Search results for "raft"
showing 10 items of 1545 documents
Photografted methacrylate-based monolithic columns coated with cellulose tris(3,5-dimethylphenylcarbamate) for chiral separation in CEC
2018
A chiral capillary monolithic column for enantiomer separation in capillary electrochromatography was prepared by coating cellulose tris(3,5-dimethylphenylcarbamate) on porous glycidyl methacrylate-co-ethylene dimethacrylate monolith in capillary format grafted with chains of [2(methacryloyloxy)ethyl] trimethylammonium chloride. The surface modification of the monolith by the photografting of [2(methacryloyloxy)ethyl] trimethylammonium chloride monomer as well as the coating conditions of cellulose tris(3,5-dimethylphenylcarbamate) onto the grafted monolithic scaffold were optimized to obtain a stable and reproducible chiral stationary phase for capillary electrochromatography. The effect o…
A comparative study of advanced oxidative processes: Degradation of chlorinated organic compounds in ultrafiltration fractions of kraft pulp bleachin…
2016
Oxidative pre-treatment methods such as the Fenton oxidation, ozonation, and photocatalytic treatment have been compared in reducing adsorbable organic halogens (AOX) and chlorophenolic compounds in untreated kraft pulp bleaching effluent. Their efficiency was also studied on effluent ultrafiltration fractions. The Fenton treatment removed all analyzed chlorophenolic compounds from the effluent. Ozonation and photocatalysis appeared to be much less effective methods. The efficiency of the Fenton oxidation appeared to be more pronounced in higher molecular weight effluent fractions. This suggests a novel design, where the filtration stage can be placed after the oxidation, and the high- -mol…
Catalytic activity of solvated and unsolvated lanthanide halides in Friedel–Crafts acylations
2000
Abstract Anhydrous lanthanide halides — chlorides and bromides — can act as homogeneous catalysts of Friedel–Crafts acylations. The catalytic activity is related to the solubility of these anhydrous salts. More soluble THF or dioxane (Diox.) neodymium and samarium adducts are more active catalysts.
UraniumIV and uranyle salts, efficient and reusable catalysts for acylation of aromatic compounds
2000
Abstract Uranium tetrachloride, uranyle chloride, fluoride and also nitrate or acetate are very efficient homogeneous catalysts for the Friedel–Crafts acylation of aromatic compounds. With uranyle salts, the reaction, carried under dry air, is highly specific and the mono- or bisacylation products are obtained in high yield. Uranyle catalyst can be quantitatively recovered and reused and the organic products are obtained free of uranium.
Friedel-Crafts catalytic alkylations using rare earth-based mineral supports
1998
Abstract Rare earth halides supported on mineral supports (K10 montmorillonite and silica) were investigated as catalysts for Friedel-Crafts alkylations. This project concerns the replacement of the widely used Lewis acid AlCl3 in Friedel-Crafts reactions by environmentally friendly catalysts in that they circumvent the production of aluminum waste. The catalytic activity of these heterogeneous catalysts was established in a series of alkylations of aromatic compounds.
Leishmaniasis, contact hypersensitivity and graft-versus-host disease: understanding the role of dendritic cell subsets in balancing skin immunity an…
2010
Dendritic cells (DC) are key elements of the immune system. In peripheral tissues, they function as sentinels taking up and processing antigens. After migration to the draining lymph nodes, the DC either present antigenic peptides by themselves or transfer them to lymph node-resident DC. The skin is the primary interface between the body and the environment and host's various DC subsets, including dermal DC (dDC) and Langerhans cells (LC). Because of their anatomical position in the epidermis, LC are believed to be responsible for induction of adaptive cutaneous immune responses. The functions of LC and dDC in the skin immune system in vivo are manifold, and it is still discussed controvers…
Iedomu valodas: H.F. Lavkrafta grāmatas “Kthulhu aicinājums” un tās latviskā tulkojuma analīze
2020
Izdomu valodas ir paredzētas būt par neatliekamu un visai svarīgu daļu izdomu pasaulēm daiļliteratūrā (un ne tikai), un ir bieži izgudrotas ar nolūku padarīt izdomu pasaules ticamākas. Daudzi slaveni rakstnieki jau senos laikos ir iepazīstinājuši daiļliteratūras lasītājus ar savām izdomu valodām. Šis maģistra darbs ir par Hovarda Filipsa Lavkrafta izdomu valodu “R’lje”, kura pastāv viņa pat izdomātā pasaulē ar nosaukumu “Cthulhu Mythos”. Šo valodu var sastapt vairākās grāmatās, filmā un arī videospēlē, bet šis maģistra darbs būs vairāk koncentrēts uz to valodu, kura sastopama tikai grāmatās un videospēlē. Šajā pētījumā es analizēju Lavkrafta grāmatu “Kthulhu aicinājums”, izvērtēju šīs grāma…
Three zone modeling of downdraft biomass gasification : equilibrium and finite kinetic approach
2013
Mathematical models and simulations are being practiced exceedingly in the field of research and development work. Simulations provide a less expensive means of evaluating the benefits and associated risk with applied field. Gasification is a complex mechanism, which incorporates thermochemical conversion of carbon based feedstock. Therefore, simulation of gasification provides a better comprehension of physical and chemical mechanism inside the gasifier than general conjecture and assist in optimizing the yield. The main objectives of present thesis work involve formulation of separate sub-model for pyrolysis and oxidation zone from published scientific references, and assembling it with p…
Koksnes staru veidošanās parastajā priedē Pinus sylvestris Tomē lāna briestaudzē
2020
Parastā priede ir pasaulē visplašāk izplatītākā un ekonomiski nozīmīga skujkoku suga. Tā veido biomasas pieaugumu, izmantojot pašreizējos asimilātus, tomēr tās augšanai tiek izmantotas arī iepriekš izveidotās rezerves, kas noglabātas koksnes staru veidā. Mainīgos vides, īpaši ekstrēmos apstākļos mainās arī uzkrāto rezervju daudzums, kas var ietekmēt biomasas pieaugumu nākotnē. Koksnes staru izmēri atspoguļo uzkrāto rezervju daudzumu koksnē un pēc tā var spriest par koku reakciju uz meteoroloģiskajiem faktoriem un sociālā statusa nozīmi vienas audzes ietvaros. Par pētījuma vietu izvēlēta saimnieciska parastās priedes audze lāna tipa mežā, Tomē. Pētījumam ievāca urbumus no I un III Krafta kla…
A comparison of force-, velocity- and balanced training approach on force-velocity mechanical outputs and vertical jump height – of national level at…
2019
Master's thesis Sports Science ME517 - University of Agder 2019 INTRODUKSJON.Optimalisering av muskulær power-produksjon har blitt vurderttil å være en essensiell del av prestasjon i ulike idretter, men det foreligger lite litteratur på utøvere på nasjonalt nivå. På bakgrunn av dette,er målet med studien å sammenlikne hvilkettreningsprogram (kraftdominert, hastighetsdominert eller balansert) som er mest gunstig for å øke kraft-hastighetsparametre (F0, V0& Pmax)og vertikal hopphøyde. METODE.Trettifem mannlige elite-utøvere ble rekruttert og delt med stratifisert randomisering ut ifraderes kraft-hastighetsprofil inn i tre ulike treningsgrupper(kraftdominert, hastighetsdominert og balansert), …