Academic Press, New York 1993, 260 pp. hardback, ISBN 0-12-603050-0

1993

Tuning Optical Properties of Al 2 O 3 /ZnO Nanolaminates Synthesized by Atomic Layer Deposition

2014

Nanolaminates are of great interest for their unique properties such as high dielectric constants and advanced mechanical, electrical, and optical properties. Here we report on the tuning of optical and structural properties of Al2O3/ZnO nanolaminates designed by atomic layer deposition (ALD). Structural properties of nanolaminates were studied by SEM, GIXRD, and AFM. Optical characterization was performed by transmittance and photoluminescence (PL) spectroscopy. Complex study of monolayer properties was performed by ellipsometry. Optical constants for Al2O3 and ZnO monolayer were calculated. The band gap of ZnO single layers and the excitonic PL peak position were shifted to the UV region …

Surface characterization of functional poly(diacetylene) and poly(butadiene) mono- and multilayers

1982

The surface properties of Langmuir-Blodgett mono- and multilayers of a variety of amphiphilic poly(diacetylene)s and poly(butadiene)s were investigated by contact angle, streaming potentialζ, ellipsometry, and X-ray photoelectron spectroscopic (XPS) measurements. Captive air and octane angles varied between approximately 60° and 105° for hydrophobicx-layers and 31° to 46° for hydrophilic surfaces depending on the particular head group, whereas advancing angles determined via the vertical plate method are considerably higher. Negative streaming potentials were obtained for all surfaces. Positively charged monolayers yielded less negativeζ- potential values (−28 mV) than negatively charged (−…

Ellipsoidal core-shell cylindrical microphases in PS-b -PB-b -PCL triblock copolymers with a crystallizable matrix

1997

Polystyrene-block-polybutadiene-block-poly(e-caprolactone) SBC triblock copolymers with a PCL matrix exhibit microphase separation into three different phases within the spherulitic superstructures. Mixing of the PS-block can occur upon melting of the PCL-block if the molecular weight is low enough. Even though the crystallization takes place well below the PS-glass transition, a deformation of the amorphous microphases into ellipsoidal core-shell cylindrical microdomains is observed by TEM. These copolymers have mechanical properties which are dominated by the PCL (Poly(e-caprolactone)) matrix with an influence of the amorphous blocks.

Formation and Characterization of Self-Assembled Films of Thiol-Derivatized Poly(Dimethylsiloxane) on Gold

1997

Poly(dimethylsiloxane) (PDMS) copolymers containing propanethiol side chain “stickers” for forming self-assembled films on gold surfaces have been studied by various experimental techniques including ellipsometry, contact angle measurements, FT-IR, angle-dependent XPS, and ToF−SIMS. The results show that the thiol-containing side chains do not all chemisorb to the gold surfaces. In addition, the concentration of these sticker units was found to have a dominant effect on the polymer film thickness, the surface wetting properties, and the orientation of the PDMS backbone. Ab initio calculations reveal that the IR-active PDMS Si−O stretching bands can be used as indications of chain orientatio…

Formation of Optical Gradient in Chemical Solution-Derived PbZr[sub 0.52]Ti[sub 0.48]O[sub 3] Thin Films: Spectroscopic Ellipsometry Investigation

2009

Investigation using a variable angle spectroscopic ellipsometer revealed the influence of sample preparation conditions on sol-gel PbZr 0.52 Ti 0.48 O 3 (PZT 52/48) thin-film homogeneity that allows identification and further optimization of thin-film performance. Separate crystallization of the layers determined the optical gradient appearance, irrespective of the chemical solvents used in this work. A more refined analysis showed that a refractive index gradient was apparent in the samples in which lattice parameters strongly changed with thickness. For these films, energy-dispersive X-ray spectroscopy analysis showed significant variation in Pb and Zr. Additionally, complex dielectric fu…

Optical Gradient of the Trapezium-Shaped NaNbO[sub 3] Thin Films Studied by Spectroscopic Ellipsometry

2008

thin films were performed in the photon energy range of 1.24–4.96 eV.Effective values of the complex refractive index and thickness nonuniformity, roughness, and depth profile of the real part of therefractive index were evaluated. An increase of the refractive index with increasing of the sample thickness was observed anddiscussed.© 2008 The Electrochemical Society. DOI: 10.1149/1.2965786 All rights reserved.Manuscript submitted May 27, 2008; revised manuscript received July 7, 2008. Published August 19, 2008.

Biomaterial Surface Hydrophobicity-Mediated Serum Protein Adsorption and Immune Responses.

2019

The nature of the protein corona forming on biomaterial surfaces can affect the performance of implanted devices. This study investigated the role of surface chemistry and wettability on human serum-derived protein corona formation on biomaterial surfaces and the subsequent effects on the cellular innate immune response. Plasma polymerization, a substrate-independent technique, was employed to create nanothin coatings with four specific chemical functionalities and a spectrum of surface charges and wettability. The amount and type of protein adsorbed was strongly influenced by surface chemistry and wettability but did not show any dependence on surface charge. An enhanced adsorption of the …

A new gas sensor electronic interface with generalized impedance converter

2008

A new gas sensor conditioning circuit that allows a direct resistance-to-frequency conversion, as well as the procedure for the design, is presented. The generalized impedance converter (GIC) proposed is configured as a variable capacitor connected with the capacitor timing terminal of an astable multivibrator implemented by a PSoC (programmable system on chip) microcontroller device. The GIC effective input impedance, which is controlled by the gas sensor resistance, controls the astable output frequency. Good correlation of the experimental output frequency, which depends on the gas concentration, is achieved. The circuit is a simple gas sensor digital interface with frequency output.