Search results for "Ruth"
showing 10 items of 661 documents
Ordering effects in extreme high-resolution depth profiling with MeV ion beams
2012
Abstract The continuing development of depth profiling with MeV ion beam methods with depth resolutions in the nanometre, and even sub-nanometre, regime implies the resolved depth become comparable with the interatomic spacing. To investigate how short-range ordering influences depth profiles at these resolutions, we have employed a mathematical modelling approach. The radial, g ( r ) and depth distribution, g ( z ) functions were calculated for (1 0 0) surface, random and amorphous Si structures at 300 K produced using molecular dynamics simulations with the EDIP quasi-empirical potential. The results showed that short-range ordering lead to reduction of the scattering yield below the deep…
Characterization of alpha sources prepared by direct evaporation using Rutherford backscattering spectrometry
1997
Abstract Standardization of solutions containing alpha emitting nuclides by direct evaporation onto metal supports is a widely used technique due to its simplicity in providing good quantitative results. In order to avoid inhomogeneity in the deposition surface, polished stainless steel disks and a spreading agent are generally used. These sources are usually measured by alpha spectrometry using passivated implanted silicon detectors. The resolution of the source is a measure of the thickness and homogeneity of the evaporated layer. Rutherford backscattering of He+ and H+ was here used to measure directly this thickness and homogeneity. The results were in agreement with semiconductor detec…
Synthesis and characterization of cobalt silicide films on silicon
2006
Cobalt silicide has emerged as a leading contact material in silicon technology due to its low resistivity, high stability and small lattice mismatch. In this study, 0.2-0.4 mu m thick Co films were deposited on Si(100) wafers by RF magnetron sputtering at room temperature, and annealed at temperatures from 600 to 900 degrees C in vacuum. As-deposited and annealed samples were characterized by Rutherford backscattering spectrometry (RBS), nuclear reaction analysis (NRA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Although the Si substrates were sputter cleaned before the deposition, all the samples showed a thin oxide layer at the Si/Co interfaces. Annealing up to 700 d…
A precise measurement of the Z resonance parameters through its hadronic decays
1990
A measurement of the cross section for e+e-→ hadrons using 11 000 hadronic decays of the Z boson at ten different center-of-mass energies is presented. A three-parameter fit gives the following values for the Z mass MZ, the total width ΓZ, the product of the electronic and hadronic partial widths ΓeΓh, and the unfolded pole cross section σ0: MZ = 91.171 ± 0.030 (stat.) ± 0.030 (beam) GeV, ΓZ = 2.511 ± 0.065 GeV, ΓeΓh = 0.148 ± 0.006 (stat.) ± 0.004 (syst.) GeV2, σ0 = 41.6 ± 0.7 (stat.) ± 1.1 (syst.) nb, Good agreement with the predictions of the standard model is observed. From a two-parameter fit the number of massless neutrino generations is found to be Nv = 2.91 ± 0.26. Thus the hypothes…
Characterization of 233U alpha recoil sources for 229()Th beam production
2019
Radioactive $^{233}$U alpha recoil sources are being considered for the production of a thorium ion source to study the low-energy isomer in $^{229}$Th with high-resolution collinear laser spectroscopy at the IGISOL facility of the University of Jyv\"askyl\"a. In this work two different $^{233}$U sources have been characterized via alpha and gamma spectroscopy of the decay radiation obtained directly from the sources and from alpha-recoils embedded in implantation foils. These measurements revealed rather low $^{229}$Th recoil efficiencies of only a few percent. Although the low efficiency of one of the two sources can be attributed to its inherent thickness, the low recoil efficiency of th…
Time-of-flight telescope for heavy-ion RBS
2007
Abstract This paper describes a time-of-flight (TOF) spectrometer for Heavy-Ion Rutherford Backscattering Spectrometry (HI-RBS) recently installed at IMEC for thin film analysis. The TOF telescope allows the use of ion beams heavier than He, with advantages in terms of depth and mass resolution and sensitivity compared to conventional RBS based on planar Si detectors. The start timing-signal is produced by the secondary electrons emitted from a thin C foil when traversed by a backscattered ion; the electrons are deflected in an electrostatic mirror towards a Micro-channel plate (MCP) assembly which provides a fast timing response. The stop signal is obtained directly from a second MCP assem…
Estimates of the Nuclear Time Delay in Dissipative U + U and U + Cm Collisions Derived from the Shape of Positron andδ-Ray Spectra
1983
Positron and delta-ray spectra have been measured in coincidence with quasielastic scattered particles and fission fragments from the bombardment of Pd, U, and Cm targets with U beams of energies between 5.9 and 8.4 MeV/u. For collisions leading to a fission reaction, the atomic positron and delta-ray spectra fall off more steeply at high energies than expected from calculations based on pure Rutherford trajectories. A quantitative analysis of this effect is in accord with a nuclear contact time of about 10/sup -21/ s.
