Search results for "computing"

showing 10 items of 25279 documents

Witnessing and measuring the impacts of cryosphere changes in the High Arctic

2016

International audience

cryosphere changesHigh Arctic[SHS.GEO] Humanities and Social Sciences/Geography[SHS.GEO]Humanities and Social Sciences/GeographyComputingMilieux_MISCELLANEOUS[ SHS.GEO ] Humanities and Social Sciences/Geography
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Catena-poly[[di-n-butyltin(IV)]-mu-trifluoromethanesulfonato-[[di-n-butyl(trifluoromethanesulfonato)tin(IV)]-di-mu-hydroxo]]

2006

International audience

crystal structure010405 organic chemistryChemistrycatena complexGeneral Chemistry[CHIM.INOR]Chemical Sciences/Inorganic chemistry010402 general chemistryCondensed Matter Physics01 natural sciencesMedicinal chemistry0104 chemical sciences3. Good healthtinGeneral Materials ScienceComputingMilieux_MISCELLANEOUS
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On the mechanistic behavior of highly efficient palladium-tetraphosphine catalytic systems for cross-coupling reactions: first spectroscopic and elec…

2008

Electrochemical studies carried out in conjunction with 31P NMR spectroscopy on the palladium(II)/palladium(0) halogeno complexes of the tetraphosphine 1,1′,2,2′-tetrakis(diphenylphosphino)-4,4′-di...

crystal structureDenticityredox reactionoxidative additiontetraphosphinechemistry.chemical_elementmechanism010402 general chemistryElectrochemistryPhotochemistry01 natural sciencesCoupling reactionCatalysisInorganic Chemistry[ CHIM.CATA ] Chemical Sciences/Catalysiscross-coupling reactionsferrocenylpolyphosphine complexesPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUSelectrochemical studies010405 organic chemistryChemistryOrganic Chemistry[CHIM.CATA]Chemical Sciences/CatalysispalladiumCombinatorial chemistryOxidative addition0104 chemical sciences3. Good healthcatalytic systemsreaction kinetics31p nmr spectroscopyPalladium
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Crystal structure of the diglycidyl ether of eugenol

2017

The diep­oxy monomer (DGE-Eu) was synthesized from eugenol by a three-step reaction. It consists of a 1,2,4-tris­ubstituted benzene ring substituted by diglycidyl ether, a meth­oxy group and a methyl­oxirane group. The three-membered oxirane rings are inclined to the benzene ring by 61.0 (3) and 27.9 (3)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds, forming layers parallel to the ab plane.

crystal structureDiglycidyl etherEpoxideep­oxy thermoset prepolymer02 engineering and technologyCrystal structure010402 general chemistryRing (chemistry)01 natural scienceseugenol derivativeResearch CommunicationsCrystalchemistry.chemical_compound[ CHIM.CRIS ] Chemical Sciences/CristallographyPolymer chemistry[CHIM.CRIS]Chemical Sciences/Cristallography[CHIM]Chemical SciencesGeneral Materials Science[CHIM.CRIS] Chemical Sciences/CristallographyBenzeneComputingMilieux_MISCELLANEOUSbio-based mol­eculebio-based moleculeCrystallographyHydrogen bondGeneral Chemistry[PHYS.MECA]Physics [physics]/Mechanics [physics]021001 nanoscience & nanotechnologyCondensed Matter Physicshydrogen bonding3. Good health0104 chemical sciencesCrystallographyMonomerchemistryQD901-999oxiraneepoxy thermoset prepolymer[PHYS.MECA] Physics [physics]/Mechanics [physics]0210 nano-technology
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Selective formation of a unique diphosphonium-diphosphine from a tetraphosphine double protonation induced by zirconium salts

2008

A mixed ferrocenyl diphosphonium-diphosphine cation, associated with two [ZrCl(5).thf](-) anions, is obtained from a ferrocenyl tetraphosphine, as a unique didentate ionic metalloligand in a perfectly selective reaction induced by ZrCl(4) in THF.

crystal structureZirconiumSelective reaction010405 organic chemistryChemistryprotonationInorganic chemistry[ CHIM.COOR ] Chemical Sciences/Coordination chemistryzirconiumIonic bondingchemistry.chemical_elementProtonationphosphonium010402 general chemistry01 natural sciencesferrocenyl0104 chemical sciences3. Good healthInorganic ChemistryPolymer chemistrypolyphosphine[CHIM.COOR]Chemical Sciences/Coordination chemistryComputingMilieux_MISCELLANEOUSDalton Transactions
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Synthesis, spectroscopic study, and crystal structure of a new organotin(IV) selenate derivative

