Search results for "STED"

showing 10 items of 2256 documents

Supramolecular functionalization and concomitant enhancement in properties of Au25 clusters

2014

We present a versatile approach for tuning the surface functionality of an atomically precise 25 atom gold cluster using specific host-guest interactions between ?-cyclodextrin (CD) and the ligand anchored on the cluster. The supramolecular interaction between the Au25 cluster protected by 4-(t-butyl)benzyl mercaptan, labeled Au25SBB18, and CD yielding Au25SBB18�?�CDn (n = 1, 2, 3, and 4) has been probed experimentally using various spectroscopic techniques and was further analyzed by density functional theory calculations and molecular modeling. The viability of our method in modifying the properties of differently functionalized Au25 clusters is demonstrated. Besides modifying their optoe…

Gold clusterta214Molecular modelta114General EngineeringSupramolecular chemistryGeneral Physics and AstronomyCombinatorial chemistrychemistry.chemical_compoundBenzyl mercaptanchemistryComputational chemistryMolecular ProbesSpectrometry Mass Matrix-Assisted Laser Desorption-IonizationCluster (physics)Surface modificationMoleculeGeneral Materials ScienceDensity functional theorySpectrophotometry UltravioletGoldAmerican Chemical Society; Host guest interactions; Inclusion complex; Optoelectronic properties; Quantum clusters; Spectroscopic technique; Supramolecular interactions; Surface functionalities; Biocompatibility; Cyclodextrins; Ligands; Metal ions; Supramolecular chemistry; Gold compounds; gold; article; chemistry; mass spectrometry; molecular probe; ultraviolet spectrophotometry; Gold; Molecular Probes; Spectrometry Mass Matrix-Assisted Laser Desorption-Ionization; Spectrophotometry UltravioletACS Nano
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Beyond Remittances

2016

Young, tertiary-educated emigrants see themselves, and are seen by their home country's government, as agents of economic and social change, especially if they can be incentivized to return home. In this paper we examine the barriers that prevent this positive impact from being fully realized, taking the case of Latvia, formerly part of the Soviet Union but since 2004 a member state of the European Union. We build our analysis on data from an online questionnaire (N = 307) and from narrative interviews (N = 30) with foreign-educated Latvian students and graduates. In moving beyond remittances, we examine knowledge transfer to the home country as a form of “social remittance” and break down …

GovernmentEconomic growth05 social sciencesSocial change0507 social and economic geographyLatvianComputer-assisted web interviewingDevelopmentlanguage.human_language0506 political scienceEmigrationPolitical science050602 political science & public administrationlanguagemedia_common.cataloged_instanceRemittanceEuropean union050703 geographyKnowledge transfermedia_commonSociology of Development
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Assessing the effectiveness of GraphoLearn combined with classroom instruction on phonics : a randomised control trial

2023

Proficiency in reading is a gateway for learning. However, the literacy rate in India stands at only 73% today. Many children studying in English-medium public schools often face a learning disadvantage through the schooling years since they struggle in learning to read in English which manifests into a struggle with reading to learn in later years. This disadvantage is more pronounced in children living in poverty. Thus, consistent efforts towards building foundational literacy skills of these children when developmentally appropriate is important to overcome the learning crisis. The aim of this study was to determine whether GraphoLearn, a computer assisted learning tool, combined with Gr…

GraphoLearncomputer-assisted learningfoundational literacytietokoneavusteinen oppiminenGraphoLearn-aligned classroom instructionphonics
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GraphoLearn India : The Effectiveness of a Computer-Assisted Reading Intervention in Supporting Struggling Readers of English

2018

India, a country with a population of more than 1.3 billion individuals, houses the world’s second largest educational system. Despite this, 100 of millions of individuals in India are still illiterate. As English medium education sweeps the country, many are forced to learn in a language which is foreign to them. Those living in poverty further struggle to learn English as it tends to be a language which they have no prior exposure to and no support at home for. Low-quality schools and poor instructional methods further exacerbate the problem. Without access to quality education, these individuals continue to struggle and are ultimately never given the chance to break the cycle of poverty.…

GraphoLearngrapheme-phoneme correspondenceFirst languagemedia_common.quotation_subjectlcsh:BF1-990PopulationEnglish language learnersIndiaPhonics050105 experimental psychologyoppimisvaikeudetIntervention (counseling)Reading (process)tietokoneavusteinen oppiminenCycle of povertyPsychologyIntiata5160501 psychology and cognitive scienceseducationkielen oppiminenta515General Psychologymedia_commonOriginal Researchreading interventionMedical educationeducation.field_of_studyPoverty4. Education05 social sciences1. No poverty050301 educationphonicsoppimispelitcomputer-assisted learninglcsh:PsychologylukutaitoPsychology0503 educationenglannin kieliPeriod (music)
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GrassPlot v. 2.00 : first update on the database of multi-scale plant diversity in Palaearctic grasslands

2019

Abstract: GrassPlot is a collaborative vegetation-plot database organised by the Eurasian Dry Grassland Group (EDGG) and listed in the Global Index of Vegetation-Plot Databases (GIVD ID EU-00-003). Following a previous Long Database Report (Dengler et al. 2018, Phyto- coenologia 48, 331–347), we provide here the first update on content and functionality of GrassPlot. The current version (GrassPlot v. 2.00) contains a total of 190,673 plots of different grain sizes across 28,171 independent plots, with 4,654 nested-plot series including at least four grain sizes. The database has improved its content as well as its functionality, including addition and harmonization of header data (land use,…

