Search results for "RATES"

showing 10 items of 1636 documents

Effective saccharification of lignocellulosic barley straw by mechanocatalytical pretreatment using potassium pyrosulfate as a catalyst

2017

The catalytic conversion of lignocellulosic biomass is attractive due to the feasible generation of valuable products such as reducing sugars which constitute the basic substrates for chemical and transportation fuel production, as well as the production of renewable hydrogen. This study shows the efficient conversion of lignocellulose, especially hemicellulose, into reducing sugars such as xylose and galactose, by mechanocatalysis using potassium pyrosulfate, K2S2O7, as an effective salt catalyst. Ball milling was performed, introducing a mechanical force which, combined with chemical pretreatment, leads to reducing sugar yields (40%) almost as high as when commonly used sulfuric acid was …

Environmental EngineeringCarbohydratesLignocellulosic biomassBioengineeringXylose010402 general chemistry01 natural sciencesPotassium pyrosulfateCatalysischemistry.chemical_compoundHydrolysisHemicelluloseBiomassWaste Management and Disposalchemistry.chemical_classificationXyloseWaste management010405 organic chemistryRenewable Energy Sustainability and the EnvironmentHydrolysisHordeumSulfuric acidGeneral MedicinePulp and paper industry0104 chemical sciencesReducing sugarchemistryPotassiumBioresource Technology
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Biological nitrate removal from wastewater of a metal-finishing industry

2006

An upflow packed bed reactor at laboratory scale has been operated for a continuous period of 5 months to investigate the technical feasibility of biological nitrate removal applied to the effluent of the coagulation-sedimentation wastewater of a metal-finishing industry. The reactor was fed with industrial wastewater in a five-fold dilution to reproduce the global spill in the factory (20/80, industrial wastewater/domestic wastewater) with a concentration of nitrate between 141 and 210 gNO(3)-N/m(3). Methanol was added as a carbon source for denitrification. Inlet flow rate was progressively increased from 9 to 40 L/day (nitrogen input load from 45 to 250 gNO(3)-N/(m(3)h)). The highest obs…

Environmental EngineeringDenitrificationNitrogenHealth Toxicology and MutagenesisIndustrial Wastechemistry.chemical_elementWater PurificationIndustrial wastewater treatmentchemistry.chemical_compoundNitrateEnvironmental ChemistryBiomassWaste Management and DisposalEffluentNitratesMethanolChemical oxygen demandEnvironmental engineeringPulp and paper industryPollutionNitrogenDilutionOxygenKineticsBiodegradation EnvironmentalModels ChemicalchemistryWastewaterWater Pollutants ChemicalJournal of Hazardous Materials
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Polar organic marker compounds in PM2.5 aerosol from a mixed forest site in western Germany

2008

The molecular composition of PM2.5 (particulate matter with an aerodynamic diameter2.5 microm) aerosol samples collected during a very warm and dry 2003 summer period at a mixed forest site in Jülich, Germany, was determined by gas chromatography/mass spectrometry in an effort to evaluate photooxidation products of biogenic volatile organic compounds (BVOCs) and other markers for aerosol source characterization. Six major classes of compounds represented by twenty-four individual organic species were identified and measured, comprising tracers for biomass combustion, short-chain acids, fatty acids, sugars/sugar alcohols, and tracers for the photooxidation of isoprene and alpha-/beta-pinene.…

Environmental EngineeringHealth Toxicology and MutagenesisCarbohydratescomplex mixturesGas Chromatography-Mass SpectrometryTreesBridged Bicyclo Compoundschemistry.chemical_compoundHemiterpenesGermanyPentanesButadienesEnvironmental ChemistryVolatile organic compoundBiomassOrganic ChemicalsChemical compositionBicyclic MonoterpenesAerosolschemistry.chemical_classificationPhotolysisChemistryPharmacology. TherapyLevoglucosanFatty AcidsPublic Health Environmental and Occupational HealthGeneral MedicineGeneral ChemistryParticulatesPollutionAerosolChemistryHydrocarbonPyrogallolEnvironmental chemistryMonoterpenesParticulate MatterAcids AcyclicMalic acidVolatilizationOxidation-ReductionChemosphere
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Melatonin alleviates Ochratoxin A-induced liver inflammation involved intestinal microbiota homeostasis and microbiota-independent manner.

