Search results for "UV"

showing 10 items of 7629 documents

DNA-binding of zinc(II) and nickel(II) salphen-like complexes extrapolated at 1 M salt concentration: Removing the ionic strength bias in physiologic…

2020

Abstract The DNA-binding of two salphen-like metal complexes of nickel(II) (1) and zinc(II) (2) was investigated in different ionic strength solutions by absorption spectroscopy. The data analysis allowed us to obtain the values of their extrapolated DNA-binding constant in physiological conditions, with DNA-binding strength in the order Ni > Zn, and to give relative weight to the electrostatic and non-electrostatic contributions to their DNA-interaction.

Absorption spectroscopyInorganic chemistryStatic ElectricitySalt (chemistry)chemistry.chemical_elementRelative weightZincPhenylenediaminesSodium Chloride010402 general chemistry01 natural sciencesBiochemistryInorganic ChemistryMetalchemistry.chemical_compoundIonic strengthCoordination ComplexesNickelSalphenchemistry.chemical_classification010405 organic chemistryChemistrySpectrum AnalysisOsmolar ConcentrationDNA0104 chemical sciencesNickelZincIonic strengthSettore CHIM/03 - Chimica Generale E Inorganicavisual_artvisual_art.visual_art_mediumUV–visible absorptionDNAJournal of Inorganic Biochemistry
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Ag11(SG)7 : A New Cluster Identified by Mass Spectrometry and Optical Spectroscopy

2014

We report a one-step and high yield synthesis of a red-luminescent silver cluster with the molecular formula, Ag11(SG)7 (SG: glutathionate) via reduction of silver ions by sodium borohydride in the presence of the tripeptide, glutathione (GSH). The as-prepared cluster shows prominent absorption features at 485 and 625 nm in its UV-vis absorption spectrum. Aging of the as-prepared cluster solution led to the disappearance of the 625 nm peak, followed by broadening of the 485 nm peak to give three maxima at ?487, 437, and 393 nm in its absorption spectrum. These peaks remain unchanged even after polyacrylamide gel electrophoresis (PAGE), where a single band was observed confirming high purity…

Absorption spectroscopyta114Electrospray ionizationAnalytical chemistryMass spectrometryAbsorption spectra; Density functional theory; Electrodeposition; Electromagnetic wave absorption; Electrophoresis; Electrospray ionization; Isotopes; Light absorption; Mass spectrometry; Metal ions; Potable water; Spectrometry; Ultraviolet spectroscopy; Absorption features; Electrospray ionization mass spectrometry; High yield synthesis; Molecular formula; Optical spectroscopy; Polyacrylamide gel electrophoresis; Sodium boro hydrides; UV-VIS absorption spectra; Absorption spectroscopySurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonSodium borohydridechemistry.chemical_compoundGeneral EnergyUltraviolet visible spectroscopychemistryPhysical and Theoretical ChemistryAbsorption (electromagnetic radiation)Spectroscopyta116Journal of Physical Chemistry C
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LATIN AMERICA AND ABYA YALA IN TEACHING SPANISH HISTORY: THE "DISCOVERY", THE CONQUEST AND CONTROVERSIES OF THE BLACK LEGEND

2019

RESUMO O trabalho explicita as representações contemporâneas da História da América no ensino de História na Espanha. Explicita e problematiza as configurações textuais e iconográficas que pretendem ensinar uma história do “descobrimento”, da conquista e da colonização da América. Usou-se a metodologia da pesquisa bibliográfica e de campo, com técnica de fichamento e observações analíticas de obras historiográficas contemporâneas, livros didáticos e lugares de memória (museus e monumentos históricos). Em relação aos manuais didáticos, foram selecionados e analisados 18 livros de ensino de História editados por seis editoras no período de 2000 a 2015. Analisou-se a história do “descobrimento…

Abya Yala021110 strategic defence & security studiesdescobrimento05 social sciencesenseignement d'Histoire0211 other engineering and technologies02 engineering and technologyAmérica Latina Abya Yaladécouverteensino de História0506 political scienceEducationteaching of HistoryEnsino de HistóriaLatin AmericaDescobrimento; América Latina; Abya YalaAmérica Latina050602 political science & public administrationenseñanza de la historia descubrimientol'Amérique Latinediscovery
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Nākotnes perspektīvas suverēnās labklājības fondu darbībā Persijas Līča Sadarbības padomes reģionā

