Search results for "thermoelectric"
showing 10 items of 188 documents
High performance p-type segmented leg of misfit-layered cobaltite and half-Heusler alloy
2015
In this study, a segmented p-type leg of doped misfit-layered cobaltite Ca_(2.8)Lu_(0.15)Ag_(0.05)Co_4O_(9+δ) and half-Heusler Ti_(0.3)Zr_(0.35)Hf_(0.35)CoSb_(0.8)Sn_(0.2) alloy was fabricated and characterized. The thermoelectric properties of single components, segmented leg, and the electrical contact resistance of the joint part were measured as a function of temperature. The output power generation characteristics of segmented legs were characterized in air under various temperature gradients, ΔT, with the hot side temperature up to 1153 K. At ΔT ≈ 756 K, the maximum conversion efficiency reached a value of ∼5%, which is about 65% of that expected from the materials without parasitic l…
Enhanced thermoelectric properties of the n-type Magnéli phase WO2.90: reduced thermal conductivity through microstructure engineering
2014
The thermoelectric properties of the Magneli phase WO2.90 were investigated, with special attention to how the thermoelectric performance can be altered by changing its microstructure. Spark plasma sintering (SPS) allowed the direct preparation of large amounts of consolidated material. Adding Ta2O5 to the reaction mixture lead to the formation of solid solutions W1−xTaxO2.90via a concurrent reaction between WO3 and Ta2O5 during the SPS treatment. In addition, micron-sized inclusions containing tungsten surrounded by WOx embedded in a WO2.90 matrix were formed, which act as additional scattering centers. As a result, the thermal conductivity of the Ta-containing samples was reduced by ≈30% …
Thermoelectric current and magnetic field interaction influence on the structure of directionally solidified Sn-10 wt.%Pb alloy
2013
International audience; In this experimental work Sn-10 wt.% Pb alloy is directionally solidified in Bridgman setup at various growth velocities (from 0.5 mu m/s to 20 mu m/s) under transverse 0.4 T magnetic field. Temperature gradient of 8 K/mm is maintained perpendicular to the solidification direction during experiments. Liquid phase convection and its influence on the structure and segregation of an alloy, caused by magnetic field and thermoelectric current interaction (thermoelectromagnetic convection or TEMC) is studied experimentally and estimated theoretically in this work. Detailed velocity order of magnitude estimation is carried out. Besides optical microscopy, component distribu…
Properties of spark plasma sintered nanostructured Zn1+xSb
2011
Engineering materials with specific physical properties has recently focused on the effect of nanoscopic inhomogeneities at the 10 nm scale. Such features are expected to scatter medium and long-wavelength phonons lowering thereby the thermal conductivity of the system without simultaneously decreasing the charge transport (phonon–glass electron–crystal concept). A new Zn1+xSb nanophase obtained by a wet chemical approach was densified by spark plasma sintering (SPS). Investigations on compounds subsumed as “Zn4Sb3” always suffer from its low thermal stability and the contamination of the nanoparticles with solvents and additives used in the synthesis. In order to gain insight into this com…
Synthesis and thermoelectric characterisation of bismuth nanoparticles
2009
An effective method of preparation of bismuth nanopowders by thermal decomposition of bismuth dodecyl-mercaptide Bi(SC12H25)3 and preliminary results on their thermoelectric properties are reported. The thermolysis process leads to Bi nanoparticles due to the efficient capping agent effect of the dodecyl-disulfide by-product, which strongly bonds the surface of the Bi clusters, preventing their aggregation and significantly reducing their growth rate. The structure and morphology of the thermolysis products were investigated by differential scanning calorimetry, thermogravimetry, X-ray diffractometry, 1H nuclear magnetic resonance spectroscopy, scanning electron microscopy, and energy dispe…
Poly(3,4-Ethylenedioxythiophene) nanoparticles as building blocks for hybrid thermoelectric flexible films
2019
Hybrid thermoelectric flexible films based on poly(3,4-ethylenedioxythiophene) (PEDOT) nanoparticles and carbon nanotubes were prepared by using layer-by-layer (LbL) assembly. The employed PEDOT nanoparticles were synthesized by oxidative miniemulsion polymerization by using iron(III) p-toluenesulfonate hexahydrate (FeTos) as an oxidant and poly(diallyldimethylammonium chloride) (PDADMAC) as stabilizer. Sodium deoxycholate (DOC) was used as a stabilizer to prepare the aqueous dispersions of the carbon nanotubes. Hybrid thermoelectric films were finally prepared with different monomer/oxidant molar ratios and different types of carbon nanotubes, aiming to maximize the power factor (PF). The …
Phase-separation-induced changes in the magnetic and transport properties of the quaternary Heusler alloyCo2Mn1−xTixSn
2010
The quaternary Heusler compound ${\text{Co}}_{2}{\text{Mn}}_{1\ensuremath{-}x}{\text{Ti}}_{x}\text{Sn}$ with $x=0$, 0.2, 0.4, 0.5, 0.6, 0.8, and 1 shows a phase separation into the two Heusler compounds, ${\text{Co}}_{2}\text{MnSn}$ and ${\text{Co}}_{2}\text{TiSn}$. Only at the edges of the composition range a slight admixture of Mn and Ti to the respective other phase is observed. This phase separation leads to a distinct microstructure which can be altered by the composition of the material. Pronounced changes in the magnetic and electronic properties take place with varying composition. Two magnetic transitions occur which indicate different Curie temperatures for both phases. The reduct…
Peltier cells as temperature control elements: Experimental characterization and modeling
2014
Abstract The use of Peltier cells to realize compact and precise temperature controlled devices is under continuous extension in recent years. In order to support the design of temperature control systems, a simplified modeling of heat transfer dynamics for thermoelectric devices is presented. By following a macroscopic approach, the heat flux removed at the cold side of Peltier cell can be expressed as Q ˙ c = γ ( T c − T c eq ) , where γ is a coefficient dependent on the electric current, Tc and T c eq are the actual and steady state cold side temperature, respectively. On the other hand, a microscopic modeling approach was pursued via finite element analysis software packages. To validat…
Wide Temperature Operation of 40-Gb/s 1550-nm Electroabsorption Modulated Lasers
2006
Electroabsorption modulated lasers (EMLs) exploiting the quantum confined Stark effect need thermoelectric coolers to achieve stable output power levels and dynamic extinction ratios. Temperature-independent operation is reported between 20/spl deg/C and 70/spl deg/C for InGaAlAs-InP-based monolithically integrated 1550-nm EMLs exploiting a shared active area at 40 Gb/s by actively controlling the electroabsorption modulator bias voltage. Dynamic extinction ratios of at least 8 dB and fiber-coupled mean modulated optical power of at least 0.85 mW are obtained over the mentioned temperature range.
Thickness-dependent properties of ultrathin bismuth and antimony chalcogenide films formed by physical vapor deposition and their application in ther…
2021
This work was supported by the European Regional Development Fund (ERDF) project No 1.1.1.1/16/A/257. J. A. acknowledges the ERDF project No. 1.1.1.2/1/16/037. Institute of Solid State Physics, University of Latvia, Latvia as the Center of Excellence has received funding from the European Union's Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017 TeamingPhase2 under grant agreement No. 739508, project CAMART2 . The raw/processed data required to reproduce these findings cannot be shared at this time as the data also form a part of an ongoing study.