Preliminary study on analysis and removal of wax from a Carrara marble statue

This preliminary study has mainly focused on the wax identification by nuclear magnetic resonance (NMR) and removal. Wax is used for many purposes in the field of art as protective coatings on wooden, stone or metal objects. From the comparison of the spectra H NMR and in particular with the correspondence of the resonance peaks of the samples taken from the statue and beeswax and paraffin, we can conclude that the wax applied on the statue surface is beeswax. From our data, it can be concluded that, to remove the beeswax, from any stone support, the more effective solvent is the mixture of cyclohexane/ethyl acetate. The removal percentages ranged from 19 to 99%. Lower percentages of remova…

Dispositivo per estrarre e purificare analiti da una matrice

Voltammetric determinations of platinum and rhodium in particulate of Palermo (Italy) area

Traffic has an important impact on the air quality which affects both the environmental and human health. Since the introduction of PGE-containing catalytic converters, a number studies have been undertaken to determine the effects of PGE emissions on human and to environment. This requires the development of good analytic methods to measure Pt and Rh concentrations in environmental matrices, as well to estimate background concentrations. In this paper are presented the results concerning Pt and Rh concentrations in PM10 samples collected at five stations within the urban area of Palermo. The highest mean values (Pt= 13 pg/m3, Rh=9.8 pg/m3) were recorded at an urban station, and the lowest …

PAHs composition of surface sediments of the‘Stagnone di Marsala’ coastal lagoon in the tyrrhenian west coast of Sicily

Gas-chromatography-mass spectrometry characterization of a double-bass (Panormus) varnishes and glues

Caratterizzazione delle vernici utilizzate nella liuteria storica

Gli acquiferi costieri del settore Bonagia-Cornino nel Trapanese: Prime analisi dei processi di contaminazione in relazione con la vulnerabilità SINTACS.

Assessment of quality of air in Palermo by chemical (ICP-OES) and cytological analyses on leaves of Eucalyptus camaldulensis

In this work, we studied the influence of air pollution on the morpho-structural, biochemical and chemical composition of Eucalyptus camaldulensis leaves. Analyses were carried out on 22 samples collected in Palermo (Italy) area. Considering the mean concentrations (in unwashed leaves) of investigated metals, nutrient elements as Fe (214 mg kg(-1) dry weight (d.w.)), Mn (160 mg kg(-1) d.w.) and Zn (39 mg kg(-1) d.w.) were the most abundant, whereas Pb (5.6 mg kg(-1) d.w.) and Cd (0.072 mg kg(-1) d.w.) showed the lowest concentrations. The values of metal pollution index (MPI) ranged from 6.0 (station no. 15) to 25 (station no. 8) and from 4.0 (station no. 16) to 17 (stations no. 7 and no. 1…

Presenza e ruolo dei microrganismi nella formazione e nella degradazione degli Idrocarburi Policiclici Aromatici nelle croste nere

Characterization of varnishes used in the ancient musical instruments

Monitoraggio di gas anestetici in sale operatorie di Palermo e provincia

Rischio biologico nei laboratori di microbiologia: epidemiologia e prevenzione

Microanalytical method for studying paintings by use of fluorescence spectroscopy combined with principal component analysis

Abstract The study of several different naturally aged films of organic painting materials, is described. Materials studied include drying oils (walnut, poppy seed and linseed oil) resin-based paint varnishes (the triterpenoid dammar and the diterpenoids sandarac and turpentine) and protein-based binding media (egg yolk and casein). A not expensive methodology for a rapid identification of binding media and varnishes, that applies principal component analysis (PCA) to Excitation Emission (EE) fluorescence spectra, is proposed. PCA was performed on a data matrix where the rows represent studied materials and columns the variables; the variables include the fluorescence intensities associated…

Geochemical mobility of toxic elements in soil and sedimets from Sicily

Analytical method for PAHs chemical speciation in sediments

The aim of this work is to optimize a method to examine the PAHs chemical speciation during the aging of sediments that is important in order to known the toxicological risk of a polluted area. In particular, we have conducted this research in order to determine if the organic contaminants fate is dependent to sediment characteristics and to study the potential role of humin and alkaline-extractable humic substances in the sequestration of PAHs in sediment. The Polycyclic Aromatic Hydrocarbons (PAHs) include molecules containing fused aromatic rings and are of special concern because of their widespread distribution throughout the environment and their often toxic and carcinogenic propertie…

Synthesis, spectroscopic characterization and antiproliferative activity of two platinum(II) complexes containing N-donor heterocycles

Abstract Novel mononuclear complexes of Pt(II), cis -[PtCl 2 (DMSO)HL]·2DMSO ( 1 ), where HL = 7-amino-2-(methylthio)[1,2,4]triazolo[1,5- a ]pyrimidine-6-carboxylic acid and Pt(bdt)Cl 2 ( 2 ), where bdt = [2,4-bis(5,6-diphenyl-1,2,4-triazin-3yl)-pyridine] have been synthesized and characterized by elemental analysis, IR and 1 H NMR spectroscopy and X-ray crystallography diffraction analyses. The molecular structure of ( 1 ) shows that Pt(II) ion has a square planar geometry with N(3) bonded heterocycle ligand, two cis chloride anions and S-bonded dimethylsulfoxide. The antiproliferative activity of complexes ( 1 ) and ( 2 ) has been tested in vitro against HepG2 human hepatoma cells and non…

Stress-induced cytological and chemical adaptations in Cupressus plants from an urban area of Palermo (Italy)

We studied stress-induced cytological and chemical adaptations in Cupressus pollens and needles from the area of Palermo (Sicily, Italy), in polluted and control sites (unpolluted) of urban and suburban areas. Pollen and needle chemical composition were investigated to provide an indicator of contamination of the trees, which were also examined structurally throughout one year. The concentration of particulate with lead was found to be significantly higher in plants at the polluted traffic site. Lead is one of the worst particulate pollutants in cities, especially in the winter season. In trees from the polluted site, all structural analysis revealed displasies. Structural changes, observed…

Determinazione degli elementi in tracce negli alimenti per celiaci tramite ICP-MS

Potential of the polychaete Sabella spallanzanii as bioindicator for PHAs

Every year 230.000 t of polycyclic aromatic hydrocarbons (PHAs) enter the marine environment, resulting ubiquitously distributed world‐wide. These compounds are aromatic molecules of special concern because of their toxic and carcinogenic properties. The two main sources of PHAs in the environment are fossil fuels, mainly crude oil, and the incomplete combustion of organic materials such as wood, coal and oil. They enter the sea by both atmospheric and aquatic routes. As a consequence of their hydrophobic nature, in aquatic environments PHAs rapidly tend to associate with particulate matter and sediments represent the most important reservoir. Animal and aquatic plants can accumulate PHAs f…

Environmental Aspect Concerning Phthalates Contamination: Analytical Approaches and Assessment of Biomonitoring in the Aquatic Environment

This review is a survey of recent progress in studies concerning the impact of phthalic acid esters in aquatic organisms. After introducing the classification, properties, sources, fate, and toxic effects related to phthalates, an overview of the techniques of extraction and analysis of these substances is provided. As a result, the general concepts of environmental bioindicators, biomonitoring systems, and other concepts related to phthalate contamination in the aquatic environment are presented. Recent bioaccumulation data of different phthalates are summarised in a table and organised according to the type of organism, tissue, and geographical area of sampling. Bioindicator organisms tha…

Platinum and rhodium in wine samples by using voltammetric techniques

For the first time, the concentrations of Pt and Rh in 42 different alcoholic beverages (white and red wines, vodka and brandy) produced in Italy, Malta and Gozo were investigated. Only the voltammetric techniques, in particular, differential Pulse Voltammetry (DPV/a) and Adsorptive Stripping Voltammetry (AdSV) were used for the determination of Pt and Rh respectively. Accuracy was tested with standard addition method and recoveries ranged from 90% to 98%. In analyzed wine samples, Pt and Rh concentrations are in the ranges from 3 to 470 μg L− 1and from 0.0006 to 0.36 μg L− 1respectively. We found a Pt/Rh ratios ranged from 37 to 180,000, in quite disagreement with the ratio in …

Comportamento delle stoffe nei confronti di alcuni inquinanti atmosferici

Photochemical sample treatment for extracts clean up in PCB analysis from sediments.

