Search results for "layered"
showing 10 items of 142 documents
Self-Assembly of 1D/2D Hybrid Nanostructures Consisting of a Cd(II) Coordination Polymer and NiAl-Layered Double Hydroxides
2015
The preparation and characterization of a novel hybrid material based on the combination of a 2D-layered double hydroxide (LDH) nanosheets and a 1D-coordination polymer (1D-CP) has been achieved through a simple mixture of suspensions of both building blocks via an exfoliation/restacking approach. The hybrid material has been thoroughly characterized demonstrating that the 1D-CP moieties are intercalated as well as adsorbed on the surface of the LDH, giving rise to a layered assembly with the coexistence of the functionalities of their initial constituents. This hybrid represents the first example of the assembly of 1D/2D nanomaterials combining LDH with CP and opens the door for a plethora…
Flexural vibrations of discontinuous layered elastically bonded beams
2018
Abstract This paper addresses the dynamic flexural behavior of layered elastically bonded beams carrying an arbitrary number of elastic translational supports and rotational joints. The beams are referred to as discontinuous for the discontinuities of response variables at the application points of supports/joints. The Euler-Bernoulli hypothesis is assumed to hold for each layer separately, and a linear constitutive relation between the horizontal interlayer slip and the interlaminar shear force is considered. Based on the theory of generalized functions to handle the discontinuities of response variables due to supports/joints, exact beam modes are obtained from a characteristic equation b…
Thickness-dependent properties of ultrathin bismuth and antimony chalcogenide films formed by physical vapor deposition and their application in ther…
2021
This work was supported by the European Regional Development Fund (ERDF) project No 1.1.1.1/16/A/257. J. A. acknowledges the ERDF project No. 1.1.1.2/1/16/037. Institute of Solid State Physics, University of Latvia, Latvia as the Center of Excellence has received funding from the European Union's Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017 TeamingPhase2 under grant agreement No. 739508, project CAMART2 . The raw/processed data required to reproduce these findings cannot be shared at this time as the data also form a part of an ongoing study.
Layered-Expanded Mesostructured Silicas: Generalized Synthesis and Functionalization
2018
Mesostructured layered silicas have been prepared through a surfactant-assisted procedure using neutral alkylamines as templates and starting from atrane complexes as hydrolytic inorganic precursors. By adjusting the synthetic parameters, this kinetically controlled reproducible one-pot method allows for obtaining both pure and functionalized (inorganic or organically) lamellar silica frameworks. These are easily deconstructed and built up again, which provides a simple way for expanding the interlamellar space. The materials present high dispersibility, which results in stable colloidal suspensions.
Layered Double Hydroxides in Bioinspired Nanotechnology
2020
Layered Double Hydroxides (LDHs) are a relevant class of inorganic lamellar nanomaterials that have attracted significant interest in life science-related applications, due to their highly controllable synthesis and high biocompatibility. Under a general point of view, this class of materials might have played an important role for the origin of life on planet Earth, given their ability to adsorb and concentrate life-relevant molecules in sea environments. It has been speculated that the organic–mineral interactions could have permitted to organize the adsorbed molecules, leading to an increase in their local concentration and finally to the emergence of life. Inspired by nature, material s…
Insights into the formation of metal carbon nanocomposites for energy storage using hybrid NiFe layered double hydroxides as precursors
2020
[EN] NiFe-carbon magnetic nanocomposites prepared using hybrid sebacate intercalated layered double hydroxides (LDHs) as precursors are shown to be of interest as supercapacitors. Here, the low-temperature formation mechanism of these materials has been deciphered by means of a combined study using complementaryin situ(temperature-dependent) techniques. Specifically, studies involving X-ray powder diffraction, thermogravimetry coupled to mass spectrometry (TG-MS), statistical Raman spectroscopy (SRS), aberration-corrected scanning transmission electron microscopy (STEM) and electron energy-loss spectroscopy (EELS) have been carried out. The experimental results confirm the early formation o…
Sepiolite-Hydrogels: Synthesis by Ultrasound Irradiation and Their Use for the Preparation of Functional Clay-Based Nanoarchitectured Materials.
2021
International audience; Sepiolite and palygorskite fibrous clay minerals are 1D silicates featuring unique textural and structural characteristics useful in diverse applications, and in particular as rheological additives. Here we report on the ability of grinded sepiolite to generate highly viscous and stable hydrogels by sonomechanical irradiation (ultrasounds). Adequate drying of such hydrogels leads to low-density xerogels that show extensive fiber disaggregation compared to the starting sepiolite-whose fibers are agglomerated as bundles. Upon re-dispersion in water under high-speed shear, these xerogels show comparable rheological properties to commercially available defibrillated sepi…
Two multilayered plate models with transverse shear warping functions issued from three dimensional elasticity equations
2014
Abstract A multilayered plate theory which uses transverse shear warping functions is presented. Two methods to obtain the transverse shear warping functions from three-dimensional elasticity equations are proposed. The warping functions are issued from the variations of transverse shear stresses computed at specific points of a simply supported plate. The first method considers an exact 3D solution of the problem. The second method uses the solution provided by the model itself: the transverse shear stresses are computed integrating equilibrium equations. Hence, an iterative process is applied, the model is updated with the new warping functions, and so on. Once the sets of warping functio…
A four-node MITC finite element for magneto-electro-elastic multilayered plates
2013
An isoparametric four-node finite element for multilayered magneto-electro-elastic plates analysis is presented. It is based on an equivalent single-layer model, which assumes the first order shear deformation theory and quasi-static behavior for the electric and magnetic fields. First, the electro-magnetic state of the plate is determined in terms of the mechanical primary variables, namely the generalized displacements, by solving the strong form of the magneto-electric governing equations coupled with the electro-magnetic interface continuity conditions and the external boundary conditions. In turn, this result is used into the layers constitutive law to infer the equivalent single-layer…
A finite element formulation for large deflection of multilayered magneto-electro-elastic plates
2014
An original finite element formulation for the analysis of large deflections in magneto-electro-elastic multilayered plates is presented. The formulation is based on an equivalent single-layer model in which first order shear deformation theory with von Karman strains and quasi-static behavior for the electric and magnetic fields are assumed. To obtain the plate model, the electro-magnetic state is firstly determined and condensed to the mechanical primary variables, namely the generalized displacements. In turn, this result is used to obtain laminate effective stiffness coefficients that allow to express the plate mechanical stress resultants in terms of the generalized displacements and a…