GrassPlotBiodiversitycomputer.software_genreGrasslandVegetation-plot database577: ÖkologieMacroecologybiodiversityvegetation- plot databasegeography.geographical_feature_categoryCommunityDatabaseLand usegrassland vegetationPalaearctic grasslandspecies-area relationship (SAR)nested plotPalaearcticGeographyscale dependenceSettore BIO/03 - Botanica Ambientale E ApplicatamacroecologyNestednessGlobal Index of Vegetation-Plot Databases (GIVD)Alpha diversityScale (map)computercommunity ecologyEurasian Dry Grassland Group (EDGG)
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Analyzing Protein-Protein Spatial-Temporal Dependencies from Image Sequences Using Fuzzy Temporal Random Sets

2008

Total Internal Reflection Fluorescence Microscopy (TIRFM) allows us to image fluorescenttagged proteins near the plasma membrane of living cells with high spatial-temporal resolution. Using TIRFM imaging of GFP-tagged clathrin endocytic proteins, areas of fluorescence are observed as overlapping spots of different sizes and durations. Standard procedures to measure protein-protein colocalization of dual labeled samples threshold the original graylevel images to segment areas covered by different proteins. This binary logic is not appropriate as it leaves a free tuning parameter which can influence the conclusions. Moreover, these procedures rely on simple statistical analysis based on corre…

Green Fluorescent ProteinsFuzzy setImage processingModels BiologicalFuzzy logicMeasure (mathematics)Fuzzy LogicProtein Interaction MappingImage Processing Computer-AssistedGeneticsComputer visionMolecular BiologyMathematicsbusiness.industryProteinsStatistical modelPattern recognitionFunction (mathematics)CovarianceClathrinEndocytosisComputational MathematicsMicroscopy FluorescenceComputational Theory and MathematicsModeling and SimulationArtificial intelligencebusinessMonte Carlo MethodRealization (probability)Journal of Computational Biology
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Efficient microwave-assisted synthesis of glycerol monodecanoate

2017

International audience; Solvent-free microwave-assisted synthesis was carried out to prepare 2,3-dihydroxypropyl decanoate, by esterification of decanoic acid in the presence of two distinct glycerol derivatives, glycidol, and glycerol carbonate, respectively. The process described is based on microwaves heating source with electrical power in the range of 200–400 W, involving stoichiometric proportions of decanoic acid and glycerol derivatives, and using catalytic amounts of TBAI used as organocatalyst. Conversion and selectivity rates of esterification reactions were monitored by 1H and 13C{1H} NMR spectroscopy. The predominantly formed ester, 2,3-dihydroxypropyl decanoate was fully chara…

Green chemistryBio-based building-blocksGlycerol derivatives02 engineering and technology010402 general chemistry01 natural sciences[ CHIM ] Chemical SciencesIndustrial and Manufacturing EngineeringCatalysischemistry.chemical_compoundGlycerolOrganic chemistry[CHIM]Chemical Sciences1-MonoacylglycerolComputingMilieux_MISCELLANEOUSGlycidolGeneral ChemistryDecanoic acidNuclear magnetic resonance spectroscopy021001 nanoscience & nanotechnology0104 chemical sciencesMicrowave-assisted organic chemistrychemistryGreen chemistry13. Climate action0210 nano-technologySelectivityStoichiometryFood ScienceBiotechnology
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A 3D Deep Neural Network for Liver Volumetry in 3T Contrast-Enhanced MRI.

2020

 To create a fully automated, reliable, and fast segmentation tool for Gd-EOB-DTPA-enhanced MRI scans using deep learning. Datasets of Gd-EOB-DTPA-enhanced liver MR images of 100 patients were assembled. Ground truth segmentation of the hepatobiliary phase images was performed manually. Automatic image segmentation was achieved with a deep convolutional neural network. Our neural network achieves an intraclass correlation coefficient (ICC) of 0.987, a Sørensen-Dice coefficient of 96.7 ± 1.9 % (mean ± std), an overlap of 92 ± 3.5 %, and a Hausdorff distance of 24.9 ± 14.7 mm compared with two expert readers who corresponded to an ICC of 0.973, a Sørensen-Dice coefficient of 95.2 ± 2.8 %, and…

Ground truthArtificial neural networkComputer sciencebusiness.industryDeep learningPattern recognitionImage processingImage segmentationConvolutional neural networkMagnetic Resonance ImagingHausdorff distanceLiverImage Processing Computer-AssistedHumansRadiology Nuclear Medicine and imagingSegmentationArtificial intelligenceNeural Networks ComputerbusinessRoFo : Fortschritte auf dem Gebiete der Rontgenstrahlen und der Nuklearmedizin
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HDlive ultrasound images in assisted reproduction treatment.

2012

Abstract The volume ultrasound technology software known as the HDlive technique represents an innovative tool, a step towards an even more realistic anatomical visualization of pelvic organ structures. HDlive can help improve physician–patient communication with the aid of life-like images and might prove useful in the field of assisted reproduction treatment. The clinical application of this novel ultrasound technology in assisted reproduction treatment deserves scientific evaluation.

GynecologyAdultPelvic organmedicine.medical_specialtymedicine.diagnostic_testReproductive Techniques Assistedbusiness.industryUltrasoundOvaryObstetrics and GynecologyVisualizationReproductive MedicineOvulation InductionImage Processing Computer-AssistedMedicineHumans3D ultrasoundMedical physicsFemalebusinessSoftwareDevelopmental BiologyPolycystic Ovary SyndromeUltrasonographyReproductive biomedicine online
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Development, validation and clinical use of an expanded pan-ethnic preconception carrier genetic screening test in assisted reproductive technology p…

2015

GynecologyGenetic screening testmedicine.medical_specialtyAssisted reproductive technologyReproductive Medicinebusiness.industryFamily medicinemedicine.medical_treatmentEthnic groupObstetrics and GynecologyMedicinebusinessFertility and Sterility
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