Sample purification can be considered the most polluting step of the whole analytical process for PCBs determination in sediment samples. The use of photochemical sample treatment represents an alternative methodology for extracts clean up allowing for a reduction of the used amount of organic solvents. The first application of a photochemical sample treatment for the selective removal or reduction of organic substances interfering with PCBs analyses in sediments is reported. The method's efficiency and robustness were compared with currently used chromatographic purification. Quality parameters such as recovery, linearity and reproducibility were studied. The entire procedure was validated…

Olive wood as possible bioaccumulator of heavy metals: analytical method by ICP-MS. GC-MS analysis

Determinazione di componenti della vernice e della colla del contrabbasso “Panormo” di Vincenzo Trusiano

Studio prelimianare sulla possibilità di recupero e di utilizzo dell’olio di caffè e del residuo privo di sostanze a carattere lipidico

Metals distribution in the organic and inorganic fractions of soil: A case study on soils from Sicily

The content of Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn, has been determined in the organic and inorganic fraction of eight soil samples from Sicily. A modified type-Tessier sequential extraction procedure has been used to recognize metals in five different fractions categorised as follows: (a) exchangeable metals, (b) metals bound to carbonates, (c) metals bound to iron and manganese oxides, (d) metals bound to organic matter, and (e) metals in residual fraction. The mineralogical composition of soils samples was characterized by X-ray diffraction. Humic substances were extracted by means of an alkaline extraction procedure. It has been found that both the mineralogical composition and the di…

Assessing polycyclic aromatic hydrocarbons (PAHs) bioaccumulation in the polychaete Sabella spallanzanii (Gmelin, 1971) (Sabellidae) in Sicilian harbours

Aldehydes measurements in public indoor environments in Palermo (Italy) using voltammetry.

Studies on indoor air quality are important since people spend more than 80% of life in confined environments, thus it is necessary to evaluate indoor contaminant concentrations and distributions for assessing total human exposure to them (Mannino and Orecchio, 2008; Orecchio, 2011). Aldehydes are indoor and outdoor chemical pollutants of particular interest due to their potential impact on health. Formaldehyde is usually the most abundant aldehyde in air and also the most studied since it is classified as human carcinogen. It is well known that formaldehyde is directly emitted from building materials, wood combustion, cigarette smoking, and is used as a bactericidal agent. One purpose of t…

Formaldehyde and total aldehydes in indoor air of public environments by voltammetry

The proposed method involves active sampling, where a sampling pump is used to pull air through a solution and voltammetric analysis of the obtained solutions. No interferences have been observed. In addition, very little sample preparation is required. Analyses were performed in 19 indoor stations and one in outdoor. Measurements were carried out on University environments: Museum of Chemistry, Zoological Museum, libraries, laboratories, corridors, meeting rooms, photocopying room, machine shop and terrace. Formaldehyde concentrations in analyzed samples ranged from 2.6 to 85 μg m-3 (median = 32 μg m-3), while the sum of others aldehydes ranged from 2 to 25 μg m-3 (median =2.4 μg m-3). In …

Phthalate esters in products and materials which come into contact with humans. GC-MS analysis

Speciazione di metalli pesanti nei sedimenti del porto e del golfo di Milazzo (Messina)

PAHs associated with the leaves of Quercus ilex L.: Extraction, GC–MS analysis, distribution and sourcesAssessment of air quality in the Palermo (Italy) area

Abstract In this study, the leaves of Quercus ilex L. were selected as possible bioaccumulators of polycyclic aromatic hydrocarbons (PAHs). Quercus is an evergreen plant that occurs widely in both urban and rural areas. Several sites (urban roadside, urban, urban park, suburban and rural) in and around Palermo city were investigated. The purpose of this research was to optimize analytical method for quercus leaves, investigate the degree of contamination in the urban area of Palermo by comparing PAH concentration in leaves of quercus from the several sites, establish distribution patterns and relate them to possible sources of PAHs. To this aim, the 16 recommended as priority pollutants by …

Polynuclear complexes of Pt(II) with polypyridyl ligands.II.Synthesis, spectroscopic and structural characterization and cytotoxic activity

Complex species formation of Cu and Cd metal ions with polyacrylate, polymethacrylate and alginate ligands. Potentiometric investigation by ISE-H+ and Ise-Me2+ electrodes

Cross-Linked Imidazolium Salts as Scavengers for Palladium.

Five imidazolium-based materials have been synthesised and used for the first time as palladium scavengers. Radical reactions of suitable bis-vinylimidazolium salts led to a series of insoluble materials through homo-polymerisation, immobilisation with a 3-mercaptopropyl-modified silica gel or co-polymerisation with ethylene glycol dimethylacrylate. These materials were screened as palladium scavengers with a set of palladium(0) and palladium(II) compounds in different solvents and at different starting amounts of palladium. In many cases, residual amounts of palladium were lower than 5 ppm, as requested for the manufacture of active pharmaceutical ingredients and fine chemicals. The applic…

Gas chromatography-mass spectrometry characterization of the varnish and glue of an ancient 18th century double bass.

A GC–MS investigation is conducted on the double bass “Panormus”, property of Conservatorio di Musica “Vincenzo Bellini” in Palermo. The most important components of the varnish (fatty acids) and of the glue (proteinaceous amino acids), with which the musical instrument was treated in the past, are determined. The analyses are carried out by prior derivatization of fatty acids by acidic methanol and of amino acids by acidic methanol and trifluoroacetic anhydride (TFAA). Analytes identification is achieved by direct comparison with several reference materials and the use of a digitized library.

Photochemical sample treatment: a greener approach to chlorobenzene determination in sediments.

Abstract Due to worker׳s exposure, solvent and stationary phases׳ consumption, sample purification is one of the most polluting steps in analytical procedures for determination of organic pollutants in real samples. The use of photochemical sample treatment represents a valid alternative methodology for extracts clean up allowing for a reduction of the used amount of organic solvents. In this paper we report the first application on the photolytic destruction of organic substances to eliminate some of the interferences in the analysis of Chlorobenzenes in sediment samples. The method׳s efficiency and robustness were compared with classic silica column purification process currently used in …

Levels, fingerprint and daily intake of polycyclic aromatic hydrocarbons (PAHs) in bread baked using wood as fuel

Concentrations, fingerprint and daily intake of 16 PAHs in 15 bread samples baked using wood as fuel are examined in this work. Analysis was performed by GC/MS after saponification of the samples and clean up of the extract. The total concentration of the 16 analytes varies from 6 to 230 microg/kg on dry weight (d.w.). The better extraction procedure was estimated by analyzing test-samples and using different extraction methods. Additionally, for every analyzed sample, the extraction yield has been determined by the use of surrogate standards. Extraction yields were never less than 77% and in most cases almost 100%. The profiles of PAHs (percentage) are similar for all the analyzed samples …

Enhancement of adsorption ability of calcium alginate gel beads towards Pd(II) ion. A kinetic and equilibrium study on hybrid Laponite and Montmorillonite–alginate gel beads

Abstract The adsorption ability of hybrid Montmorillonite and Laponite–calcium alginate gel beads towards Pd 2 + ion was studied in the pH range 2–4, in pure water and in aqueous NaCl solution at I = 0.01 mol L − 1 and T = 25 °C. The pseudo second order kinetic equation and the Langmuir and Freundlich isotherms were used to fit the kinetic and thermodynamic experimental data. A comparison of the results already published on the adsorption capacity of calcium alginate gel beads at the same experimental conditions was made. Enhancement of palladium(II) adsorption by alginate beads with the addition of the two clay minerals was obtained, with increments higher than 50% of Pd(II) ion recovered/…

Synthesis, structural characterization, anti-proliferative and antimicrobial activity of binuclear and mononuclear Pt(II) complexes with perfluoroalkyl-heterocyclic ligands

