Search results for "proteolytic enzymes"

showing 10 items of 57 documents

Cathepsin L in metastatic bone disease: therapeutic implications

2010

AbstractCathepsin L is a lysosomal cysteine proteinase primarily devoted to the metabolic turnover of intracellular proteins. However, accumulating evidence suggests that this endopeptidase might also be implicated in the regulation of other important biological functions, including bone resorption in normal and pathological conditions. These findings support the concept that cathepsin L, in concert with other proteolytic enzymes involved in bone remodeling processes, could contribute to facilitate bone metastasis formation. In support of this hypothesis, recent studies indicate that cathepsin L can foster this process by triggering multiple mechanisms which, in part, differ from those of t…

Bone diseaseClinical BiochemistryBone NeoplasmsBone metastasis; cancer; cathepsin K; cathepsin L; cysteine proteinases; proteinase inhibitorsBiologycathepsin KBiochemistryBone and BonesBone resorptioncathepsin LBone remodelingcysteine proteinaseCathepsin LmedicineCathepsin KAnimalsHumanscancerNeoplasm MetastasisMolecular BiologyCathepsinProteolytic enzymesproteinase inhibitorsBone metastasismedicine.diseaseBone metastasiCancer researchbiology.proteinSettore BIO/14 - Farmacologia
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Fetuin-A and Cystatin C Are Endogenous Inhibitors of Human Meprin Metalloproteases

2010

Meprin α and β, zinc metalloproteinases, play significant roles in inflammation, including inflammatory bowel disease (IBD), possibly by activating cytokines, like interleukin 1β, interleukin 18, or tumor growth factor α. Although a number of potential activators for meprins are known, no endogenous inhibitors have been identified. In this work, we analyzed the inhibitory potential of human plasma and identified bovine fetuin-A as an endogenous meprin inhibitor with a K(i) (inhibition constant) of 4.2 × 10(-5) M for meprin α and a K(i) of 1.1 × 10(-6) M meprin β. This correlated with data obtained for a fetuin-A homologue from carp (nephrosin inhibitor) that revealed a potent meprin α and β…

Carpsalpha-2-HS-GlycoproteinMolecular Sequence DataMatrix metalloproteinaseBiochemistryPlasma03 medical and health sciencesmedicineAnimalsHumansAmino Acid SequenceCystatin C030304 developmental biology0303 health sciencesMetalloproteinasebiology030302 biochemistry & molecular biologyProteolytic enzymesMetalloendopeptidasesBlood ProteinsTrypsinFetuinProtease inhibitor (biology)3. Good healthBiochemistryCystatin Cbiology.proteinCattleCystatinSequence Alignmentmedicine.drugBiochemistry
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Shed membrane vesicles and clustering of membrane-bound proteolytic enzymes

2003

Publisher Summary Eukaryotic cells appear to release into the extracellular medium several populations of exovesicles, which are suggested to have different origins and functions and are identified by different names. This chapter deals with vesicles believed to originate from the cell membrane and named membrane vesicles. These are structures in which membrane-bound proteolytic enzymes are clustered and they play important roles in matrix remodeling. Relatively large membrane vesicles (diameters ranging from 100 nm to 1 μm) are shed from plasma membranes through unidentified budding mechanisms. These membrane structures are enriched in selected plasma-membrane components including integrin…

Cell membraneCell signalingmedicine.anatomical_structureVesicleCellIntegrinExtracellularmedicinebiology.proteinProteolytic enzymesBiologyMicrovesiclesCell biology
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Mise en évidence d'une production de protéases exocellulaires par les levures au cours de la fermentation alcoolique du moût de raisin

1980

<p style="text-align: justify;">La durée d'activité très limitée dans le temps des protéases du raisin est confirmée en vinification en blanc, mais une nouvelle activité protéolytique peut être caractérisée à 37 °C et à pH 3,7 dans le moût au cours de la fermentation alcoolique.</p><p style="text-align: justify;">Cette activité doit être attribuée à des protéases exocellulaires libérées dans le milieu des levures. Parmi les souches essayées <em>S. bayanus</em> a une activité protéolytique plus importante que <em>S. cerevisiae</em>, ce qui se traduit par l'obtention de vins plus riches en azote soluble, donc plus stables du point de vue protéique et …

