Search results for "Surfaces"
showing 10 items of 2837 documents
Patterning of Magnetic Bimetallic Coordination Nanoparticles of Prussian Blue Derivatives by the Langmuir–Blodgett Technique
2012
We report a novel method to prepare patterns of nanoparticles over large areas of the substrate. This method is based on the adsorption of the negatively charged nanoparticles dispersed in an aqueous subphase onto a monolayer of the phospholipid dipalmitoyl-l-α-phosphatidylcholine (DPPC) at the air-water interface. It has been used to prepare patterns of nanoparticles of Prussian blue analogues (PBA) of different size (K(0.25)Ni[Fe(CN)(6)](0.75) (NiFe), K(0.25)Ni[Cr(CN)(6)](0.75) (NiCr), K(0.25)Ni[Co(CN)(6)](0.75) (NiCo), Cs(0.4)Co[Cr(CN)(6)](0.8) (CsCoCr), and Cs(0.4)Co[Fe(CN)(6)](0.9) (CsCoFe)). The behavior of DPPC monolayer at the air-water interface in the presence of the subphase of P…
EIS and Ac-electrogravimetry study of PB films in KCl, NaCl, and CsCl aqueous solutions
2003
Prussian Blue films have been studied by means of ac-electrogravimetry, electrochemical impedance spectroscopy, and electrochemical quartz crystal microbalance in different aqueous salt solutions. Impedance data was interpreted in terms of a model based on a potential drop at the electrode/film interface and a potential drop at the film/solution interface. Quantitative results obtained by the fitting of impedance and ac-electrogravimetry allow to conclude that the main contribution to the potential drop at the film/solution interface is due to the dehydration-hydration process of cations on entering or leaving the film.
Solvent-Independent Electrode Potentials of Solids Undergoing Insertion Electrochemical Reactions: Part III. Experimental Data for Prussian Blue Unde…
2012
Prussian blue-modified electrodes immersed in K+-containing solutions can be used to obtain a solvent-independent redox potential system. On the basis of theoretical modeling of diffusion processes occurring under the conditions of voltammetry of immobilized particles, voltammetric and chronoamperometric data can be combined to obtain solvent-independent electrode potentials for the K+-assisted one-electron reduction of Prussian blue to Berlin white. Data for water, MeOH, EtOH, MeCN, DMS, DMF, and NM are provided.
Identification of Processes Associated with Different Iron Sites in the Prussian Blue Structure by in Situ Electrochemical, Gravimetric, and Spectros…
2012
The physicochemical properties of Prussian blue films are strongly dependent on the ratio Fe3+/Fe2+ in the structure. This ratio can be modulated by electrochemical techniques such as cyclic voltammetry, and some information about physicochemical properties can be extracted from in situ auxiliary techniques. Prussian blue films have been studied by the use of in situ vis–NIR spectroscopy, quartz crystal microbalance, and electrochemical techniques (cyclic voltammetry and electrochemical impedance spectroscopy). By cyclic voltammetry + absorbance derivative curves + mass derivative curves, it has been possible to identify at least three different processes during the reduction of Prussian bl…
Innovative Combination of Three Alternating Current Relaxation Techniques: Electrical Charge, Mass, and Color Impedance Spectroscopy. Part II: Prussi…
2009
The simultaneous recording of three impedance functions (electrochemical impedance, color, and mass impedance) allows the role of different species to be distinguished easily during electrochemical processes in conducting and electrochromic films. Herein, this technique has been applied to the study of the Prussian blue films at several potentials between the blue form (Prussian blue) and the colorless form (Everitt’s salt). At these potentials, these electrochemical reactions take place by means of exchange of different ions. Thus, the exchange of potassium cations is related to the changes of absorbance at 690 nm, whereas the exchange of protons does not introduce color changes at this wa…
Sol-gel produced humidity sensor
1993
Abstract The sol-gel produced polycrystalline Prussian Blue thick films as planar humidity sensors have been investigated by impedance spectroscopy. The equivalent circuit used allows simulation in all the investigated r.h. range (10–100%). The region of changes of sample resistance is about five orders, which is enough for high measuring sensitivity.
Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr5.5(CN)12·11.5H2O
2013
The magnetoresistance (MR) effect of thin films of the Prussian Blue Analogue (PBA) Cr5.5(CN)12·11.5H2O, prepared by electrochemical deposition, has been measured using the standard two-point probe method. This molecule-based ferrimagnetic material, with a Tc = 240 K, exhibits MR up to 2% at 6 T and 200 K.
Interfacial role of Cesium in Prussian Blue Films
2015
The simultaneous measurement of current, mass, motional resistance and absorbance magnitudes allows the electrochemical cation insertion process to be explained during successive voltammograms around the Prussian Blue ⇄ Everitt's Salt system in CsCl aqueous acid solutions. Two different ways for the entrance of cesium to the porous structure of Prussian Blue have been observed. Firstly, Cs+ is spontaneously absorbed as CsCl into the interstitial cluster of water of the channels formed by the Fe(II)low spinCNFe(III)high spin structural units of the crystal. This chemical absorption involves a spontaneous substitution of inner water molecules of the interstitial water cluster. Finally, Cs+ …
Study of localized pulsed laser depassivation by interferometric probe
1997
Optical interferometry has been implemented as a novel approach to monitor sensitively the localized pulsed laser depassivation of iron or stainless steel samples. This new method, complementing the previous transient current measurements and channel flow double-electrode, is based on the time-resolved measurement of the rear surface displacement of the test sample induced by the laser generated ultrasonic wave. The removal of any material, such as the passive film, from the irradiated surface results in an enhancement of the longitudinal component of the laser generated ultrasonic wave, which is manifested in a change of the displacement characteristics of the rear surface of the test samp…
Ulrich bundles on K3 surfaces
2019
We show that any polarized K3 surface supports special Ulrich bundles of rank 2.