Abstract In this paper we report the synthesis of four Pt(II) complexes with 5-perfluoroalkyl-1,2,4-oxadiazolyl-pyridine and 3-perfluoroalkyl-1-methyl-1,2,4-triazolyl-pyridine ligands. Two binuclear complexes [PtCl(pfibap)2](µ-Cl)2 (1), [Pt2(µ-Cl)2(pfioap)4]Cl2 (2), and two mononuclear [PtCl2(pfptp)] (3), [PtCl2(pfhtp)2] (4), were synthesized with the ligands: 2-(5-perfluoropropyl)-1,2,4-oxadiazole-3yl)-pyridine (pfpop), 2-(5-perfluoroheptyl-1,2,4-oxadiazole-3yl)-pyridine (pfhop), 2-(3-perfluoropropyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfptp), 2-(3-perfluoroheptyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfhtp), and were structurally characterized. All complexes were tested in vitro on th…

POLYCHLORINATED BIPHENYLS ADSORPTION ONTO ALGINATE BEADS AND HYBRID ALGINATE MONTMORILLONITE BEADS: ISOTHERMAL AND KINETIC STUDIES

The PAH composition of surface sediments from Stagnone coastal lagoon, Marsala (Italy)

Abstract This paper examines the presence, distribution, nature and sources of 22 Aromatic Hydrocarbons (PAHs), which are important environmentally and toxicologically, in sediments from the Stagnone coastal lagoon at Marsala (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM). The total concentration of polycyclic aromatic hydrocarbons ranged from 72 to 18381 μg/kg of dry matrix. The relative standard deviation (RSD) of the replicates on the concentrations of individual compounds ranged from 5% to 20%. The accuracy of method was estimated by analyzing “blank” samples added of known quantities of analytes and the recover percent…

Identificazione dei microrganismi nelle Croste Nere

The use of leaves of Rosmarinus officinalis L. as samplers for polycyclic aromatic hydrocarbons. Assessment of air quality in the area of Palermo

The quantitative analysis of polycyclic aromatic hydrocarbons (PAHs) in vegetables and animals allows us to evaluate the quality of air, in a determined geographic area, without the need of making long samplers with complicate instrumentation. In this work, Rosmarinus officinalis leaves have been used as passive samplers. In particular, this plant was chosen because it is widespread in the Mediterranean area and it is commonly found both in the metropolitan and in the peripheral areas of the city of Palermo. Results for the concentration of total polycyclic aromatic hydrocarbons (the sum of the 22 compounds) and the PAHs distribution in leaves from Rosmarinus officinalis are presented. Puri…

Determination of Selected Phthalates by Gas Chromatography–Mass Spectrometry in Personal Perfumes

A simple and fast method is proposed to analyze commercial personal perfumes. Our method includes measurement of phthalates, known to be major sources of endocrine disruptor chemicals (EDC), which originate from the less volatile fraction of perfumes. The quantification of phthalates were carried out directly with no sample preparation required on 30 samples of commercial products using gas chromatography and mass spectrometry (GC-MS) as a detector. The total concentrations of 15 investigated compounds ranged from 17 to 9650 mg/L with an average of 2643 mg/L. The highest total concentration was found in cologne. Diethyl phthalate (DEP), diisobutyl phthalate (DiBP), di(2-ethylhexyl) phthalat…

Fractionation of mercury in sediments during draining of Augusta (Italy) coastal area by modified Tessier method

Abstract A modified Tessier method was applied to sediments dredged from Augusta (Italy) coastal area with the purpose of establishing the amount and the forms in which mercury is present in the different sediment fractions. The mercury fractionation was made by measuring the concentration of the metal ion on the solutions and directly on the sediment fractions obtained by sequential extraction. The measurements on the solutions as well as that on the solid fractions were carried out by using a Direct Mercury Analyser, DMA 80. This new instrument does not require sample preparation, and gives results comparable to those obtained with CV-AAS and ICP-MS and few minutes are necessary for each …

Voltammetric determination of platinum il leaves of Nerium oleander L. ; Preliminary data on assessment of air quality in the Palermo

POLYCYCLIC AROMATIC HYDROCARBONS IN MUD OF VULCANO ISLAND

Phthalate esters in indoor dust matter of Palermo (Italy) area. Extraction, GC-MS analysis

Indoor air is normally monitored using automatic. Consequently, the costs and difficulty in managing the monitoring of a great number of indoor environments appear immediately relevant. A practical problem in analyzing environmental contaminants is their very low concentration near or below the detectable analytical limits. In air, concentrations widely vary over time. Interpreting trace contaminants concentrations in air and predicting the threat they pose to human life under variable physical-chemical conditions are very difficult. The purpose of this work is to present a simple method to analyze phthalic esters in indoor dust, used as a passive sampler, because there is a correlation bet…

Neolithic ceramic findings from western Sicily. Chemical – physical and mineralogical characterization

This paper presents the results of a study that is part of a wider research program regarding the knowledge of the initial living phases of Sicilian agricultural and pastoral societies.Three ceramic samples attributed to the medium initial Neolithic (NEO1 and NEO2) and to the first neolithic (NEO3), recovered in two different archaeological sites of the western Sicily, have been analysed. Chemical, mineralogical and spectroscopic data point out a similarity between NEO1 and NEO3 samples; compositional and morphological differences instead have been observed in the NEO2 sample. The firing temperatures of the samples have been estimated by Mössbauer spectroscopy; they are lower than 500°C for…

PLATINUM AND RHODIUM IN WINES

Recover and reutilization of waste matter of coffee preparation. An experiment for Environmental Science Course

This work is designed as an experience for organic and analytical chemistry laboratories involved in environmental science courses. It achieves the following goals: 1. It shows that environmental samples are not homogeneous (1). 2. It is possible to build up students’ confidence in manipulating everyday matter when they are beginning to study scientific subjects and to introduce some methods of sample preparation in analytical chemistry. 3. It demonstrates some fundamental analytical principles (acid–base and redox analysis, solid–liquid and liquid– liquid extraction, etc.). 4. It shows the importance of instrumental analysis, such as gas chromatography, atomic absorption spectroscopy and e…

Vanadium and molybdenum concentrations in particulate from Palermo (Italy): analytical methods using voltammetry

The main purpose of this work was to develop a reliable method for the determination of vanadium (V) and molybdenum (Mo) in atmosphere particles or aerosols because they can not be readily measured using conventional techniques. For this research, 30 particulate samples were collected from five different stations located at Palermo, Italy. We used the catalytic adsorptive stripping voltammetry and differential pulsed voltammetry to measure Vand Mo in atmospheric particulate, respectively. The represented method includes advantages of high sensitivity, high selectivity, simplicity, reproducibility, speed and low costs. The quantification limits for V and Mo are, respectively, 0.57 and 0.80 n…

Fotodegradazione di esteri ftalici su pitture murali tramite irradiazioni uv

Gli esteri ftalici (esteri dell’acido ftalico), rappresentano una particolare classe di inquinanti organici ubiquitari, resistenzi alla bio-degradazione, capaci da fungere da distruttori endocrini e dannosi a causa del loro effetto mutageno e cancerogeno. Molti composti di questa classe di sostanze per decenni, e probabilmente ancora oggi, sono stati utilizzati come ammorbidenti nelle pitture murali superficiali utilizzate nelle comuni abitazioni domestiche. Considerando quindi che oggigiorno, le attività di demolizione e ristrutturazione rapprsentano una cospiqua fetta di mercato delle attività edilizie, e che spesso i lavoratori impiegati in queste attività sono sogetti in maniera continu…

The PAH composition in limpets (Patella vulgate L.) from the coasts of Sicily (Italy)

This article examines the presence, distribution, nature and sources of 19 Polycyclic Aromatic Hydrocarbons (PAH), in Patellae (patella vulgate L.) and seaweed (vulva) sampled in different stations of Sicilian coastal environments and analyzed for their polycyclic aromatic hydrocarbon (PAH) content. Analysis was performed by gas chromatography/mass spectrometry (GC/MS) with selected ion monitoring (SIM), after saponification of the sample and clean up of the extract. In the limpets the total concentration of polycyclic aromatic hydrocarbons ranged from 34 to 750 μg/Kg of dry matrix. The relative standard deviation (RSD) of the replicas on the concentrations of individual compounds ranged fr…

“Analisi di idrocarburi policiclici aromatici nei sedimenti del golfo e del porto di Milazzo (Messina)

Identificazione di Batteri nelle Croste Nere

Protection and monitoring of water resources in North-East Sicily (with particular regard to the S. Fratello-Acquedolci karst area)

