Search results for "interfaces"
showing 10 items of 1258 documents
Structural characterization of TiNxOy/TiO2 single crystalline and nanometric multilayers grown by LP-MOCVD on (110)TiO2
2001
TiO2/TiNxOy superlattices were grown by Low Pressure-Metal-Organic Vapor Phase Epitaxy (LP-MOVPE) technique at deposition temperatures ranking from 650 to 750°C. The growth was performed on top of TiO2(110) rutile substrates. Intense peaks observed in the X-rays rocking curves and θ-2θ diffraction patterns show the presence of crystalline epilayers. The TiNxOy layers were grown in a (200) cubic structure on the (110) quadratic TiO2 epilayer structure. Transmission electron microscopy confirmed the XRD results and showed the formation of periodic and well structured epilayers.
Preparation of photocatalytic brookite thin films
2007
Pure brookite films were deposited from a brookite dispersion obtained by peptizing a mixture brookite–rutile prepared by thermolysis of TiCl4 in a HCl solution. The films were characterised by X-ray diffraction and Raman spectroscopy. The photoactivity of the samples was tested by using the photo-oxidation of 2-propanol in gas–solid regime as a probe reaction. The brookite films efficiently degraded 2-propanol under UV illumination.
Holographic recording of surface relief gratings in tolyle-based azobenzene oligomers
2008
Abstract Holographic recording of surface relief gratings (SRG) in tolyle-based azobenzene oligomer films have been carried out at 514.5 nm. It was experimentally studied by spectroscopic and AFM methods. The maximum surface modulation amplitude was 35 nm. SRG formation is explained by the mean-field model and by the photodegradation of chromophores enabling the directional mass transport as the result of trans–cis transformations. The conclusion is made that SRG are stable but the diffraction efficiency (DE) changes are due to the complementary decaying amplitude-phase gratings. Strong polarization dependences of transmitted and reflected DE are found. They are explained by the diffraction…
Assessment of the out-plane and in-plane ordering of high quality ZnO nanorods by X-ray multiple diffraction
2013
Abstract ZnO nanorods grown on buffered and non buffered sapphire substrates have been investigated by X-ray multiple diffraction using Renninger scans of the ZnO(0001) and ZnO(0003) forbidden reflections. In this technique the diffracted X-ray beam is simultaneously diffracted by several sets of planes, providing information on the broadening in different directions, as well as from nanorods, and from the layer on which they grow. The intensities and angular widths of peaks obtained by azimuthal and omega scans have been analyzed, making a direct comparison with conventional measurements of the full width at half-maximum of symmetric and asymmetric reflections. The analysis leads to establ…
Chirality effects on 2D phase transitions
1996
Monolayers of the racemate and pure enantiomers of 1-hexadecyl-glycerol were investigated by grazing incidence X-ray diffraction (GID) at 5 and 20 °C on compression from 0 mN m−1 to pressures greater than 30 mN m−1. The racemate lattice is centred-rectangular for both temperatures at all investigated pressures. However, at both temperatures, there is a sharp phase transition from a low-pressure phase, in which the molecules are tilted towards nearest neighbours (NN) and the distortion azimuth also points towards NN, to a high-pressure phase, in which the molecules are tilted towards next-nearest neighbours (NNN) and an NNN-distorted lattice is observed. At 5 °C, the transition pressure is 1…
Thickness and temperature dependent structure of Cd arachidate Langmuir-Blodgett films
1992
Abstract The structure of monolayers of Cd arachidate on water and on solid support, and the thickness dependent changes when building up a multilayer via the LB technique are studied by means of grazing incidence diffraction of X-ray. In monolayers the perpendicularly oriented amphiphilic molecules are arranged in a hexagonal lattice, whereas for thicker layers (even for three layers) they crystallize in an orthorhombic unit cell with a reduced molecular are ( A = 18.2 A 2 ) compared to that of the monolayer ( A = 19.7 A 2 ). In-plane diffraction measurements with wave vector transfer perpendicular to the surface (rod scans) could prove for multilayers a maximum tilt angle of 2°. The data …
Backward transition radiation in the extreme ultraviolet region as a tool for the transverse beam profile diagnostic
2014
The present article summarizes the results of two experiments which were performed to study the radiation properties of backward transition radiation (BTR) in the extreme ultraviolet (EUV) region. This wavelength region is of particular interest for transverse beam profile imaging, because the spatial resolution is improved as a result of the reduced contribution in the imaging process of the fundamental diffraction limit. In addition, the influence of coherent effects in the transition radiation emission process, which have been observed in the visible region, might be mitigated. The first experiment, dedicated to the investigation of the BTR angular characteristics, indicates that the rad…
IMAGING OF DICHROISM IN PHOTOEMISSION ELECTRON MICROSCOPY AT NONMAGNETIC MATERIALS USING CIRCULARLY POLARIZED SOFT X-RAYS
2002
A new approach for investigations of circular dichroism in the angular distribution of photoelectrons (CDAD) is presented. The image contrast using a photoemission line of a certain material is combined with imaging of the angular distribution pattern using a photoemission electron microscope (PEEM). CDAD can be used to investigate pure scattering information by means of the same instrument in microscopically selected regions on a surface. The experiment combines angle-resolved XPS imaging with the indirect mapping of the local environment of atoms by means of CDAD holography. In a conventional photoelectron diffraction or photoelectron holography experiment, it is necessary to move the sa…
Surface plasmon assisted thermal coupling of multiple photon energies
2006
A novel optical effect can be observed in a thin gold foil due to the excitation of surface plasmons which permits a form of all-optical modulation at low pulse rates. Modulated excitation of surface plasmons by infrared photons is shown to couple to several beams at visible-photon energies. The coupling is manifested by the observation of the visible photons being pulsed by the action of the infrared pulses, and by the far field diffraction of the visible beams into concentric rings. When each visible beam also excites surface plasmons, then a quadratic dependence of the visible photon power upon the infrared incident power is measured. The decay of surface plasmons is implicated as the pr…
Vapor growth of Hg1−xCdxI2 on glass using CdTe buffer
2001
Abstract Vapor phase epitaxy (VPE) of Hg1−xCdxI2 layers on glass substrates covered by a CdTe buffer layer has been studied. The buffer layers of 2–4 μm thickness were formed by VPE using polycrystalline CdTe and Cd metal sources. The Hg1−xCdxI2 layers were grown using a (Hg1−yCdy)1−z(I2)z polycrystalline source, with a composition in the range of y=0.1–0.5 and z=0.5–0.8. Scanning electron microscopy and X-ray diffraction studies have shown that the composition and structure of Hg1−xCdxI2 layers depend strongly on the VPE conditions. Varying the growth time and source composition, it has been possible to obtain Hg1−xCdxI2 layers with the composition x in the range from approximately 0 (HgI2…