Search results for "optical"

showing 10 items of 7671 documents

Dimensional encapsulation of I− I 2 I− in an organic salt crystal matrix

2010

Bis(trimethylammonium)hexane diiodide encapsulates iodine from solution and through a gas/solid reaction yielding in a predictable and controllable manner the selective formation of the rare polyiodide species I(-)...I-I...I(-), which matches in length to the chosen dication.

inorganic chemicalseducationInorganic chemistryMetals and Alloyschemistry.chemical_elementGeneral ChemistrySolid reactionIodinebehavioral disciplines and activitieshumanitiesCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsDicationHexanePolyiodidechemistry.chemical_compoundchemistryMaterials ChemistryCeramics and Compositeshealth care economics and organizations
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Structural Characterization of Surfactant-Coated Bimetallic Cobalt/Nickel Nanoclusters by XPS, EXAFS, WAXS, and SAXS

2011

Cobalt nickel bimetallic nanoparticles were synthesized by changing the sequence of the chemical reduction of Co(II) and Ni(II) ions confined in the core of bis(2-ethylhexyl)phosphate (2)., and Ni(DEHP)(2). The reduction was carried out by mixing, sequentially or contemporaneously, fixed amounts of n-heptane solution of Co(DEHP)2 and Ni(DEHP)2 micelles with a solution of sodium borohydride in ethanol at a fixed (reductant)/(total metal) molar ratio. This procedure involves the rapid formation of surfactant-coated nanoparticles, indicated as Co/Ni (Co after Ni), Ni/Co (Ni after Co), and Co + Ni (simultaneous), followed by their slow separation as nanostructures embedded in a sodium bis(2-eth…

inorganic chemicalsendocrine systemMaterials sciencechemistry.chemical_elementNanoparticleNanoclustersMetalSodium borohydridechemistry.chemical_compoundX-ray photoelectron spectroscopyNANOPARTICLESPARTICLESBimetallic Cobalt/Nickel Nanoclusters. XPS. EXAFS. WAXS. SAXS.GOLDPhysical and Theoretical ChemistryBimetallic stripMICELLESSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyNickelGeneral Energychemistryvisual_artNANOPARTICLES; PARTICLES; GOLD; MICELLESvisual_art.visual_art_mediumCobaltNuclear chemistry
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ChemInform Abstract: Base-Catalyzed Isomerization of 2-Isoxazolines Enables a Two-Step Enantioselective Synthesis of β-Hydroxynitriles from Enals.

2011

Treatment of chiral isoxazoles with catalytic amounts of DBU results in efficient formation of optically active β-hydroxynitriles.

inorganic chemicalsgenetic structuresChemistryorganic chemicalsTwo stepEnantioselective synthesisGeneral MedicineOptically activeBase (exponentiation)IsomerizationCombinatorial chemistryeye diseasesCatalysisChemInform
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Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis

2014

Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P–P*)] (P–P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations. peerReviewed

intactLigandStereochemistryMetals and AlloysEnantioselective synthesisDiastereomerTiglic acidGeneral Chemistryhydrogenation catalysisCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysisMetalchemistry.chemical_compoundchemistryvisual_artMaterials ChemistryCeramics and Compositesvisual_art.visual_art_mediumCluster (physics)triruthenium clustersta116Chemical Communications
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Results on performance and ageing of solar modules based on Elkem Solar Silicon (ESS™) from installations at various locations

2014

Abstract The present study aims to present the current status of the results obtained using Elkem Solar Silicon (ESS™) as feedstock basis for solar cell and modules. It is shown that solar cells based on ESS™ are able to follow the development of the solar industry obtaining comparable efficiencies to standard polysilicon based cells. The characteristics of ESS™ based solar cells, having normally higher V oc and FF and lower I sc , seem to give clear advantages in the field for solar modules located at high irradiance areas. Results from several locations show enhanced electricity production of ESS™ based solar modules compared to polysilicon at increasing solar irradiance. This is explaine…

integumentary systemSiliconRenewable Energy Sustainability and the Environmentbusiness.industryHigh irradiancefood and beverageschemistry.chemical_elementSolar irradianceEngineering physicsSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialslaw.inventionPhotovoltaic thermal hybrid solar collectorElectricity generationSolar cell efficiencyOpticschemistrySolar industrylawbiological sciencesSolar cellEnvironmental sciencebusinessSolar Energy Materials and Solar Cells
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Distribution and generation of traps in SiO2/Al2O3 gate stacks

2007

In this work we combine charge-pumping measurements with positive constant voltage stress to investigate trap generation in SiO2/ Al2O3 n-MOSFET. Trap density has been scanned either in energy or in position based on charge-pumping (CP) measurements performed under different operating conditions in terms of amplitude and frequency of the gate pulse. Our results have revealed that the traps are meanly localized shallow in energy level, deeper in spatial position and they are mostly generated near the Si/SiO2 interface. (C) 2007 Elsevier Ltd. All rights reserved.