Ottimizzazione delle procedure di estrazione degli IPA e valutazione della possibilità di utilizzare Sabella spallanzanii come bioaccumulatore

Sequestering ability of landfill leachate towards toxic metal ions

The great part of municipal solid wastes is worldwide stored in sanitary landfills. The interaction of organic and inorganic wastes with rainwater produces in the landfill a leachate of extremely variable composition. It depends on several variables such as the type of wastes, the age of landfill, the pH, the redox potential, etc [1-2]. Four are the recognized categories of pollutants in landfill leachate: inorganic macrocomponents, dissolved organic matter (DOM), heavy metals and xenobiotic organic compounds [3]. In particular, heavy metals (arsenic, cadmium, copper, lead, mercury, etc.) are usually present at concentration of few ppb and up to some ppm. A variable but consistent fraction …

Quantification of Platinum in Edible Mushrooms Using Voltammetric Techniques

Edible mushrooms are a food source with interesting nutritional values. The chief objective of this research was to develop a consistent method for the quantitative ultra-trace analysis of Pt in mushrooms, which is complex because it cannot be readily quantified by common analytical procedures. This research is one of the first analytical methods to establish Pt amount in these vegetables. In this research, 28 different edible mushroom samples from Italy were investigated. Determination of Pt in mushrooms was completed using Differential Pulse Voltammetry (DPV). In this study, we applied the standard addition method because there are no certified reference mushrooms containing platinum grou…

DETERMINATION OF MACRO ELEMENTS IN GLUTEN-FREE FOOD FOR CELIAC PEOPLE BY ICP-OES

This paper is the first analytical approach to the study of seven nutrients in the gluten-free foods for celiac people. The ICP-OES technique was used. One of the advantages about the use of ICP-OES for this characterization is the high selectivity and low interferences for studied elements. The concentration values of K, Li, Sr, Na, Ca, Mg and Al in seventeen gluten-free food samples are reported. Considering the average concentrations of the elements analyzed, excluding lithium, in the present study it can be concluded that they are inadequate if compared with the recommended daily intake by international organisms, providing only from 1.5 to 20% of the RDI for the essential metals. In pa…

Analytical method, pattern and sources of polycyclic aromatic hydrocarbons (PAHs) in the stone of the Temples of Agrigento (Italy)

Abstract This study shows the extraction and analytical conditions for the determination of polycyclic aromatic hydrocarbons (PAHs) in the stone of archaeological and historical interest. The aim of this research was to determine the concentrations, distribution and the main sources of PAHs present in the surface layer of stone of the Temples of Agrigento. Together with PAHs, we analyzed sulphates and nitrates since it has been demonstrated that these are very destructive salts that play an important role in the deterioration of stones. Total PAHs at different sites of the Valley of Temples at Agrigento varied from 18 to 84 μg/kg. Analyses were performed by GC–MS. The relative abundance of …

Variazione dei livelli di concentrazione di IPA in Patella coerulea nelle acque costiere siciliane

Voltammetric method with microwave-assisted sample digestion for the determination of platinum in biological matrices: preliminary data on pharmacokinetic study of hepatic perfusion with oxaliplatin

CHEMICAL CHARACTERIZATION OF ANCIENT LITURGICAL VESTMENT (CHASUBLE) BY ICP-OES

LEAVES OFNERIUM OLEANDERL. AS BIOACCUMULATORS OF POLYCYCLIC AROMATIC HYDROCARBONS (PAH) IN THE AIR OF PALERMO (ITALY): EXTRACTION AND GC-MS ANALYSIS, DISTRIBUTION AND SOURCES

Polycyclic Aromatic Hydrocarbons (PAH) were determined in the leaves of Nerium oleander L. an evergreen plant that occurs widely in both urban and rural areas, to monitor the degree of pollution in the urban area of Palermo (Italy) compared to remote areas. Twenty sites (urban roadside, urban, urban park, suburban and rural) in and around Palermo city were investigated. The purpose of this research was to investigate concentration levels and distribution patterns and relate them to possible sources. Analysis of 19 PAH was performed by gas chromatography/mass spectrometry (GCMS) using selected ion monitoring (SIM). The total amount of PAH ranged from 10 to 166 μg/Kg d.w. Each source gives ri…

Valutazione del bioaccumulo di metalli pesanti nel polichete Sabella spallanzani (Gmelin 1791) (Sabellidae) in tre aree portuali della Sicilia

II) Wood pellets for home heating can be considered environmentally friendly fuels? Heavy metals determination by inductively coupled plasma-optical emission spectrometry (ICP-OES) in their ashes and the health risk assessment for the operators

Abstract The aim of the present study was to determine the concentrations of twelve potentially hazardous elements in wood pellet ashes obtained by the combustion of 13 pellet brands for sale in Italy, the impact of adding the ashes to soils and health risk of operator due to dust exposure. Samples were analysed by Inductively Coupled Plasma Optical Emission Spectrometry. The concentrations of heavy metals in ashes from stoves ranged from 0.41 to 7.2 mg kg − 1 for As, from 1.3 to 12 mg kg − 1 for Sb, from 1.8 to 12 mg kg − 1 for Zn, from 0.23 to 0.8 mg kg − 1 for Pb, from 0.18 to 2.8 mg kg − 1 for Ni, from 0.09 to 1.0 mg kg − 1 for Cd, from 0.46 to 3.4 mg kg − 1 for Cr, from 0.94 to 2.7 mg …

Contamination from polycyclic aromatic hydrocarbons (PAHs) in the soil of a botanic garden localized next to a former manufacturing gas plant in Palermo (Italy).

The Botanical Garden lies within the city of Palermo, a few meters away from one of the largest unused Manufacturing Gas Plant in Sicily. The total concentrations of PAHs (23 compounds) in the soil of Botanical Garden ranged from 947 to 18,072 microg/kg. The wide range of PAH concentrations (RSD=84%) found in the soil samples indicates heterogeneous levels of contamination in the area and this can be explained by considering the different tree distributions which prevents the homogeneous deposition of pollutants on the soil. Soils collected in the Botanical Garden generally showed the highest PAH concentrations, being almost 2-3 times higher than the concentration samples obtained in the ur…

How building an underwater pipeline connecting Libya to Sicilian coast is affecting environment: polycyclic aromatic hydrocarbons (PAHs) in sediments; monitoring the evolution of the shore approach area of the Gulf of Gela (Italy)

The purpose of this study was to determine the variation of concentrations and distribution of PAHs in the sediments of the Gela coastal area (Italy) caused by the construction of an underwater pipeline connecting Libya to Sicilian coast. The receiving terminal of offshore pipeline, crossing the Mediterranean Sea, 516 Km long, up to 1127 meters deep, is located in Gela (Sicily, Italy). No bibliographic data regarding hydrocarbons are available for this area. In this paper we report the results of analysis on the water and organic along PAHs.The total concentrations of 16 PAHs in the sediments, analyzed during five surveys, ranged from 2.4 to 434 microg/kg of dry weight. The highest concentr…

Phthalate esters in coffee brew samples: Analytical method by GC-MS, profile, levels and sources

The present study was aimed to develop a procedure for the analysis of trace concentration of phthalate esters (PEA) in coffee brew stored in plastic cups. Phthalates are esters of phthalic acid, generally have high boiling points, lowvolatility are insoluble in water andpredominantly fat-soluble. Phthalates with higher molecular weights, such as bis(2-ethylhexyl) phthalate (DEHP) are largely used as additives and plasticizers in plastic material (PVC), while those with lower molecular weights are components of solvents, adhesive, wax, ink, pharmaceutical products, insecticide materials and cosmetic. Dimethyl phthalate and diethyl phthalate are present in plastics based on cellulose esters …

Determination of trace elements in gluten-free food for celiac people by ICP-MS

Abstract This paper is the first analytical approach to the study of twenty heavy metals in the gluten-free foods for celiac people. Only the ICP-MS technique was used. One of the advantages about the use of ICP-MS for this characterization is the high sensitivity that improved the limits of quantification levels for some elements that are present at low quantities in some samples. The concentration values of As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Sb, Se, Sn, V and Zn in seventeen gluten-free food samples are reported. The highest arsenic and molybdenum levels were measured in Rice noodle from China (0.088 and 0.47 mg kg − 1 , respectively). The highest concentrations of some metal…

Test microcristalloscopico per ditio ed etilenbisditiocarbammati

The use of leaves of Olea europaea L. as passive samplers for polycyclic aromatic hydrocarbons. Assessment of the quality of the air in Palermo

Interest in polynuclear aromatic hydrocarbons (PAHS), both from an analytical and an environmental point of view, arises from the fact that although most of them have absolutely no practical use, they are widely diffused into the environment. Their widespread distribution means that every individue is unwittingly exposed to the action of this class of substances, in working environments, in the home and in the open air. In this paper, Oleae europaea leaves have been used as passive samplers. The correlation obtained clearly shows that the quantitative analysis of PAHs in the Olea leaves permits to evaluate the quality of air, in a determined geographic area, without the need of making long …

Analisi chimiche su un’antica veste infantile del XVII secolo

Assessment of polycyclic aromatic hydrocarbons (PAHs) in soil of a Natural Reserve (Isola delle Femmine) (Italy) located in front of a plant for the production of cement.

