Search results for "silver"

showing 10 items of 697 documents

The first silver(I) nitrate π-complexes with unsaturated organosilicons: Synthesis and structural characterization of [Ag(DADPS)xNO3] (DADPS=diallyld…

2011

Abstract Tetraethylene glycol dimethyl ether (tetraglyme) was used for the first time to induce the activation of silver nitrate resulting in the step-by-step formation of complexes with diallyldiphenylsilane (DADPS). Two crystal compounds of this series were examined by FTIR spectroscopy and X-ray diffraction. The analysis of the obtained data showed that the Ag (C C) η 2 -interaction is involved in the synergistic effect of intra and intermolecular forces. In particular the interlayer π–π stacking interactions promoted by asymmetric weak Ag C(phenyl) bond have a significant influence on the thermal behavior and stability of the synthesized products. It was also found that a decrease of si…

Coordination sphereOrganic ChemistryInorganic chemistryIntermolecular forceStackingRing (chemistry)Analytical ChemistryInorganic ChemistryCrystalTetraethylene glycol dimethyl etherchemistry.chemical_compoundSilver nitrateCrystallographychemistryFourier transform infrared spectroscopySpectroscopyJournal of Molecular Structure
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Committenze ospitaliere d'arte decorativa siciliana. Coralli barocchi e argenti rococò

2016

Il contributo analizza manufatti d'arte decorativa siciliana, in particolare coralli barocchi e argenti rococò, commissionati da Cavalieri dell'Ordine di Malta che oggi si trovano in importanti collezioni melitensi. The essay deals with Sicilian decorative artefacts, in particular baroque corals and rococo silverware, commissioned by Knights of the Order of Malta, which are now found in important collections in Malta.

Corals Silverware Sicily Knights of MaltaCoralli argenti Sicilia Cavalieri di MaltaSettore L-ART/02 - Storia Dell'Arte Moderna
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Presentazione

2018

Si presenta il volume di Calogero Ridulfo mettendo maggiormente in evidenza le notizie che arricchiscono la conoscenza del patrimonio artistico dell'ultimo scorcio del Medioevo a Corleone quando vi operavano importanti pittori, da Tommaso De Vigilia a Pietro Ruzzolone, affiancati da altri abili artisti ora sottratti dall'oblio The volume by Calogero Ridulfo is presented, highlighting the news that enriches the knowledge of the artistic heritage of the last part of the Middle Ages in Corleone when important painters worked there, from Tommaso De Vigilia to Pietro Ruzzolone, alongside other skilled artists now stolen from oblivion

Corleone late Middle age painters wood carvers silversmithsSettore L-ART/01 - Storia Dell'Arte MedievaleCorleone tardo Medioevo pittori intagliatori lignei argentieri
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The benedictine church and monastery of Santa Maria Maddalena of Corleone. Works of art and documents

2019

Il lavoro esamina le diverse fasi di costruzione della chiesa e del complesso monastico di santa Maria Maddalena di Corleone, importante centro dell’entroterra siciliano, soffermandosi in particolare all’età moderna. Le inedite fonti archivistiche indagate oltre ad individuare le maestranze impegnate nei lavori fanno emergere importanti artisti. Successivamente si passa all’individuazione delle opere d’arte sacra ancora esistenti mai indagate scientificamente e raccolte insieme per la prima volta. This work examines the different phases of construction of the church and the monastic complex of Santa Maria Maddalena of Corleone, an important centre in the Sicilian hinterland, focusing in par…

Corleone monastero benedettino arte sacra arti decorative pittura scultura argenti paratiCorleone Benedictine monastery sacred art decorative arts painting sculpture silverware textilesSettore L-ART/02 - Storia Dell'Arte Moderna
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<title>Primary radiation defect formation in silver halides</title>

1998

Under irradiation the formation of primary intrinsic defects in silver halide solid solutions AgBr1-xClx take place via strong exciton-phonon interaction. Efficiency of these defects formation depend on solid solution composition and within 0 <EQ x <EQ 0.15 dependence on temperature was observed too. Estimation shows efficiency of defects creation is approximately 0.01 for AgCl and noticeably higher for AgBr.© (1998) COPYRIGHT SPIE--The International Society for Optical Engineering. Downloading of the abstract is permitted for personal use only.

