Search results for "SUBSTITUTION"
showing 10 items of 536 documents
Peptide classification using optimal and information theoretic syntactic modeling
2010
Accepted version of an article published in the journal: Pattern Recognition. Published version available on Sciverse: http://dx.doi.org/10.1016/j.patcog.2010.05.022 We consider the problem of classifying peptides using the information residing in their syntactic representations. This problem, which has been studied for more than a decade, has typically been investigated using distance-based metrics that involve the edit operations required in the peptide comparisons. In this paper, we shall demonstrate that the Optimal and Information Theoretic (OIT) model of Oommen and Kashyap [22] applicable for syntactic pattern recognition can be used to tackle peptide classification problem. We advoca…
Synthesis of new asymmetric xanthene dyes via catalyst-free SNAr with sulfur nucleophiles
2014
Addition of a single functional handle to the tricyclic moiety of fluorescein results in asymmetric xanthene dyes. Our synthesis of a new class of asymmetric xanthenes proceeds via an unusual SNAr with sulfur nucleophiles on electron rich aromatic xanthenes scaffolds in the absence of a metal catalyst. The resulting 3'-thioethers exhibit high photostability and are conveniently converted into reactive dyes for macromolecule labelling.
ChemInform Abstract: Synthesis of New Asymmetric Xanthene Dyes via Catalyst-Free SNAr with Sulfur Nucleophiles.
2014
Addition of a single functional handle to the tricyclic moiety of fluorescein results in asymmetric xanthene dyes. Our synthesis of a new class of asymmetric xanthenes proceeds via an unusual SNAr with sulfur nucleophiles on electron rich aromatic xanthenes scaffolds in the absence of a metal catalyst. The resulting 3′-thioethers exhibit high photostability and are conveniently converted into reactive dyes for macromolecule labelling.
SIMILARITY NETWORK FOR SEMANTIC WEB SERVICES SUBSTITUTION
2013
Web services substitution is one of the most challenging tasks for automating the composition process of multiple Web services. It aims to improve performances and to deal efficiently with Web services failures. Many existing solutions have approached the problem through classification of substitutable Web services. To go a step further, we propose in this paper a network based approach where nodes are Web services operations and links join similar operations. Four similarity measures based on the comparison of input and output parameters values of Web services operations are presented. A comparative evaluation of the topological structure of the corresponding networks is performed on a ben…
Where Alonso meets Sierpinski: an urban economic model of a fractal metropolitan area
2004
International audience; La coexistence d'activités résidentielles et agricoles dans des ceintures périurbaines caractérise de nombreuses aires métropolitaines modernes. Malheureusement, peu de modèles théoriques de l'économie urbaine prennent en compte ce type de mixité spatiale. L'article contribue à combler cette lacune : les auteurs présentent un modèle de localisation résidentielle (standard en économie urbaine) opérant dans un espace structuré par la géométrie spatiale. Plus précisément, d'un côté, un tapis de Sierpinski est utilisé pour rendre compte de l'organisation hiérarchisée de sites urbains et ruraux dans une aire métropolitaine. D'un autre côté, un ménage maximise, sous contra…
The diversion of institution
2010
The diversion of an institution is a notion which was established by the jurisprudence of the « French Court of Cassation », in the early 1990s, about adoption and the phenomena of surrogate mothers.From a chronological point of view, the diversion of institution first broke away from the studies of the doctrine dedicated to the abuse of rights , and was first used by the jurisprudence in labour law, before being dedicated to family rights. Because it deals with diversion of the finality of a legal system institution, it is often confused with the abuse of rights, the abuse of power, and fraud of the law or similar. Nevertheless, common points between the diversion of institution and other …
Le stockage agricole de l'eau : l'adaptation idéale au changement climatique?
2019
International audience; Déjà à l’œuvre, le changement climatique affecte la disponibilité des ressources hydriques, en particulier pour les besoins agricoles. Face aux risques de sécheresses estivales plus sévères, des projets de stockage de l’eau hivernale se multiplient pour satisfaire la demande d’irrigation. La stratégie se déploie cependant dans un cadre normatif imparfait et un contexte d’oppositions citoyennes radicales. Stocker l’eau ou en réduire la consommation ? Telle serait l’alternative dans laquelle se trouve la future agriculture. Une voie médiane, moins clivante, est pourtant envisageable, fondée sur un partage de la ressource à l’échelle territoriale et associée à une trans…
Tourisme procréatif : l'enfant hors la loi française
2006
Numéro intitulé : Filiations; National audience
Substitutional carbon defects in silicon: A quantum mechanical characterization through the infrared and Raman spectra
2020
EUROfusion Enabling Research Project, Grant/Award Number: ENR‐MFE19.ISSP‐UL‐02; GENCI, Grant/Award Number: 2018‐[A0050810537] (Ph. D'Arco) Access to the HPC resources of CINES/IDRIS/TGCC obtained thanks to the grant 2018-[A0050810537]
Extending existential feeling through sensory substitution
2023
AbstractIn current philosophy of mind, there is lively debate over whether emotions, moods, and other affects can extend to comprise elements beyond one’s organismic boundaries. At the same time, there has been growing interest in the nature and significance of so-called existential feelings, which, as the term suggests, are feelings of one’s overall being in the world. In this article, I bring these two strands of investigation together to ask: can the material underpinnings of existential feelings extend beyond one’s skull and skin? To begin, I introduce and adopt a componential-systemic view of extended affectivity. In doing so, I specify the vehicle externalist criteria for extension em…