Search results for "ta218"
showing 10 items of 83 documents
Generic Method for Modular Surface Modification of Cellulosic Materials in Aqueous Medium by Sequential Click-Reaction and Adsorption
2012
A generic approach for heterogeneous surface modification of cellulosic materials in aqueous medium, applicable for a wide range of functionalizations, is presented. In the first step, carboxymethyl cellulose (CMC) modified with azide or alkyne functionality, was adsorbed on a cellulosic substrate, thus, providing reactive sites for azide–alkyne cycloaddition click reactions. In the second step, functional units with complementary click units were reacted on the cellulose surface, coated by the click-modified CMC. Selected model functionalizations on diverse cellulosic substrates are shown to demonstrate the generality of the approach. The concept by sequentially combining the robust physic…
Leachate formation and characteristics from gasification and grate incineration bottom ash under landfill conditions
2011
Characteristics and formation of leachates from waste gasification and grate firing bottom ash were studied using continuous field measurements from 112 m(3) lysimeters embedded into landfill body for three years. In addition, the total element concentrations of the fresh ash were analysed and laboratory batch tests were performed to study leachate composition. The three-year continuous flow measurement showed that about one fifth of the leachates were formed, when the flow rate was200 l/d, covering3.5% of the study time. After three years, the liquid/solid-ratio for the quenched grate ash was 1 (l/kg (d.m.)) and for the initially dry gasification ash 0.4 (l/kg (d.m.)). The low initial wate…
A comparative economic analysis of torrefied pellet production based on state-of-the-art pellets
2017
Abstract Torrefied pellets have fuel properties superior to those of conventional wood pellets and potentially allow greater rates of co-firing and thus larger reductions in net CO 2 emissions. Despite the growing amount of scientific output on torrefaction, the economic feasibility of torrefied pellet production is still a topic of considerable uncertainty. This is an obstacle for decision makers looking to implement sustainable energy policies. This paper compares the economics of torrefied pellets to conventional wood pellets. Working backwards from demonstrated pellet properties, this work attempts to answer the following question: Based on state-of-the-art torrefied pellets, what would…
The effect of automated taxa identification errors on biological indices
2017
In benthic macroinvertebrate biomonitoring systems, the target is to determine the status of ecosystems based on several biological indices. To increase cost-efficiency, computer-based taxa identification for image data has recently been developed. Taxa identification errors can, however, have strong effects on the indices and thus on the determination of the ecological status. In order to shift the biomonitoring process towards automated expert systems, we need a clear understanding on the bias caused by automation. In this paper, we examine eleven classification methods in the case of macroinvertebrate image data and show how their classification errors propagate into different biological…
Vortices in rotating two-component boson and fermion traps
2010
Quantum liquids may carry angular momentum by the formation of vortex states. This is well known for Bose-Einstein condensates in rotating traps, and was even found to occur in quantum dots at strong magnetic fields. Here we consider a two-component quantum liquid, where coreless vortices and interlaced lattices of coreless vortices appear in a very similar way for fermions and bosons with repulsive two-body interactions. The ground states at given angular momentum, as well as the pair correlations for equal and different numbers of atoms in the two components, are studied. (C) 2009 Elsevier B.V. All rights reserved.
Decision support for centralizing cargo at a Moroccan airport hub using stochastic multicriteria acceptability analysis
2010
The geographical location of Morocco places it at the heart of important sea, air, rail and motorway transport routes between four continents. In this study we evaluate different alternatives to centralize multimodal cargo at a Moroccan airport hub. The choice depends on different socio-economical criteria, the geographical location, and the environmental impacts. Some of the criteria can be measured quantitatively, while for others only qualitative assessment is feasible. Furthermore, significant uncertainty is present in both the criteria measurements and the preferences. We aided this decision process using Stochastic Multicriteria Acceptability Analysis (SMAA). SMAA is a method that all…
Communication modes in vector diffraction
2010
The communication modes, which mathematically correspond to singular value decomposition, have proven a useful concept in optical scalar-field diffraction, with applications in resolution studies, image synthesis, and wave propagation. For optical near-field geometries the communication modes have to be extended to electromagnetic field accounting for the polarization properties. In this paper we present the vector-valued communication modes method based on the rigorous electric-field diffraction integral. As a special case the transverse-electric scalar field modes are obtained. The intensity and polarization properties of the leading electromagnetic communication modes in near-field arran…
Hidden Structural Features of Multicompartment Micelles Revealed by Cryogenic Transmission Electron Tomography
2014
The demand for ever more complex nanostructures in materials and soft matter nanoscience also requires sophisticated characterization tools for reliable visualization and interpretation of internal morphological features. Here, we address both aspects and present synthetic concepts for the compartmentalization of nanoparticle peripheries as well as their in situ tomographic characterization. We first form negatively charged spherical multicompartment micelles from ampholytic triblock terpolymers in aqueous media, followed by interpolyelectrolyte complex (IPEC) formation of the anionic corona with bis-hydrophilic cationic/neutral diblock copolymers. At a 1:1 stoichiometric ratio of anionic a…
Dielectrophoretic trapping of multilayer DNA origami nanostructures and DNA origami-induced local destruction of silicon dioxide
2015
DNA origami is a widely used method for fabrication of custom-shaped nanostructures. However, to utilize such structures, one needs to controllably position them on nanoscale. Here we demonstrate how different types of 3D scaffolded multilayer origamis can be accurately anchored to lithographically fabricated nanoelectrodes on a silicon dioxide substrate by DEP. Straight brick-like origami structures, constructed both in square (SQL) and honeycomb lattices, as well as curved "C"-shaped and angular "L"-shaped origamis were trapped with nanoscale precision and single-structure accuracy. We show that the positioning and immobilization of all these structures can be realized with or without thi…
Multicriteria evaluation of carbon-neutral heat-only production technologies for district heating
2018
Climate change mitigation requires reducing dependence on fossil fuels and transition to low carbon energy production technologies. Nearly half of the global final energy consumption is thermal energy produced from technologies with high carbon dioxide emission. As such, it is imperative to employ carbon-neutral heat production to achieve a sustainable energy system. This paper presents a real-life case of applying multicriteria decision analysis for evaluating carbon-neutral heat-only production technologies in a major district heating system in Finland. A group of 10 experts from the energy company contributed in defining the alternative technologies and multiple economic, technological, …