Search results for "Polar"
showing 10 items of 3817 documents
Investigation on partial discharges in HVDC cables after polarity reversal events
2020
Due to the accumulation of space charge inside the insulating layer of HVDC cables, the electric field under load conditions may be altered compared to what is established in HVAC cables. For example, a high thermal gradient leads to the inversion of the electric field pattern until the maximum value is reached in proximity of the dielectric-semicon interfaces. These maximum values can be further increased due to transient overvoltages and polarity reversal events until reaching electric field values higher than the rated ones. The main goal of this research is to investigate the possibility that, during these transient phenomena, conditions are created that favor the occurrence of partial …
Effect of Polarity Reversal on the Partial Discharge Phenomena
2020
In the field of High Voltage Direct Current (HVDC) transmission, the space charge accumulation phenomenon and the Partial Discharges (PD) phenomena are considered the main causes of dielectric ageing. During the years, the degradation effect of both phenomena under constant DC stress has been widely studied by several researchers. In case of polarity reversal, typically carried out to control bi-directional power flow between interconnected High Voltage transmission systems, the space charge movement may not synchronously follow the electric field polarity. This could make the moment of reversing polarity a very critical one, where space charge injected during preceding polarity produces hi…
Polarity reversal in HVDC joints - The effect of the axial thermal conduction
2020
It has been shown that the establishment of a thermal gradient over the radius of HVDC cables involves the accumulation of space charge within the dielectric layer. High thermal gradients over the insulation thickness of loaded cables can lead to the inversion of the radial electric field pattern. In this scenarios, transient overvoltages and polarity reversal can lead to local and transitory peaks of electric field. Since the temperature distribution plays an important role in reaching critical values of the electric field, it has been considered interesting to have a more in-depth view of the thermal behavior of HVDC systems close the discontinuities of the geometry along the cable axis. …
Development of hard x-ray photoelectron SPLEED-based spectrometer applicable for probing of buried magnetic layer valence states
2016
Abstract A novel design of high-voltage compatible polarimeter for spin-resolved hard X-ray photoelectron spectroscopy (Spin-HAXPES) went into operation at beamline BL09XU of SPring-8 in Hyogo, Japan. The detector is based on the well-established principle of electron diffraction from a W(001) single-crystal at a scattering energy of 103.5 eV. It's special feature is that it can be operated at a high negative bias potential up to 10 kV, necessary to access the HAXPES range. The polarimeter is operated behind a large hemispherical analyzer (Scienta R-4000). It was optimized for high transmission of the transfer optics. A delay-line detector (20 mm dia.) is positioned at the exit plane of the…
Laser-induced enhancement of tunneling in NHD2
2012
We apply and explore techniques aiming at enhancing the tunneling by laser fields, originally developed for a one-dimensional model, to a complete six-dimensional vibrational model of the inversion motion in NHD(2). The computational study is performed with the multi-configuration time-dependent Hartree method. Assuming an ideal three-dimensional alignment we obtain a driven tunneling time twenty times smaller than the natural one, in rather good agreement with an oversimplified three-state model. In the case of one-dimensional alignment, a linearly polarized field leads to a poor enhancement of the tunneling probability, after averaging over the rotation about the alignment axis, whereas a…
A QM/MM Approach Using the AMOEBA Polarizable Embedding: From Ground State Energies to Electronic Excitations
2016
International audience; A fully polarizable implementation of the hybrid Quantum Mechanics/Molecular Mechanics approach is presented, where the classical environment is described through the AMOEBA polarizable force field. A variational formalism, offering a self-consistent 1 relaxation of both the MM induced dipoles and the QM electronic density is used for ground state energies and extended to electronic excitations in the framework of Time-Dependent Density Functional Theory combined with a state specific response of the classical part. An application to the calculation of the solvatochromism of the pyridinium N-phenolate betaine dye used to define the solvent ET30 scale is presented. Th…
Dynamic Polarizability and Higher-Order Electric Properties of Fluorene, Carbazole, and Dibenzofuran
2019
Static electric properties, from the dipole moment to the second-hyperpolarizability tensor γ, of the 3-membered, isoelectronic ring molecules, fluorene (FL), carbazole (CR), and dibenzofuran (DBF), have been calculated at various levels of approximation. The electron correlation effects have been included at the coupled-cluster (CC) level, using CCSD and CC2 versions of the method. DFT calculations with the CAM-B3LYP functional have also been performed, and the results are compared to the CC values. The electric property-tailored Pol basis set and its more compact Z3Pol version have been employed in all static calculations. Differences between dipole polarizability values computed at the P…
Enhanced alignment and orientation of polar molecules by vibrational resonant adiabatic passage
2007
The authors show that polar molecules can be adiabatically aligned and oriented by laser pulses more efficiently when the laser frequencies are vibrationally resonant. The aligned molecules are found in a superposition of vibrational pendular states, each associated with the alignment of the rotor in one vibrational state. The authors construct the dressed potential associated with this mechanism. Values of detunings and field amplitudes are given to optimize the degree of alignment and orientation for the CO molecule.
Inelastic neutron scattering study of proton dynamics in Ca(OH)2 at 20 K
1995
Abstract Inelastic neutron scattering (INS) spectra of Ca(OH) 2 at 20 K are presented from 30 to 4000 cm −1 for a powder sample, from 30 to 12000 cm −1 for an oriented single-crystal. INS band splitting due to the lattice density-of-states is observed. Polarization effects reveal the orientation of atomic displacements for each mode and a new band assignment scheme is proposed. For the single-crystal, the v OH mode and overtones are observed. This oscillator shows only moderate anharmonicity. Spectrum simulation reveals that INS spectral intensities are not consistent with simple normal coordinates and harmonic force-fields for Ca(OH) 2 entities. A new dynamical model is proposed, including…
Pressure‐induced widths and shifts for the ν3 band of methane
1994
International audience; Widths and shifts of methane lines perturbed by nitrogen are calculated using a complex-valued implementation of Robert-Bonamy (RB) theory. The static intermolecular potential is described as a sum of electrostatic forces and Lennard-Jones (6-12) atom-atom terms, using literature values for all physical parameters. Vibrational dependence of the isotropic potential is obtained from the polarizability of methane assuming a dispersion interaction. The repulsive part of the Lennard-Jones accounts for the greatest part of widths, while dispersion interactions are largely responsible for shifts. Although the average error between calculated and observed linewidths (up to J…