2015

Mana bakalaura darba tēma ir „Nākotnes perspektīvas suverēnās labklājības fondu darbībā Persijas Līča Sadarbības Padomes reģionā”. Mērķis ir izpētīt, suverēnās labklājības fondu attīstību nākotnē. Uzdevumi - starptautiskās finanšu sistēmas raksturojums, reģiona un turētājvalstu ekonomisko rādītāju, dokumentācijas un informācijas avotu analīze. Pētījums - trīs suverēnās labklājības fondu rādītāju analīze, stratēģiju noteikšana, darbības apjoma pieauguma radītāju analīze un secinājumu veidošana. Pētījuma rezultāti apstiprina, ka suverēnās labklājības fondi Persijas Līča Sadarbības padomes reģionā ir valstu alternatīva nākotnes paaudžu labklājības veidošanā.

Abū Dabī investīciju fondsKuveitas Investīciju fondsPersijas līča Sadarbības PadomeEkonomikaSaūda Arābijas Monetārā aģentūraSuverēnās labklājības fonds
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GEOV1: LAI, FAPAR essential climate variables and FCOVER global time series capitalizing over existing products. Part 2: Validation and intercomparis…

2013

International audience; This paper describes the scientific validation of the first version of global biophysical products (i.e., leaf area index, fraction of absorbed photosynthetically active radiation and fraction of vegetation cover), namely GEOV1, developed in the framework of the geoland-2/BioPar core mapping service at 1 km spatial resolution and 10-days temporal frequency. The strategy follows the recommendations of the CEOS/WGCV Land Product Validation for LAI global products validation. Several criteria of performance were evaluated, including continuity, spatial and temporal consistency, dynamic range of retrievals, statistical analysis per biome type, precision and accuracy. The…

Accuracy and precision010504 meteorology & atmospheric sciencescouvert végétalcomparaison de modèlesBiomecritère de performanceSoil ScienceMagnitude (mathematics)Context (language use)01 natural sciencesGEOV1;Vegetation variables;Validation;GMES;Land monitoring core servicevalidation scientifiquefraction of absorbed photosynthetically active radiation (fAPAR)GEOV1ValidationfcoverFraction (mathematics)Computers in Earth SciencesLeaf area indexvariable climatiqueMilieux et Changements globauxfraction de couvert0105 earth and related environmental sciencesRemote sensinggmescarte de référenceanalyse statistiquefaparLand monitoring core serviceGeology04 agricultural and veterinary sciencesresolution spatiale15. Life on landComputer scienceLAIindice de surface foliaireSeaWiFSbiome13. Climate actionPhotosynthetically active radiationInformatique (Sciences cognitives)surveillance de l'environnement[SDE]Environmental Sciences040103 agronomy & agriculture0401 agriculture forestry and fisheriesEnvironmental scienceVegetation variables
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L'application de la loi du 15 mai 2001 réformant l'article 2061 du code civil aux clauses compromissoires conclues antérieurement à son entrée en vig…

2003

International audience; (TGI Paris, ord. réf., 8 oct. 2002, Sté Euroconsultaudit c/ Thoman et Windenberger Jenner, D. 2003, p. 1928, note B. Moreau ; Rev. arb. 2003.199, note L. Jaegger)

Activité professionnelle[SHS.DROIT]Humanities and Social Sciences/Law[SHS.DROIT] Humanities and Social Sciences/LawLoi du 15 mai 2001 sur les nouvelles régulations économiquesARBITRAGEClause compromissoireValidité
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Treatment Results In Acute Myeloid Leukemia Over a Time Period Of 20 Years: Analysis Of The German-Austrian Acute Myeloid Leukemia Study Group (AMLSG)

2013

Abstract Background Overall survival (OS) in acute myeloid leukemia (AML) treated with intensive chemotherapy has improved over the last 20 year especially in younger adults (18-60 years) but still remains poor in older patients (>60 years) (Döhner et al. Blood 2010). The German-Austrian AMLSG performed controlled prospective treatment trials since 1993 starting with a risk-adapted approach (phase I, 1993-1997), followed by randomized and risk-adapted treatment strategies based on cytogenetic risk groups (phase II, 1997-2002); since 2003 addition of differentiating agents and HiDAC inhibitors to intensive induction therapy was evaluated (phase III, 2003-2007). Of note, until 2007 younger…