Isola delle Femmine Natural Reserve is a very little isle about 15 km from the centre of Palermo, in front of a plant for the production of cement and about 600 m from coast. In the present research, profiles soil PAHs were obtained for 16 sites within the reserve and for 8 stations on the rural soil taken as reference. summation Sigma PAHs, in the soil of investigated area, ranged from 35 to 545 microg/kg. With the aim to find the origin of PAHs in the soil of Isola delle Femmine, we compare the distribution of single analytes in the investigated area with those of the reference rural area (Monte Raffo Rosso), with those of atmospheric urban particulate collected at Palermo along with repo…

Vulnerabilità all'inquinamento e vulnerazione di acquiferi in aree carsiche della Sicilia: stato delle conoscenze e nuovi contributi

Studio della capacità sequestrante della biomassa nei confronti dello ione rame (II)

Photochemical sample treatment: A greener approach for PCBs analysis in sediments

Electrical installations and industrial outlets are the major source in environment of chlorinated organic compounds. These are distributed in several geographical areas through long-range atmospheric transport and deposition. Additionally, chlorinated organic compounds can be introduced in the food chain and reach the consumers in very high levels. Besides toxicological studies on PCBs, recent research is focusing on more sophisticated analytical methods for PCBs detection. Distribution and dispersion of PCBs mostly occur through air, water, soils, and sediments. The latter are complex matrices whose analysis often involves costly extraction and purification procedures. In particular, PCBs…

Determination of selected phthalates by gas chromatography–mass spectrometry in mural paintings from Palermo (Italy)

Abstract Phthalate esters for decades, and probably even now, were used as softeners in water-based paintings. In general, these compounds are dangerous owing to their carcinogenicity and reproductive effects. Phthalates are not chemically but only physically bound to the matrices, hence, they may be leached into the environment and are ubiquitously found in environmental matrices. Considering that, construction is one of most important fields in Europe, and probably worldwide, with respect to its economic, technological and environmental impact. In the present work the phthalate esters content of several mural paintings was evaluated by gas chromatography–mass spectrometry (GC-MS). Because…

Analytical Method for Quantification of Several Phthalate Acid Esters by Gas Chromatography-Mass Spectrometry in Coffee Brew Samples

Several phthalate acid esters (PAEs), often called phthalate esters or phthalates, are substances classified as harmful due to their carcinogenic and mutagenic properties, and moreover, as dangerous for humans because they interfere with the endocrine system. In general, phthalic esters are used as plasticizers for different polymers and more other consumer products. In the present study, we describe a simple method to quantify PAEs in coffee brew using a liquid-liquid extraction without purification processes through analysing the obtained organic phase by GCMS in the single ion monitoring mode. The totals of single PAEs, in coffee brew samples analysed by us, are in the range of 159-5305 …

Absorption of polycyclic aromatic hydrocarbons by pinus bark: analytical method and use for environmental pollution monitoring in the Palermo area (Sicily, Italy)

Abstract In the light of using biomaterial as pollutants sorbents for the environmental biomonitoring, we report here the results of the absorption of polycyclic aromatic hydrocarbons (PAHs) by pine bark. Quantitative analysis of 19 different polycyclic aromatic compounds was performed, after Soxhlet extraction in dichloromethane, by means GC–MS technique. Pinus was chosen due to its wide distribution in the Mediterranean area. The passive absorption of PAH by pine bark in the metropolitan areas allowed us to evaluate the air quality of Palermo. The obtained results showed a very high range of PAHs concentrations, from 33 μg/kg (bark dry weight), as ΣPAHs, at the control site to 1015 μg/kg …

Speciation studies of iron in ancient pots from Sicily (Italy)

Abstract Manufacture technology involves several aspects of pottery making, such as the type and the atmosphere of firing to obtain the finished item. During the firing of clay, at different environment of the oven, different compounds of iron (Fe(II) and Fe(III)) are formed and this is the reason for a different color of the ceramic body. Despite the great interest in this field, no works are devoted to the study the speciation of iron in ancient ceramics. The proposed method, even if considered destructive by archaeologists, allows the speciation of iron, using quantity of sample in the order of milligram. In order to achieve information about their firing conditions, thirty-nine pottery …

Identification of Polycyclic Aromatic Hydrocarbons (PAHs) in the black crusts of Sicilian stone monuments: distribution and sources

Polycyclic Aromatic Hydrocarbons are a family of compounds with known carcinogenic potential; their properties of lipophilicity, low water solubility and adsorption to particles and sediments make them a potentially dangerous group of chemicals and a threat to the environment and its bio-resources. The concentrations of total Polycyclic Aromatic Hydrocarbons (PAHs) and 19 individual compounds in 8 black crusts sampled from historical building of Palermo (Italy) were analyzed, by gas chromatography/mass spectrometry (GC/MS) in selected ion monitoring (SIM) mode. PAH concentrations ranged from 78 to 9798 g/Kg of dry matrix. The resulting distributions and molecular ratios of specific compo…

Metal distribution in organic and inorganic fractions of soils from Sicily

Photodegradation of selected phthalates on mural painting surfaces under UV light irradiation

Abstract The esters of phthalic acid are considered as hazardous pollutants due to their mutagenicity, carcinogenicity and are also classified as endocrine disruptor chemicals. Several compounds of this class of substances for decades, and probably even now, were used as softeners in water-based synthetic paintings. Surfaces and structures, such as house walls painted with phthalates based paintings, can be a concern to construction workers engaged in demolition, restore and paint removal activities if they are not protected from hazardous dust inhalation. In this paper we report the results of an investigation about phthalate ester degradation by direct UV irradiation at 254 nm. The result…

Wood pellets for home heating can be considered environmentally friendly fuels? Polycyclic aromatic hydrocarbons (PAHs) in their ashes

This paper reports the results of the first quantitative investigations of PAHs in wood pellet ashes. Investigations were carried out into the fifteen PAHs identified by the US-Environment Protection Agency (US-EPA) as requiring priority monitoring; other non-US-EPA listed PAHs and perylene were also investigated. The total concentrations for the 17 investigated compounds, expressed as the sum of the concentrations (∑PAHs), in the ashes produced by the wood pellet combustion, ranged from 0.064mg kg-1 to 0.90mg kg-1 of dry weight with a means of 0.31mg kg-1. The lowest concentrations (<0.1mg kg-1) were measured in the conifer ash samples. Concentrations of PAHs found in this paper will al…

Occurrence and concentration of PAHs in clams and sediments of the marine coastal lagoon of Ganzirri (Italy). Extraction, GC-MS analysis, distribution and sources

The distribution of selected Polycyclic Aromatic Hydrocarbons (PAHs) in surface sediments and clams of marine coastal lagoons, called Ganzirri, located at the Sicilian coast of the, Messina's strait, has been investigated by GC/MS analysis with Selected Ion Monitoring (SIM) mode. The lagoon is characterized by abundant organic detritus, deriving from aquagenic and anthropogenic inputs. Anoxic/reduced conditions of sediments make them a preferential site for uptake and preservation of PAHs. From an eco-toxicological point of view, the aquatic ecosystem investigated appears to be moderately polluted. The investigations have been performed on the 16 PAHs recommended by US-EPA as priority pollu…

Chemical speciation of polycyclic aromatic hydrocarbons in sediments: partitioning and extraction of humic substances.

