Search results for "Tact"
showing 10 items of 1313 documents
Half-sandwich Mo(III) complexes with asymmetric diazadiene ligands
2006
The asymmetric 1,4-diazadiene ligands R ∗ N CHCH NR ∗ [R ∗ = ( S )-CH(CH 3 )Ph], R 2 ∗ dad , and 2,2′-bis(4-ethyloxazoline), as-ox, have been used to generate half-sandwich Mo III derivatives by addition to Cp 2 Mo 2 Cl 4 . Ligand R 2 ∗ dad affords a mononuclear, paramagnetic 17-electron product, CpMoCl 2 ( R 2 ∗ dad ) , whereas as-ox leads to the isolation of a dinuclear compound where only one molecule of ligand has been added per two Mo atoms, Cp 2 Mo 2 Cl 4 (as-ox). In the presence of free as-ox, this compound coexists with the paramagnetic mononuclear complex in solution. Both products are capable of controlling the radical polymerization of styrene under typical atom transfer radical…
Mixed and Nitsche's discretizations of frictional contact-mechanics in fractured porous media
2023
This work deals with the discretization of single-phase Darcy flows in fractured and deformable porous media, including frictional contact at the matrix-fracture interfaces. Fractures are described as a network of planar surfaces leading to so-called mixed dimensional models. Small displacements and a linear poro-elastic behavior are considered in the matrix. One key difficulty to simulate such coupled poro-mechanical models is related to the formulation and discretization of the contact mechanical sub-problem. Our starting point is based on the mixed formulation using facewise constant Lagrange multipliers along the fractures representing normal and tangential stresses. This is a natural c…
HHT-α and TR-BDF2 schemes for dynamic contact problems
2023
This work focuses on the numerical performance of HHT-α and TR-BDF2 schemes for dynamic frictionless unilateral contact problems between an elastic body and a rigid obstacle. Nitsche's method, the penalty method, and the augmented Lagrangian method are considered to handle unilateral contact conditions. Analysis of the convergence of an opposed value of the parameter α for the HHT-α method is achieved. The mass redistribution method has also been tested and compared with the standard mass matrix. Numerical results for 1D and 3D benchmarks show the functionality of the combinations of schemes and methods used.
Ethiopian Semitic Languages
2006
The article presents an overview of the Ethiopian Semitic (ES) languages spoken in the Horn of Africa. Among the presently spoken Semitic languages, ES languages comprise more than 80% and are divided into a northern and a southern group. Although this division is basically regional, there is a strong morpho-syntactic support for this classification. ES languages show a higher complexity in the use of concatenative and nonconcatentative morphemes for various grammatical categories. This rich morphological behavior, the SOV order, and other peculiar morphophonemic features are assumed to be the result of language contact, but sufficient data for this claim are still lacking.
Production of refractory elements close to the Z=N line using the ion-guide technique
1998
Production of neutron-deficient isotopes of refractory elements in the A = 80-88 region was studied using the IGISOL technique and the 165 MeV Si-32 + Ni-nat reaction. Radioactive isotopes of Y through Mo could be produced up to the M-T = + 1 line. New information on the decay of the A = 82 and 85 nuclei, including a more detailed decay scheme and more accurate half-life for Y-82, was obtained. (C) 1998 Elsevier Science B.V. All rights reserved.
Development of micro-contact printing of osteosarcoma cells using MeV ion beam lithography
2009
Abstract For investigation of spatial effects in signalling between cells and also signal substances that trigger cell proliferation and behaviour we are developing a micro Contact Printing process ( μ CP ) . In order to allow printing of cells stamps with high aspect ratio are required and these have been fabricated using Programmed Proximity Aperture Lithography (PPAL) with 3 MeV 4 He 2 + ions to produce PMMA masters for casting the stamps in PDMS. A simple printing device was developed and the first results using this to print human osteosarcoma cells is demonstrated.
State of the art of CPMAS 13C-NMR spectroscopy applied to natural organic matter
2004
A number of different techniques are presently available for characterizing humified natural organic matter (NOM). Carbon-13 nuclear magnetic resonance spectroscopy (13C-NMR) in the solid state using cross-polarization (CP) and magic angle spinning (MAS) represents the most powerful experimental approach used to collect direct information on the structural and conformational characteristics of humic carbon backbones. Despite the problems due to the presence of paramagnetic impurities and the generally low organic matter concentration, cross-polarization magic angle spinning 13C-NMR spectroscopy (CPMAS 13C-NMR) is applied in soil chemistry and geochemistry mainly because of its relevance in …
Wettability and compositional analysis of hydroxyapatite films modified by low and high energy ion irradiation
2008
Abstract Hydroxyapatite-like thin films on silicon substrate were deposited using atomic layer deposition and were subjected to irradiation with Ar ions accelerated through 0.6–1.2 kV as well as 2 MeV 16 O + ions. After low energy Ar irradiation a significant reduction in contact angle was observed. However, the Ca/P atomic ratio remained unchanged. No reduction in contact angle was seen for high energy 16 O + irradiation. Atomic force microscopy showed the enhancement of floral-like pattern after low energy Ar bombardment while high energy oxygen irradiation lead to raised islands on as-deposited films.
Development of new CdZnTe detectors for room-temperature high-flux radiation measurements
2017
Recently, CdZnTe (CZT) detectors have been widely proposed and developed for room-temperature X-ray spectroscopy even at high fluxes, and great efforts have been made on both the device and the crystal growth technologies. In this work, the performance of new travelling-heater-method (THM)-grown CZT detectors, recently developed at IMEM-CNR Parma, Italy, is presented. Thick planar detectors (3 mm thick) with gold electroless contacts were realised, with a planar cathode covering the detector surface (4.1 mm × 4.1 mm) and a central anode (2 mm × 2 mm) surrounded by a guard-ring electrode. The detectors, characterized by low leakage currents at room temperature (4.7 nA cm−2 at 1000 V cm−1), a…
Electrical properties of Au/CdZnTe/Au detectors grown by the boron oxide encapsulated Vertical Bridgman technique
2016
Abstract In this work we report on the results of electrical characterization of new CdZnTe detectors grown by the Boron oxide encapsulated Vertical Bridgman technique (B-VB), currently produced at IMEM-CNR (Parma, Italy). The detectors, with gold electroless contacts, have different thicknesses (1 and 2.5 mm) and the same electrode layout, characterized by a central anode surrounded by a guard-ring electrode. Investigations on the charge transport mechanisms and the electrical contact properties, through the modeling of the measured current–voltage ( I – V ) curves, were performed. Generally, the detectors are characterized by low leakage currents at high bias voltages even at room tempera…