Acute promyelocytic leukemiamedicine.medical_specialtyPediatricsmedicine.medical_treatmentImmunologyHematopoietic stem cell transplantationBiochemistry03 medical and health sciences0302 clinical medicineInternal medicinemedicineMyelofibrosisNeoadjuvant therapy030304 developmental biology0303 health sciencesChemotherapybusiness.industryMortality rateCell BiologyHematologymedicine.diseasePomalidomideChemotherapy regimen3. Good healthbusiness030215 immunologymedicine.drugBlood
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Management of acute promyelocytic leukemia: updated recommendations from an expert panel of the European LeukemiaNet

2019

Abstract Since the comprehensive recommendations for the management of acute promyelocytic leukemia (APL) reported in 2009, several studies have provided important insights, particularly regarding the role of arsenic trioxide (ATO) in frontline therapy. Ten years later, a European LeukemiaNet expert panel has reviewed the recent advances in the management of APL in both frontline and relapse settings in order to develop updated evidence- and expert opinion–based recommendations on the management of this disease. Together with providing current indications on genetic diagnosis, modern risk-adapted frontline therapy, and salvage treatment, the review contains specific recommendations for the …

Acute promyelocytic leukemiamedicine.medical_specialtymedicine.medical_treatmentImmunologyMEDLINETretinoinDiseaseHemorrhagic DisordersBiochemistryHemorrhagic disorderEuropean LeukemiaNetArsenic TrioxideLeukemia Promyelocytic AcutePregnancyRecurrenceHumansMedicineDisease management (health)Intensive care medicineSpecial ReportNeoadjuvant therapyAPL Differentiation SyndromeAgedbusiness.industryDisease ManagementCell BiologyHematologymedicine.diseasePractice Guidelines as TopicFemalebusinessBlood
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El «Llibre de les Bèsties» (1287-1289) de Ramon Llull: anàlisi d'adaptacions infantils i juvenils

2020

En aquest article presentem una anàlisi de les sis adaptacions que del Llibre de les Bèsties (1287- 1289) es van publicar per al públic infantil i juvenil amb motiu de l’Any Llull (2015-2016). Després de presentar la figura de Ramon Llull com a escriptor de referència en l’època medieval i de situar Llibre de les Bèsties dins de la producció literària de Llull, analitzem els paratextos extratextuals i textuals de les sis adaptacions aquí estudiades. La presentació i l’anàlisi d’aquests paratextos ens permet determinar, d’una banda, a quin tipus de nivell lector va adreçada cada adaptació i quin treball didàctic en pot resultar; i, d’altra banda, com el missatge que Llull transmet en aquesta…

AdaptacionsLinguistics and Languageliteratura infantil i juvenilRamon LlullLiteratura infantil i juvenil“UNESCO:HISTORIA”adaptacionsLlibre de les BèstiesparatextosLanguage and Linguistics
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Verschiedenartige Additionsreaktionen von 2-Cyano-2-propylradikalen an p-Tolylmethacrylat und 4-Cyclohexylphenylmethacrylat

1976

Durch Umsetzung von p-Tolylmethacrylat oder 4-Cyclohexylphenylmethacrylat in stark verdunnter, siedender Benzollosung mit einem sehr grosen Uberschus an 2,2′-Azoisobutyronitril wurden die erwarteten Additionsprodukte mit 2-Cyano-2-propylradikalen (1) erhalten, namlich p-Tolyl- bzw. 4-Cyclohexylphenyl-[4-cyano-2-(2-cyano-2-propyl)-2,4-dimethyl]valerianat (3a bzw. 3b) mit rund 50% Ausbeute. Daneben wurden p-Tolyl- bzw. 4-Cyclohexylphenyl-(4-cyano-4-methyl-2-methylen)valerianat (4a bzw. 4b), p-Tolyl- bzw. 4-Cyclohexylphenyl-[4-cyano-2(2-cyano-2-methyl-1-propyl)-4-methyl]valerianat (5a bzw. 5b), p-Tolyl- bzw. 4-Cyclohexylphenyl-(4-cyano-2,4-dimethyl)valerianat (6a bzw. 6b) und p-Tolyl- bzw. 4-C…

Addition reactionUv spectraChemistryPolymer chemistryDisproportionationMass spectrometricDie Makromolekulare Chemie
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