2021

Melatonin (MEL) shows an anti-inflammatory effect and regulates intestinal microbiota communities in animals and humans; Ochratoxin A (OTA) induces liver inflammation through intestinal microbiota. However, it remains to know whether MEL alleviates the liver inflammation induced by OTA. In this study, MEL reversed various adverse effects induced by OTA. MEL recovered the swarming and motility of intestinal microbiota, decreased the accumulation of lipopolysaccharide (LPS), enhanced the tight junction proteins of jejunum and cecum segments; ultimately alleviated OTA-induced liver inflammation in ducks. However, it is worth noting that MEL still had positive effects on the OTA-exposed ducks a…

Environmental EngineeringLipopolysaccharideHealth Toxicology and Mutagenesis0211 other engineering and technologiesMotilityInflammation02 engineering and technology010501 environmental sciencesBiologyPharmacologydigestive system01 natural sciencesAntioxidantsJejunumMelatoninCecumchemistry.chemical_compoundhemic and lymphatic diseasesmedicineEnvironmental ChemistryAnimalsHomeostasisHumansneoplasmsWaste Management and Disposal0105 earth and related environmental sciencesMelatoninInflammation021110 strategic defence & security studiesTight junctionPollutionOchratoxinsGastrointestinal Microbiomecarbohydrates (lipids)medicine.anatomical_structurechemistryLivermedicine.symptomHomeostasismedicine.drugJournal of hazardous materials
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Performances of a granular sequencing batch reactor (GSBR).

2007

Aerobic granulation in sequencing batch reactors is widely reported in literature and in particular in SBAR (Sequencing batch airlift reactor) configuration, due to the high localised hydrodynamic shear forces that occur in this type of configuration. The aim of this work was to observe the phenomenon of the aerobic granulation and to confirm the excellent removal efficiencies that can be achieved with this technology. In order to do that, a laboratory-scale plant, inoculated with activated sludge collected from a conventional WWTP, was operated for 64 days: 42 days as a SBAR and 22 days as a SBBC (sequencing batch bubble column). The performances of the pilot plant showed excellent organic…

Environmental EngineeringMaterials scienceNitratesSettore ICAR/03 - Ingegneria Sanitaria-AmbientaleBacteriaSettling timebusiness.industryGranule (cell biology)Sequencing batch reactorGranular Sludge SBR wastewater treatmentWaste Disposal FluidAerobiosisQuaternary Ammonium CompoundsPilot plantActivated sludgeBioreactorsAerobic granulationSewage treatmentExperimental workProcess engineeringbusinessWater Pollutants ChemicalWater Science and TechnologyWater science and technology : a journal of the International Association on Water Pollution Research
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New silica based adsorbent material from rice straw and its in-flow application to nitrate reduction in waters: Process sustainability and scale-up p…

2021

Abstract This paper shows a particular example to move to a sustainable circular economical process from valorization of rice straw ashes by developing a green synthesis for obtaining a useful sub-product. This strategy can palliate negative effects of the agriculture waste practices on the environment and also the obtained silica reduced nitrate content in waters. It is demonstrated that the silica synthesis developed at lab was scalable more than a hundred times with good results. Adsorption studies of nitrate in standards and real well waters at lab scale and scaling-up provided similar results. Adsorption values near to 15 mg/g for nitrate standards and 8.5 mg/g for well water were obta…

Environmental EngineeringNitratesLab scaleFlow (psychology)OryzaRice strawPulp and paper industrySilicon DioxidePollutionWater Purificationchemistry.chemical_compoundKineticsAdsorptionNitratechemistryScientific methodSCALE-UPSustainabilityEnvironmental ChemistryEnvironmental scienceAdsorptionWaste Management and DisposalWater Pollutants ChemicalThe Science of the total environment
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Calibration of denitrifying activity of polyphosphate accumulating organisms in an extended ASM2d model

2010

Abstract This paper presents the results of an experimental study for the modelling and calibration of denitrifying activity of polyphosphate accumulating organisms (PAOs) in full-scale WWTPs that incorporate simultaneous nitrogen and phosphorus removal. The convenience of using different yields under aerobic and anoxic conditions for modelling biological phosphorus removal processes with the ASM2d has been demonstrated. Thus, parameter ηPAO in the model is given a physical meaning and represents the fraction of PAOs that are able to follow the DPAO metabolism. Using stoichiometric relationships, which are based on assumed biochemical pathways, the anoxic yields considered in the extended A…