interface trapsWork (thermodynamics)Materials sciencecharge pumping (CP)Settore ING-INF/01 - ElettronicaTrap (computing)Stress (mechanics)Position (vector)Electrical and Electronic EngineeringSafety Risk Reliability and QualityBulk trapsbusiness.industryElectrical engineeringCondensed Matter PhysicsAtomic and Molecular Physics and OpticsSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsPulse (physics)AmplitudeDistribution (mathematics)Control and Systems Engineeringenergy distributionAtomic physicsbusinesshigh-k dielectricsEnergy (signal processing)
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Gas-Phase Hydrogenation of Propionitrile Catalyzed by LnCu2 (Ln = La, Ce, Pr, Nd)

2007

The hydrogenation of propionitrile over binary copper−lanthanide intermetallic compounds (LnCu2, Ln = La, Ce, Pr, Nd) was studied in the gas phase. The results show that the reaction main product is the primary amine, the n-propylamine. To our knowledge, it is the first time that such behavior is reported for copper catalysts.

intermetallicInorganic chemistryKineticsIntermetallicchemistry.chemical_element02 engineering and technology010402 general chemistry01 natural sciencescatalystsGas phaseCatalysischemistry.chemical_compound[ CHIM.CATA ] Chemical Sciences/Catalysislanthanum-copperPhysical and Theoretical ChemistryComputingMilieux_MISCELLANEOUSChemistrypropionitrile[CHIM.CATA]Chemical Sciences/Catalysis021001 nanoscience & nanotechnologyCopper0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsGeneral EnergykineticsPhysical chemistryAmine gas treatingPropionitrilegas phasehydrogenation0210 nano-technology
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UV variability and accretion in NGC 2264

2015

Photometric variability is a distinctive feature of young stellar objects; exploring variability signatures at different wavelengths provides insight into the physical processes at work in these sources. We explore the variability signatures at ultraviolet (UV) and optical wavelengths for several hundred accreting and non-accreting members of the star-forming region NGC 2264 (~3Myr). Cone search capability for table J/A+A/581/A66/table2 (Median photometry, variability amplitudes, light curve rms, J index, and color slopes for members monitored at CFHT)

interstellar mediumAccretionUltraviolet astronomyAstrophysics and AstronomyAstrophysics::High Energy Astrophysical PhenomenaPhysicsAstrophysics::Cosmology and Extragalactic Astrophysicsstellar astronomyYoung stellar objectsOptical astronomyPhotometryobservational astronomyAstrophysics::Solar and Stellar AstrophysicsAstrophysics::Earth and Planetary AstrophysicsCCD photometryAstrophysical ProcessesNatural SciencesSloan photometryAstrophysics::Galaxy Astrophysics
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Variability in proto-PNe. II.

2014

We have carried out a detailed observational study of the light, color, and velocity variations of two bright, carbon-rich proto-planetary nebulae, IRAS 22223+4327 and 22272+5435. The light curves are based upon our observations from 1994 to 2011, together with published data by Arkhipova and collaborators. They each display four significant periods, with primary periods for IRAS 22223+4327 and 22272+5435 being 90 and 132 days, respectively. For each of them, the ratio of secondary to primary period is 0.95, a value much different from that found in Cepheids, but which may be characteristic of post-asymptotic giant branch (AGB) stars. Fewer significant periods are found in the smaller radia…

interstellar mediumAstrophysics and AstronomyRadial velocityCarbon starsPhysicsPlanetary nebulaeexoplanet astronomystellar astronomyOptical astronomyobservational astronomyPhotometryGiant starsAstrophysics::Solar and Stellar AstrophysicsAstrophysics::Earth and Planetary AstrophysicsNatural SciencesAstrophysics::Galaxy AstrophysicsInfrared photometry
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Radio-optical scrutiny of compact AGN

2010

We study the correlations between the VLBA (Very Long Baseline Array) radio emission at 15GHz, extended emission at 151MHz, and optical nuclear emission at 5100{AA} for a complete sample of 135 compact jets. We use the partial Kendall's tau correlation analysis to check the link between radio properties of parsec-scale jets and optical nuclear luminosities of host active galactic nuclei (AGN). Cone search capability for table J/A+A/520/A62/table3 (Optical and radio parameters of 135 AGN)

interstellar mediumgalactic and extragalactic astronomyAstrophysics and Astronomyhigh energy astrophysicsAstrophysics::High Energy Astrophysical PhenomenaPhysicsAstrophysics::Instrumentation and Methods for AstrophysicsAstrophysics::Cosmology and Extragalactic AstrophysicsGalaxiesstellar astronomyOptical astronomyCosmologyobservational astronomyRadio continuum emissionRadio galaxiesRadio astronomyNatural SciencesQuasarsAstrophysics::Galaxy AstrophysicsSpectroscopyVery long baseline interferometry
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