The primary objective of this study was to examine the chemical speciation of polycyclic aromatic hydrocarbons (PAHs) found in sediments endowed with different characteristics. To achieve this purpose and because the nature of the sediments influences the distribution of PAHs, we have analyzed four different types of sediments. To study the role of organic matter in the sequestration of PAHs, we fractionated humic substances into humic acids and humin–mineral fractions. After their separation and purification, the humic components were examined for their sorptive reactivity by extracting them with organic solvents; these extracts were subsequently subjected to GC/MS analysis. Our results sh…

Discrimination of almonds (Prunus dulcis) geographical origin by minerals and fatty acids profiling

Twenty-one almond samples from three different geographical origins (Sicily, Spain and California) were investigated by determining minerals and fatty acids compositions. Data were used to discriminate by chemometry almond origin by linear discriminant analysis. With respect to previous PCA profiling studies, this work provides a simpler analytical protocol for the identification of almonds geographical origin. Classification by using mineral contents data only was correct in 77% of the samples, while, by using fatty acid profiles, the percentages of samples correctly classified reached 82%. The coupling of mineral contents and fatty acid profiles lead to an increased efficiency of the clas…

Chemical characterization of ancient potteries from Himera and Pestavecchia necropolis (Sicily, Italy) by Inductively Coupled Plasma–Optical Emission Spectrometry (ICP–OES)

Abstract Thirty-eight samples of pottery were analyzed for determining chemical composition in order to establish their provenance. The potteries tested in the present research come from Himera and Pestavecchia archaeological sites. After digestion in microwave oven, the samples have been analyzed for fourteen minor elements (Ba, Cd, Co, Cr, Cu, Ga, Li, Mn, Ni, Pb, Sr, Ti, Tl, and Zn) and six major elements (Al, Ca, Fe, K, Mg, and Na). Chemical analysis was carried out by Inductively Coupled Plasma–Optical Emission Spectroscopy (ICP–OES). The most abundant minor elements are Cr, Ba and Ni. Cr concentration ranged from 66 to 3635 mg kg − 1 , Ba concentration ranged from 388 to 2677 mg kg − 1…

Mononuclear Perfluoroalkyl-Heterocyclic Complexes of Pd(II): Synthesis, Structural Characterization and Antimicrobial Activity

Two mononuclear Pd(II) complexes [PdCl2(pfptp)] (1) and [PdCl2(pfhtp)] (2), with ligands 2-(3-perfluoropropyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfptp) and 2-(3-perfluoroheptyl-1-methyl-1,2,4-triazole-5yl)-pyridine (pfhtp), were synthesized and structurally characterized. The two complexes showed a bidentate coordination of the ligand occurring through N atom of pyridine ring and N4 atom of 1,2,4-triazole. Both complexes showed antimicrobial activity when tested against both Gram-negative and Gram-positive bacterial strains.

Microanalytical characterization of decorations in handmade ancient floor tiles using inductively coupled plasma optical emission spectrometry (ICP-OES).

In this study a total of 114 glazed decorations of 42 ceramic floor tiles, manufactured in Sicily fromthe 16th to 19 the 21th AD, were investigated. The micro sampling method, proposed by us, using a cotton swab soaked in hydrofluoric acid, includes advantages of high sensitivity, high selectivity, simplicity, speed, not expensive and can be considered non-destructive because the point of sampling remains invisible to the human eye. ICP-OES technique was used in this study. Twenty-four elements (Al, As, B, Be, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mn, Mo, Ni, Pb, Sb, Se, Si, Sn, Ti, V and Zn) were determined in each colored enamel. Enameled decorations in Sicilian tiles were varied in tones an…

Polycyclic aromatic hydrocarbons (PAHs) in indoor emission from decorative candles

Abstract This study investigates PAHs indoor emissions from burning decorative candle in an indoor environment because emissions from burning wax in home have rarely been addressed. A total of 12 air samples were collected during the entire burning period of the decorative candles. Particulate and gaseous PAHs emissions were simultaneously measured by passing effluent through a filter (to collect particulate-phase PAHs), a cold trap and ORBO 43 tubes (to capture gaseous-phase PAHs). Analysis involved ultrasound extraction, followed by gas chromatography–mass spectrometry (GC–MS). The measured total PAHs concentration (particulate + aqueous phase + gas phases) for the candles, reported as ma…

Assessment of the quality of the air in the city of Palermo through chemical and cell analyses on Pinus Needles

The influence of air pollution on the chemical composition of Pinus sp. needles was examined in polluted and control sites in and around the city of Palermo (Sicily). The chemical composition of needles indicated the extent of contamination of the trees, which were cytologically examined. Cell analysis was carried out on pine samples, including needles and pollens, from 15 different locations. Biostructural and spectrophotometric tests were performed. In particular, concentrations of toxic (Cd, Pb) and non-toxic metals (Fe,Cu, Zn) were determined, as well as injury caused by their accumulation in the needles. The more highly urbanised areas showed higher concentrations of metals (Pb, Cu. Zn…

Diallyldimethylammonium Chloride (DADMAC) in Water Treated with Poly-Diallyldimethylammonium Chloride (PDADMAC) by Reversed-Phase Ion-Pair Chromatography—Electrospray Ionization Mass Spectrometry

Poly-diallyldimethylammonium (PDADMAC) chloride is a flocculant agent extensively used in water clarification treatments. Commercial polyelectrolyte formulations often contain residual monomer (DADMAC), reaction by-products and other reactants as contaminants that could potentially affect human health. In the present study, we optimized an analytical method based on reversed-phase ion-pair chromatography coupled with mass spectrometry for quantifying ultra-trace levels of DADMAC, without preliminary treatments, in drinking water distributed by the Palermo aqueduct. The method was validated in terms of accuracy (recovery between 80 to 120%), precision (RSD < 10%), linearity range (from 0.…

Analysis of Contaminants in Beverages

Abstract The main purpose of our researches, in the last years, was to develop reliable methods for the determination of emerging and old contaminants (Pt, Rh, V, Mo, polycyclic aromatic hydrocarbons (PAHs), etc.), at trace levels, in the solutions obtained from the mineralization or extraction of environmental and food matrices, because, in particular for metals, some of them cannot be readily analyzed using traditional method, for example, inductively coupled plasma-optical emission spectrometry and inductively coupled plasma with mass spectrometry techniques. Few data are available on the evaluations of Pt, Rh, V, and Mo concentrations, in food matrices, because have ever been carried ou…

Elemental contamination of an open-pit mining area in the Peruvian Andes

New technologies and higher prices of raw materials have promoted the expansion of mining activity throughout the world; if not properly regulated, this activity can lead to contamination of the local and regional environ- ment. The city of Cerro de Pasco is located close to a large open-pit mine and in recent years, several reports have pro- vided evidence of environmental contamination and related health problems. The aim of this paper is to evaluate the contamination in fluvial water, sediments and biological fluids from this area. The collective results show elevated metal and metalloid concentrations in rivers and sediments, especially in the areas downstream of the mine. For instance,…

Idrocarburi policiclici aromatici nelle croste nere presenti in edifici di zone fortemente antropizzate: aspetti analitici e sanitari

Comparison of different methods for extraction of polycyclic aromatic hydrocarbons (PAHs) from Sicilian (Italy) coastal area sediments.