ChemistryProteolytic enzymeslcsh:Sfood and beveragesS. cerevisiaeproteolytic stabilityHorticultureEthanol fermentationgrapeMolecular biologylcsh:QK1-989Soluble nitrogenlcsh:Agriculturestrainmalolactic fermentationBiochemistryalcoholic fermentationproteolytic enzymeS. bayanuslcsh:BotanyMalolactic fermentationFermentationwineFood Sciencenitrogen contentOENO One
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Glucagon fibril polymorphism reflects differences in protofilament backbone structure

2010

Amyloid fibrils formed by the 29-residue peptide hormone glucagon at different concentrations have strikingly different morphologies when observed by transmission electron microscopy. Fibrils formed at low concentration (0.25 mg/mL) consist of two or more protofilaments with a regular twist, while fibrils at high concentration (8 mg/mL) consist of two straight protofilaments. Here, we explore the structural differences underlying glucagon polymorphism using proteolytic degradation, linear and circular dichroism, Fourier transform infrared spectroscopy (FTIR), and X-ray fiber diffraction. Morphological differences are perpetuated at all structural levels, indicating that the two fibril class…

Circular dichroismAmyloidProtein FoldingChemistryProtein StabilityCircular DichroismProteolytic enzymesmacromolecular substancesLinear dichroismFibrilGlucagonSettore FIS/07 - Fisica Applicata(Beni Culturali Ambientali Biol.e Medicin)Protein Structure SecondaryCrystallographyX-Ray DiffractionStructural BiologySpectroscopy Fourier Transform InfraredSide chainFourier transform infrared spectroscopyProtein MultimerizationFiber diffractionMolecular BiologyProtein secondary structurePolymorphism Amyloid Glucagon Structural changesPeptide Hydrolases
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Enzymatic cleaning of inorganic ultrafiltration membranes used for whey protein fractionation

2003

Abstract The aim of this work was to study the cleaning of inorganic membranes fouled by whey protein solutions using proteolytic enzymes. Tami ® 150+4T membranes (Tami Industries, S.A., 26110 Nyons, France) of 400 kg/mol molecular weight cut-off (MWCO) and a ZrO 2 filtering layer were selected to carry out the tests and Maxatase ® XL (Genencor International, 2333 CN Leiden, The Netherlands) and P3-Ultrasil ® 62 (Henkel Iberica, S.A., 08025 Barcelona, Spain) were investigated as cleaning agents. Cleaning efficiency was observed to be a function of the operating conditions. The operating conditions studied were the pH of the cleaning solution, the enzymatic agent concentration and cleaning t…

Cleaning agentWhey proteinChromatographyChemistryUltrafiltrationProteolytic enzymesFiltration and SeparationFractionationPermeationBiochemistryHydrolysisMembraneGeneral Materials SciencePhysical and Theoretical ChemistryJournal of Membrane Science
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Halloysite nanotubes for efficient loading, stabilization and controlled release of insulin

2018

Hypothesis: Oral insulin administration is not actually effective due to insulin rapid degradation, inactivation and digestion by proteolytic enzymes which results in low bioavailability. Moreover insulin is poorly permeable and lack of lipophilicity. These limits can be overcome by the loading of protein in some nanostructured carrier such as halloysite nanotubes (HNTs). Experiments: Herein we propose an easy strategy to obtain HNT hybrid materials for the delivery of insulin. We report a detailed description on the thermal behavior and stability of insulin loaded and released from the HNTs hybrid by the combination of several techniques. Findings: Release experiments of insulin from the H…

Dichroismmedicine.medical_treatmentHalloysite nanotube02 engineering and technology01 natural sciencesBiochemistryNanocompositesChitosanchemistry.chemical_compoundColloid and Surface ChemistryDrug StabilityProtein stabilityHalloysite nanotube (HNTs)InsulinTransdermalSettore CHIM/02 - Chimica FisicaDrug CarriersNanotubesProteolytic enzymes021001 nanoscience & nanotechnologyControlled releaseSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsEnzyme inhibitionAluminum SilicatesBionanocomposite film0210 nano-technologyHybrid materialBionanocomposite hybridSurface PropertiesDrug Compoundingengineering.materialCircular dichroism data010402 general chemistrySustained release InsulinAdministration CutaneousHalloysiteBiomaterialsKaolinitemedicineParticle SizeHybrid materialChitosanInsulinBiomedical applicationMedical applicationYarn Bio-nanocompositeMembranes Artificial0104 chemical sciencesNanotubeDrug LiberationHalloysite nanotubes Insulin Protein stability Sustained release Bionanocomposite hybridchemistryChemical engineeringDelayed-Action PreparationsengineeringClayNanocarriersSustained release
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Naturally occurring hemolysins in the coelomic fluid of Holothuria polii delle chiaie (Echinodermata).