Crystallographychemistry.chemical_compoundMaterials scienceSilver halidechemistryPhononExcitonHalidePhysical chemistryIrradiationAbsorption (chemistry)LuminescenceSolid solutionOptical Information Science and Technology (OIST97): Optical Recording Mechanisms and Media
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Powder X-ray diffraction data for potassium silver thiocyanate, AgK(SCN)2 and dipotassium silver thiocyanate, AgK2(SCN)3

2002

Previously unpublished powder X-ray diffraction data for potassium silver thiocyanate, AgK(SCN)2 and dipotassium silver thiocyanate, AgK2(SCN)3 are presented. F30 values for AgK(SCN)2 and AgK2(SCN)3 are 80(0.0075, 50) and 53(0.0089, 63), respectively. The Rietveld refinement of the patterns is also performed. For AgK(SCN)2Rp=6.98, Rwp=11.84, and RBragg=2.9. For AgK2(SCN)3Rp=7.22, Rwp=10.79, and RBragg=5.0.

Crystallographychemistry.chemical_compoundRadiationchemistrySilver thiocyanateRietveld refinementPotassiumX-ray crystallographyInorganic chemistrychemistry.chemical_elementGeneral Materials ScienceCondensed Matter PhysicsInstrumentationPowder Diffraction
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Insights into the Mechanism of Cumene Peroxidation Using Supported Gold and Silver Nanoparticles

2013

Due to the considerable industrial implications, an in-depth study of cumene peroxidation using supported gold and silver nanoparticles was carried out to gain more insight into the mechanism of this reaction. Supported gold nanoparticles were found to efficiently catalyze the decomposition of cumene hydroperoxide with a selectivity of 25% at 80 °C when using gold supported on hydrotalcite (AuNP@HT), and 2-phenyl-2-propanol (i.e., cumyl alcohol) was the main product. Further, silver nanoparticles supported on hydrotalcite (AgNP@HT) converted cumene to cumene hydroperoxide at 80 °C with 80% selectivity. Both benchtop and oxygen-uptake experiments were used to probe the reaction mechanism and…

CumeneReaction mechanismHydrotalcite010405 organic chemistryChemistryGeneral Chemistry010402 general chemistryPhotochemistry01 natural sciencesCatalysisSilver nanoparticle0104 chemical sciences3. Good healthCatalysischemistry.chemical_compoundCumene hydroperoxideColloidal goldSelectivityACS Catalysis
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PCR testing for Treponema pallidum in paraffin-embedded skin biopsy specimens: test design and impact on the diagnosis of syphilis

2007

Background: Syphilis, a chronic infection caused by Treponema pallidum (T. pallidum), is a disease which is increasing in incidence, and thus more and more becoming a differential diagnosis in routine pathology. Aim: Since histological changes are not specific, we sought to develop a polymerase chain reaction (PCR)-based molecular assay for the detection of T. pallidum in formalin-fixed, paraffin-embedded tissues, and evaluate its diagnostic power, especially in comparison with other ancillary methods, i.e. immunohistochemistry and Dieterle staining. Methods: 36 skin biopsies with the clinical and /or serological diagnosis of syphilis were evaluated by morphology, immunohistochemistry and s…

DNA BacterialMaleSexually transmitted diseaseSilver StainingPathologymedicine.medical_specialtyMolecular Sequence DataBiologyPolymerase Chain ReactionSensitivity and SpecificityPathology and Forensic Medicinelaw.inventionSilver stainlawBiopsymedicineHumansTreponema pallidumPolymerase chain reactionDNA PrimersSkinParaffin EmbeddingTreponemaBase Sequencemedicine.diagnostic_testSyphilis CutaneousGeneral Medicinemedicine.diseasebiology.organism_classificationImmunohistochemistrySyphilis SerodiagnosisStainingSkin biopsyFemaleSyphilisJournal of Clinical Pathology
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Acquasantiera con Santa Rosalia e il Genio del Fiume Oreto

2021

Historical and critical analysis of a silver and coral filigree font made in Sicily in 1678. Description and iconographic reading of the figurative elements

Decorative artSilverwareCoralHoly artSettore L-ART/02 - Storia Dell'Arte Moderna
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La Mostra d’Arte Sacra delle Madonie di Maria Accascina. Il catalogo che non c’era

2017

Critical and reasoned reconstruction of the catalog of the Madonie Sacred Art Exhibition created by Maria Accascina in 1937. A tribute to the curator, a review of works of art, sacred art and decorative art ranging from the fourteenth to the nineteenth century

Decorative artSilverwarePaintingJewelerySculptureHoly artSettore L-ART/02 - Storia Dell'Arte Moderna
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