Environmental EngineeringNitrogenElectronsPilot ProjectsModels BiologicalWaste Disposal FluidDenitrifying bacteriaPolyphosphatesCalibrationProcess optimizationAnaerobiosisWaste Management and DisposalAcetic AcidWater Science and TechnologyCivil and Structural EngineeringAutotrophic ProcessesNitratesBacteriaSewageChemistryEcological ModelingEnvironmental engineeringPhosphorusPollutionAnoxic watersOxygenPolyphosphate-accumulating organismsPilot plantActivated sludgeEnhanced biological phosphorus removalCalibrationBiological systemWater Research
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A parsimonious dynamic model for river water quality assessment

2010

Water quality modelling is of crucial importance for the assessment of physical, chemical, and biological changes in water bodies. Mathematical approaches to water modelling have become more prevalent over recent years. Different model types ranging from detailed physical models to simplified conceptual models are available. Actually, a possible middle ground between detailed and simplified models may be parsimonious models that represent the simplest approach that fits the application. The appropriate modelling approach depends on the research goal as well as on data available for correct model application. When there is inadequate data, it is mandatory to focus on a simple river water qua…

Environmental EngineeringQuality managementmedia_common.quotation_subjectFresh WaterCivil engineeringRiversWater SupplyQuality (business)mathematical modellingPhotosynthesisphysical-chemical water qualityWater Science and Technologymedia_commonHydrologyNitratesPhysical modelSettore ICAR/03 - Ingegneria Sanitaria-AmbientaleSewageMathematical modelSettore ICAR/02 - Costruzioni Idrauliche E Marittime E IdrologiaWater quality modellingsensitivity analysiModels Theoreticalsimplified modelOxygenQuaternary Ammonium CompoundsKineticsItalyData qualityConceptual modelEnvironmental scienceEnvironmental PollutantsWater qualityAlgorithmsWater Science and Technology
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Multivariate Correlation between Analytical Data for Various Organics Dissolved during Autohydrolysis of Silver Birch (Betula pendula) Chips and Trea…

2014

Autohydrolysis pre-treatments were performed for the production of hemicellulose-rich autohydrolysates from silver birch (Betula pendula) chips prior to chemical pulping. Pre-treatment conditions were varied with respect to time (from 30 to 120 min) and temperature (130 and 150 °C), covering a P-factor range from 10 to 238. Hydrolysates were analyzed in terms of carbohydrates, lignin, volatile organic acids, and furanoic compounds. The analytical data were subjected to various chemometric techniques to establish the relationships between dissolved organic components, hardwood and softwood used in the experiments, and applied pre-treatment conditions. Using this method, differences between t…

Environmental EngineeringSoftwoodChemistrylcsh:BiotechnologyCarbohydratesPrincipal component analysisBioengineeringPulp and paper industryLigninChemical pulpingchemistry.chemical_compoundVolatile acidsAutohydrolysisBetula pendulaBiorefininglcsh:TP248.13-248.65HardwoodBetula pendulaOrganic chemistryLigninOrganic componentBiorefiningFuransWaste Management and DisposalBioResources
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Biogas production and saccharification of Salix pretreated at different steam explosion conditions.

2011

Abstract Different steam explosion conditions were applied to Salix chips and the effect of this pretreatment was evaluated by running both enzymatic hydrolysis and biogas tests. Total enzymatic release of glucose and xylose increased with pretreatment harshness, with maximum values being obtained after pretreatment for 10 min at 210 °C. Harsher pretreatment conditions did not increase glucose release, led to degradation of xylose and to formation of furfurals. Samples pretreated at 220 and 230 °C initially showed low production of biogas, probably because of inhibitors produced during the pretreatment, but the microbial community was able to adapt and showed high final biogas production. I…

Environmental EngineeringWaste managementRenewable Energy Sustainability and the EnvironmentChemistryCarbohydratesPoison controlBiomassLignocellulosic biomassBioengineeringSalixGeneral MedicineXylosePulp and paper industrychemistry.chemical_compoundBiogasBioenergyEnzymatic hydrolysisBiofuelsWaste Management and DisposalChromatography High Pressure LiquidSteam explosionBioresource technology
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