Synthesis and Oxidant Properties of Phase 1 Benzepine N-Oxides of Common Antipsychotic Drugs
2013
There is increasing evidence that cell constituents are oxidized by widely used antipsychotic drugs but until now the underlying chemistry has remained unclear. It is well known that such drugs readily undergo N-oxidation as a first key metabolic step. To gain insight into the problem, the tertiary phase 1 N-oxides of clozapine, olanzapine, quetiapine, and zotepine were synthesized, together with the N,S-dioxides of quetiapine and zotepine. These N-oxides were then subjected to well-established chemical transformations to test their oxidant properties in group VIII transition-metal-catalyzed reactions. In the osmium tetroxide catalyzed dihydroxylation of styrene or cinnamyl alcohol and in …
The taint of torture and the brazilian legal system
2019
In Brazil, the practice of torture intertwines deeply with its own history. The literature on the subject has had a greater intensification on its registers during the Dictatorial Regime (1964 to 1985). In spite of the Brazilian Constitution of 1988, Brazil only makes efforts to investigate the crimes of torture of this period to comply with the provisions of the United Nations in 2011. Within this scenario, the NationalTruth Commission (Law 12.528, of November 2011) was created with the purpose of clarifying the facts and circumstances of cases concerning human rights violations, as well as the Law on Access to Information (Law 12.527 of November 2011), which have regulated the constitutio…
Mono-, bi- and polynuclear complexes of dimethyldiphenylsilane, diphenylether and biphenyl with Cr, Co and Ru. Synthesis and 1H, 13C, 17O and 29Si NM…
1995
Abstract Mono- and bimetallic transition metal carbonyls of dimethyldiphenylsilane, Ph 2 Si(CH 3 ) 2 (L1), diphenylether, Ph 2 O (L2) and biphenyl, Ph 2 (L3): Ph 2 Si(CH 3 ) 2 Cr(CO) 3 ( 1 ), Ph 2 Si(CH 3 ) 2 [Cr(CO) 3 ] 2 ( 2 ), Ph 2 Si(CH 3 ) 2 Co 4 (CO) 9 ( 3 ), Ph 2 Si(CH 3 ) 2 [Co 4 (CO) 9 ] 2 ( 4 ), Ph 2 Si(CH 3 ) 2 Cr(CO) 3 Co 4 (CO) 9 ( 5 ), Ph 2 OCr(CO) 3 ( 6 ), Ph 2 OCo 4 (CO) 9 ( 7 ), Ph 2 ORu 6 C(CO) 14 ( 8 ), Ph 2 OCr(CO) 3 Co 4 (CO) 9 ( 9 ) and Ph 2 Ru 6 C(CO) 14 ( 10 ) have been prepared and characterized by means of 1 H, 13 C, 17 O and 29 Si NMR spectroscopy. The same order of the shielding effects induced by the transition metal (Co 1 H NMR chemical shifts of the η 6 -coord…