This paper describes a work aimed at improving the conditions of an extraction method, coupling GC-MS determination, for the analysis without cleanup phase, of polycyclic aromatic hydrocarbons (PAHs) from sediment samples. The automatic Soxhlet extraction in warm mode (using Extraction System B-811 Standard, Buchi) has demonstrated advantages for automation, reduced extraction time, and lower solvent use than for conventional Soxhlet extraction. Under these conditions, the recoveries are very good as they resulted greater than 85 % and, in most of the cases, near 100 %. The repeatability is also satisfactory (relative standard deviation less than 15 %). The detection limits are also accepta…

Analisi di vernici utilizzate nella liuteria storica

Speciation of organotin compounds in NaCl aqueous solution: interaction of mono-, di- and tri-organotin(IV) cations with nucleotide 5′ monophosphates

Formation constants for complex species of mono-, di- and tri-alkyltin(IV) cations with some nucleotide 5'-monophosphates (AMP, UMP, IMP and GMP) are reported, at T=25°C and at I = 0.16 mol 1 -1 (NaCI). The investigation was performed in the light of speciation of organometallic compounds in natural fluids in the presence of nucleotides whose biological importance is well recognized. The simple and mixed hydrolytic complex species formed in all the systems investigated in the pH range 3-9 are (L = nucleotide; M = organotin cation R x Sn (4-x)+ , with x = 1 to 3): ML + , ML(OH)° and ML(OH) 2 - for the system CH 3 Sn 3+ -L (L = AMP, IMP, UMP); ML 0 and ML(OH)-for the system (C 2 H 5 ) 2 Sn 2+…

Synthesis, structural characterisation and biological studies of new mononuclear platinum(II) complexes with sterically hindered heterocyclic ligands

Abstract Three novel cisplatin analogues were synthesized, designed according to an approach which violates the “classical” structure–activity relationship, by replacing the diamine ligands with a planar N donor heterocycle giving a sterically hindered complex. Moreover, the sterical hindrance of antitumor drug candidates potentially makes them less susceptible to deactivation by sulphur-containing proteins and helping to overcome resistance mechanisms. The resulting mononuclear complexes of sterically hindered polidentate heterocyclic N ligands [PtCl(bbp)]Cl ( 1 ) [bbp = 2,6-bis(2-benzimidazolyl)pyridine], [PtCl 2 (dptdn)](H 2 O) ( 2 ) [dptdn = sodium 5,6-diphenyl-3-(2′-pyridyl)-1,2,4-tria…

XRF characterization of pigments in a votive shrine of popular interest in Cefalù (Italy),

PAHs and Humic acids

Polycyclic aromatic hydrocarbons (PAHs) in coffee brew samples: analytical method by GC-MS, profile, levels and sources.

Roasting is a crucial step for the production of coffee, as it enables the development of color, aroma, and flavor, which are essential for the characterization of the coffee quality. At the same time, roasting may lead to the formation of not desirable compounds, such as polycyclic aromatic hydrocarbons (PAHs). In this paper, we report a method for PAHs determination in coffee brew, based on saponification and liquid-liquid extraction with small volumes of hexane, with exclusion of further processes of purification since we analyze the extract by gas chromatography with mass spectrometric detectors in the single ion monitoring mode (SIM). The total concentration of the 28 compounds investi…

Neutral solar photo-Fenton degradation of 4-nitrophenol on iron-enriched hybrid montmorillonite-alginate beads (Fe-MABs)

Hybrid montmorillonite-alginate beads (MABs) were prepared by the ion-gelation method from alginate and montmorillonite clay suspension dropped in a calcium chloride solution. Similarly, iron-enriched beads (Fe-MABs) were prepared using iron-exchanged montmorillonite. All beads were characterized by atomic absorption and Fourier-transform infrared spectroscopy. The efficiency of Fe-MABs as catalysts for the solar photo-Fenton performed at initial pH = 7.0 was evaluated by varying the catalyst amount and hydrogen peroxide concentration, and monitoring the removal of 4-nitrophenol (4-NP) at initial concentration of 10 ppm. A kinetic analysis showed that the removal of 4-NP by Fe-MABs followed…

Assessment of the quality of the air in the isle of Ustica through chemical analyses on Pinus needles

Phthalate esters (PEAs) and Polycyclic Aromatic Hydrocarbons (PAHs) in indoor dust matter of Palermo (Italy) area. Extraction, GC-MS analysis

Studies on indoor pollution are important since people spend more than 80% of their time indoor environments. A variety of air pollutants, associated with volatile semi-volatile and particulate matter, are generated in indoor environment from human activities. Among the hazardous pollutants polycyclic aromatic hydrocarbons (PAHs) are important owing to their carcinogenicity and mutagenicity. Phthalates are introduced into the environment by anthropogenic sources. Phthalates with higher molecular weights are largely used as additives and plasticizers in plastic material (PVC), while those with lower molecular weights are components of solvents, adhesive, wax, ink, pharmaceutical products, et…

Platinum in indoor settled dust matter (homes and cars)

Abstract This paper presents a method for Pt analysis in indoor (homes and cars) settled dust, used as passive samplers, and the results relative to samples collected in the Sicilian area are used to evaluate the magnitude and distribution of concentrations inside common environments and the possible origins of the considered contaminant. The concentrations of platinum in settled indoor dust were measured by differential pulsed voltammetry (DPV). Concentrations of Pt in homes are in the range from 30 to 1460 μg kg − 1 d.w. while, in the vehicles from 30 to 1750 μg kg − 1 d.w. Considering the geoaccumulation index (I geo ), 42% of the settled dust sampled in homes could be classified as extr…

Adsorption of polyciclic aromatic hydrocarbons (PAHs) by pine barks and their use for environmental pollution monitoring in the Palermo (ITALY) area

Pelargonium leaves as bioaccumulator of polynuclear aromatic hydrocarbons: Analysis and evaluation of sources and air quality in Palermo area

The leaves of Pelargonium zonale have been chosen because this plant is widespread in both the Mediterranean metropolitan and peripheral areas. The paper describes the analytical method, and the results concerning the determination of PAHs in Pelargonium leaves collected in the Palermo area, and their possible origins. The GC-MS method was applied, since identification of all the different compounds with spectra libraries is possible. Samples were analyzed for 22 PAHs. The reported analytical method is complete within 2 hours, and more convenient than that of other researches. Total PAH concentrations in leaves varied between 24-357 g/kg d.w. The relative abundance of the analyzed PAHs can …

Speciation of vanadium in urban, industrial and volcanic soils by a modified Tessier method

Vanadium (V) concentrations in industrial, urban and volcanic soils were sequentially extracted using a modified Tessier's method. The voltammetric technique was used to determine V concentrations in solutions obtained from the various extraction steps. At the reference stations, the V concentrations (sum of four individual fractions) in soils ranged from 0.72 to 0.24 g kg(-1) dry weight (d.w.) with a mean value of 0.18 g kg(-1) d.w. V concentrations in soils of the Palermo urban area ranged from 0.34 to 2.1 g kg(-1) d.w., in the Milazzo (industrial) area between 0.26 and 5.4 g kg(-1) d.w. and in the volcanic area near Mt. Etna from 0.91 to 2.9 g kg(-1) d.w. When the V concentrations around…

Polycyclic aromatic hydrocarbons (PAHs) in sediments: Monitoring the evolution of the shore approach area of the Gulf of Gela

Polychlorinated Biphenyls in Sediments from Sicilian Coastal Area (Scoglitti) using Automated Soxhlet, GC-MS, and Principal Component Analysis

A methodology for the PAHs and PCBs congener determination in sediment samples has been revised. We determined the distributions of PAHs and PCBs in the superficial sediments of the Scoglitti (Italy) coastal area to provide data for comparison with other marine systems and to hypothesize the sources. Extraction yield, for PCB, was never less than 60% in most cases, while for PAHs, utilizing perdeuterated surrogate standard (benz[a]anthracene-d12 and anthracene-d10) was never less than 72%. The total concentration of the 16 PAHs investigated, expressed as the sum of concentrations, PAHs, varied from 1–5087 μg/kg of dry matrix, while the PCBs ranged from detection limit to 36 μg/kg of dry mat…

Fatty Acid Composition of Gluten-Free Food (Bakery Products) for Celiac People

The aim of this study (first analytical approach) was to obtain data concerning the fatty acid composition of gluten-free foods (bakery products) for celiac people. The study included 35 different products (snacks, biscuits, bakery products, pasta, flours, etc.) from several manufacturers. After extraction and esterification, the fatty acid composition was determined by Gaschromatography (GC&ndash

Potential of the polychaete Sabella spallanzanii as bioindicator for PAHs

Synthesis, properties, antitumor and antibacterial activity of new Pt(II) and Pd(II) complexes with 2,2′-dithiobis(benzothiazole) ligand