2018

Abstract The polymeric organotin(IV) selenate complex [(Me3Sn)3(SeO4)(OH)]n (1) has been isolated as single crystals from the reaction of [(Me2NH2)2SeO4] and Me3SnCl in methanol. In the solid state, compound 1 was characterized by X-ray diffraction analysis, Fourier transform-infrared spectroscopy, and elemental analysis. 1 crystallizes in the orthorhombic system space group Pbca with a=11.0231(2) Å, b=16.3461(3) Å, c=20.9945(4) Å, α=β=γ=90°, V=3782.89(12) Å3, and Z=8. Its structure can be described as a polymeric zigzag chain based on Me3Sn moieties linked by tridentate selenate anions. Pendant (Me3Sn)2OH groups are also connected to the chain, according to a syndiotactic organization, and…

crystal structurechemistry.chemical_elementCrystal structureorganotin(iv)010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesSelenateoxoanionschemistry.chemical_compoundComputational chemistryMaterials Chemistry[CHIM]Chemical Sciences[CHIM.COOR]Chemical Sciences/Coordination chemistryseleniumQD1-999ComputingMilieux_MISCELLANEOUSMetals and AlloysGeneral ChemistryCondensed Matter Physics0104 chemical sciencesChemistrychemistrysn-o-se moietySeleniumDerivative (chemistry)Main Group Metal Chemistry
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Crystal structure of 2-methyl-1H-imidazol-3-ium hydrogen oxalate dihydrate

2016

In the title mol­ecular salt 2-methyl-1H-imidazol-3-ium hydrogen oxalate dihydrate, N—H⋯(O,O) and O—H⋯O hydrogen bonds link the components into a bilayer-like assembly.

crystal structurecrystal structure organic salt monosubstituted imidazolium hydrogen oxalate hydrogen bonds monohydrateHydrogenOxalic acidInorganic chemistrychemistry.chemical_elementSalt (chemistry)Crystal structuremonosubstituted imidazolium010402 general chemistry010403 inorganic & nuclear chemistry[ CHIM ] Chemical Sciences01 natural sciencesOxalateResearch Communicationslaw.inventionCrystalchemistry.chemical_compoundlawmonohydrate[CHIM.CRIS]Chemical Sciences/Cristallography[CHIM]Chemical SciencesGeneral Materials ScienceCrystallizationComputingMilieux_MISCELLANEOUSchemistry.chemical_classificationCrystallographyHydrogen bondGeneral ChemistryCondensed Matter Physics0104 chemical sciences3. Good healthCrystallographychemistryQD901-999hydrogen bondsorganic salthydrogen oxalateActa Crystallographica Section E Crystallographic Communications
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Crystal structure of tricarbonyl(μ-diphenylphosphido-κ2P:P)(methyldiphenylsilyl-κSi)bis(triphenylphosphane-κP)iron(II)platinum(0)(Fe—Pt)

2015

The title compound belongs to the large family of heterodinuclear phosphide-bridged complexes. The Fe—Pt bond is of 2.7738 (4) Å and there is an unprecedented arrangement of the silyl ligand in a trans-position with respect to the metal–metal vector in the family of phosphide-bridged iron–platinum heterobimetallics.

crystal structuremetal–metal bondSilylationStereochemistrychemistry.chemical_elementCrystal structureMedicinal chemistryResearch Communicationslcsh:Chemistrychemistry.chemical_compoundphosphido bridges[CHIM]Chemical SciencesGeneral Materials Sciencediphenylmethylsilyl ligandComputingMilieux_MISCELLANEOUSdi­phenyl­methyl­silyl ligandLigandTricarbonGeneral ChemistryCondensed Matter Physics3. Good healthiron complexeslcsh:QD1-999chemistryheterobimetallicsPlatinumplatinum complexesActa Crystallographica Section E Crystallographic Communications
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Cuerpos adolescentes en el cine español 1982-1998

2018

El presente artículo propone esbozar un panorama de las representaciones de adolescentes en el cine español durante los gobiernos socialistas a partir de 1982 y hasta 1998. Tras la reivindicación de la libertad propia de la Transición, en que el adolescente tenía a menudo la autonomía de un adulto, el cuerpo adolescente del período posterior traduce más bien en la pantalla un abanico de deseos frustrados. También es un cuerpo malherido por los excesos de todo tipo, el consumo en abuso de drogas o imágenes, quizás un fantasma más que un cuerpo dado que nunca llega a figurar la revolución que es (o que debería ser) la adolescencia.

cuerpoadolescencia[SHS.INFO]Humanities and Social Sciences/Library and information sciencescine españolGeneral Medicinedélinquance[SHS.ART]Humanities and Social Sciences/Art and art history[SHS.INFO] Humanities and Social Sciences/Library and information sciencescorpsgeneración Xadolescence[SHS.ART] Humanities and Social Sciences/Art and art historyimagepost-transiciónblessuresComputingMilieux_MISCELLANEOUSblessure
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Intercultural Workplace Communication

2017

The workplace is a highly meaningful context for intercultural communication where persons who come from different countries, identify with different ethnic groups or speak different languages get to collaborate and develop relationships with one another. Needless to say, interpersonal communication in the workplace has always been a primary area of interest for intercultural communication research. Early scholarship focused on the preparation of U.S. military personnel, diplomats, business people, and missionaries for overseas assignments. However, the increasing pluralization of the social landscape has bolstered research endeavors. These days, the scope of intercultural workplace communi…

cultural identityWorkplace communicationCultural identityCommunication studiesWorkplace relationshipsworkplace relationshipskulttuurienvälinen viestintäInterpersonal communicationorganizational diversitytiimitkeskinäisviestintäCultural diversityPolitical sciencetyöelämäta518ryhmätviestintäComputingMilieux_THECOMPUTINGPROFESSIONkulttuurittyöpaikatworkplacesIntercultural communicationintergroup communicationintercultural communicationcultural diversitySocial psychologykulttuuri-identiteettiIntergroup communication
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