1979

Abstract The coelomic fluid of Holothuria polii D.Ch contains hemolytic activity against erythrocytes of several vertebrate species. The hemolytic potency depends upon calcium ion concentration and varies according to erythrocyte source and cell number in the reaction mixture. Absorption experiments with formalinized rabbit erythrocytes suggest that hemolytic activity is not specific. Its heat lability, water insolubility at low pH values, and sensitivity to proteolytic enzymes suggest that hemolytic activity resides in protein molecules. The activity, maximal in alkaline media, appears to depend up time and temperature.

ErythrocytesCations DivalentSea CucumbersImmunologyDose-Response Relationship Immunologicchemistry.chemical_elementCalciumHemolysisHemolysin ProteinsPotencyAnimalsbiologyLabilityProteolytic enzymesTemperatureHemolysinExudates and TransudatesHydrogen-Ion Concentrationbiology.organism_classificationKineticschemistryBiochemistryCoelomAbsorption (chemistry)HolothuriaDevelopmental BiologyEchinodermataDevelopmental and comparative immunology
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In Vitro Bioactivity of Astaxanthin and Peptides from Hydrolisates of Shrimp (Parapenaeus longirostris) By-Products: From the Extraction Process to B…

2021

Non-edible parts of crustaceans could be a rich source of valuable bioactive compounds such as the carotenoid astaxanthin and peptides, which have well-recognized beneficial effects. These compounds are widely used in nutraceuticals and pharmaceuticals, and their market is rapidly growing, suggesting the need to find alternative sources. The aim of this work was to set up a pilot-scale protocol for the reutilization of by-products of processed shrimp, in order to address the utilization of this valuable biomass for nutraceutical and pharmaceuticals application, through the extraction of astaxanthin-enriched oil and antioxidant-rich protein hydrolysates. Astaxanthin (AST) was obtained using …

Fish ProteinsFood Handlingantioxidant activityPharmaceutical ScienceAngiotensin-Converting Enzyme InhibitorsPilot ProjectsXanthophyllsfish oilArticleAntioxidantsMicechemistry.chemical_compoundNutraceuticalPenaeidaeprotein hydrolysatesAstaxanthinDrug Discoveryshrimp by-productsAnimalsHumansFood sciencelcsh:QH301-705.5Pharmacology Toxicology and Pharmaceutics (miscellaneous)ShellfishWaste Productschemistry.chemical_classificationHydrolysisExtraction (chemistry)Proteolytic enzymesSupercritical fluid extractionFatty acidChromatography Supercritical FluidGreen Chemistry Technology3T3 Cellsproteolytic enzymesFibroblastsShrimpastaxanthinOxidative Stresslcsh:Biology (General)chemistrySPDsupercritical fluid extractionRabbitsPeptidesPUFAPolyunsaturated fatty acidMarine Drugs
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The mechanism of formamide hydrolysis in water from ab initio calculations and simulations.

2005

The neutral hydrolysis of formamide in water is a suitable reference to quantify the efficiency of proteolytic enzymes. However, experimental data for this reaction has only very recently been obtained and the kinetic constant determined experimentally is significantly higher than that predicted by previous theoretical estimations. In this work, we have investigated in detail the possible mechanisms of this reaction. Several solvent models have been considered that represent a considerable improvement on those used in previous studies. Density functional and ab initio calculations have been carried out on a system which explicitly includes the first solvation shell of the formamide molecule…

FormamideModels MolecularReaction mechanismFormamidesMolecular StructureReaction stepHydrolysisOrganic ChemistryProteolytic enzymesHydrogen BondingGeneral ChemistryReaction intermediateCrystallography X-RayCatalysischemistry.chemical_compoundSolvation shellchemistrySolvent modelsAb initio quantum chemistry methodsComputational chemistryThermodynamicsComputer SimulationChemistry (Weinheim an der Bergstrasse, Germany)
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