Mono- and binuclear Pt(II) and Pd(II) complexes with 2,20-dithiobis(benzothiazole) (DTBTA) ligand are reported. [Pt(DTBTA)(DMSO)Cl]Cl∙CHCl3 (1) and [Pd2(m-Cl)2(DTBTA)2]Cl2 (2) have been synthesized and structurally characterized by elemental analysis, IR, 1H and 13C NMR spectroscopy, MS spectrometry and the content of platinum and palladium was determined using a flame atomic spectrometer. Two different coordination modes of 1 and 2 complexes were found; in both complexes, the coordination of Pt(II) and Pd(II) ions involves the N(3) atoms of the ligand but the binuclear complex 2, is a cis-chloro-bridged palladium complex. Evaluation of their in vitro antitumor activity against two human tu…

Escherichia coli inactivation by neutral solar heterogeneous photo-Fenton (HPF) over hybrid iron/montmorillonite/alginate beads

Abstract Hybrid alginate montmorillonite iron enriched beads (Fe-MABs) were synthesized using ion gelation method and used as catalyst in Escherichia coli inactivation in neutral solar photo-Fenton conditions. A kinetic analysis showed that the E. coli inactivation by Fe-MABs followed a pseudo first-order kinetics model. Complete disinfection was achieved in 1 h of irradiation by using Fe-MABs in the presence of 10 ppm of H 2 O 2 . Preliminary studies on recyclability showed possible beads reused up to four times. Overall, Fe-MABs represent an environmental friendly material able to achieve bactericidal performance measured by E. coli inactivation under photooxidative conditions.

Bacterial and chemical indicator of coastal water pollution.

This study has been carried out to compare the presence of some organic compounds of long environmental persistance (OCLEP) and heavy metals, in sea water samples, with faecal pollution indicators. Along the Sicily coast line three sites with different grade of pollution (urban, agricultural, industrial) were sampled. 69 samples were obtained from October 1987 to May 1990. Only indicators of faecal pollution were found linked to human settlements, while the other investigated anthropogenic activity related substances were found independently from sampling area.

Gli acquiferi costieri del settore Bonagia-Cornino nel Trapanese: analisi dei processi di contaminazione e loro relazione con i parametri di vulnerabilità SINTACS

Platinum levels in urban soils from Palermo (Italy); Analytical method using voltammetry

Abstract A fast accumulation of platinum in the environmental and biological matrices was observed in the last years and concern arose about potential environmental and health risks. The toxicity of platinum species has been investigated in various studies, some of their, especially the chlorinated ones, are very toxic and allergenic. Information of the acute toxicity of some Pt-chlorinated salts and evidence of DNA damage due to Pt exposure have been observed both in vitro and in vivo. Taking into account what is written above, the development of reliable analytic methods to measure very low Pt concentrations is required. In this work was developed a reliable method for the determination o…

Occurrence and concentrations of PAHs in clams and sediments of marine coastal lagoons of Ganzirri (Italy). Extraction and GC-MS analysis distributions and sources

The distribution of phthalate esters in indoor dust of Palermo (Italy).

In this work, phthalic acid esters (PAEs): dimethyl phthalate (DMP), diethyl phthalate (DEP), di-n-butyl phthalate, benzyl butyl phthalate, bis(2-ethylhexyl) phthalate, and di-n-octyl phthalate in indoor dust (used as passive sampler) were investigated. The settled dust samples were collected from thirteen indoor environments from Palermo city. A fast and simple method using Soxhlet and GC–MS analysis has been optimized to identify and quantify the phthalates. Total phthalates concentrations in indoor dusts ranged from 269 to 4,831 mg/kg d.w. (d.w. = dry weight). The data show a linear correlation between total PAEs concentration and a single compound content, with the exclusion of the two …

Effect of solid waste landfill organic pollutants on groundwater in three areas of Sicily (Italy) characterized by different vulnerability

The aim of this study was to obtain information on the presence and levels of hazardous organic pollutants in groundwater located close to solid waste landfills. Eighty-two environmental contaminants, including 16 polycyclic aromatic hydrocarbons (PAHs), 20 volatile organic compounds (VOCs), 29 polychlorinated biphenyls (PCBs), 7 dioxins (polychlorinated dibenzo-p-dioxins, PCDDs) and 10 furans (polychlorinated dibenzofurans, PCDFs) were monitored in areas characterised by different geological environments surrounding three municipal solid waste landfills (Palermo, Siculiana and Ragusa) in Sicily (Italy) in three sampling campaigns. The total concentrations of the 16 PAHs were always below t…

Acid-base behaviour of fulvic acids in seawater at different salinities

Chemical characterization of ancient liturgical vestment (chasuble) by Inductively Coupled Plasma–Optical Emission Spectrometry (ICP–OES)

Abstract This paper presents the chemical characterization of the yarns of an ancient liturgical vestment (chasuble). The samples have been analyzed for Al, Ag, Au, Cd, Co, Cr, Cu, Ni, Pb and Zn using amounts always less than 1 mg by Inductively Coupled Plasma–Optical Emission Spectrometry (ICP-OES). Except a sample, silver is the most abundant element in all the yarns. In the samples containing silver, it ranged from 68 to 97%. Only two samples contain aluminum. Although the investigated chasuble is recorded in the inventory as an artifact of the XV century, a part of the yarns is composed of materials attributed to later period. In fact, the voluntary use of aluminum in metal alloys is du…

Polycyclic Aromatic Hydrocarbons in Sediments of Marine Coastal Lagoons in Messina, Italy: Extraction and GC/MS Analysis, Distribution and Sources

The content of 21 polycyclic aromatic hydrocarbons (PAHs) has been determined in 16 samples of sediments collected from Ganzirri and Faro marine coastal lagoons in Messina (Italy). Analysis was performed by gas chromatography/mass spectrometry (GC/MS) in selected ion monitoring (SIM) mode. The total concentration of polycyclic aromatic hydrocarbons (PAHs) ranged from 74 to 5755 ...g/Kg of dry matrix. The resulting distributions and molecular ratios of specific compounds have been discussed in terms of sampling location and origin of organic matter. The results obtained show that levels of contamination are not homogeneous throughout the stations, while the relative distributions of PAH are…

Volatile Profiles of Emissions from Different Activities Analyzed Using Canister Samplers and Gas Chromatography-Mass Spectrometry (GC/MS) Analysis: A Case Study

The objective of present study was to identify volatile organic compounds (VOCs) emitted from several sources (fuels, traffic, landfills, coffee roasting, a street-food laboratory, building work, indoor use of incense and candles, a dental laboratory, etc.) located in Palermo (Italy) by using canister autosamplers and gas chromatography-mass spectrometry (GC-MS) technique. In this study, 181 VOCs were monitored. In the atmosphere of Palermo city, propane, butane, isopentane, methyl pentane, hexane, benzene, toluene, meta- and para-xylene, 1,2,4 trimethyl benzene, 1,3,5 trimethyl benzene, ethylbenzene, 4 ethyl toluene and heptane were identified and quantified in all sampling sites.

Voltammetric determination of platinum in perfusate and blood: Preliminary data on pharmacokinetic study of arterial infusion with oxaliplatin

Abstract Because Platinum Group Elements have found widespread use in catalytic converters in cars and as chemotherapeutic agent, interest in the development of reliable analytical methods is carried out in order to monitor these analita in humans to protect the citizen's health. Considering that information on the levels of many trace elements in biological matrices is scarce and for many non-essential elements, baseline levels in the population, and especially in those particularly exposed to the risk are lacking, in this paper we optimize an analytical method for biological matrices, using a voltammetric technique to measure the concentration of Pt in blood and perfusate. The amount of P…

Micro-determination of dithiocarbamates in pesticide formulations using voltammetry

Abstract The purpose of this work was to develop a reliable method for the micro-determination of dithiocarbamates (mancozeb, maneb, propineb, nabam, Na(CH3)2DTC, zineb, ziram, ferbam and thiram) in pesticide formulations for agriculture using adsorptive stripping voltammetry (AdSV). The accuracy of analytical method was valued by analyzing simulate formulation samples prepared by us with known amounts of active ingredients. In addition, the applicability of the AdSV procedure for the analysis of DTCs and EBDTCs in micro-samples was evaluated by estimating its recoveries from spiked commercial formulate samples. The accuracy, valuated as recovery percentage ranged between 85% and 97%. The p…

Studies of aluminium leaching from coffeemaker during the preparation and the storage of brewed coffee. An experiment for undergraduate instrumental analysis laboratory.

Pelargonium leaves as bioindicator of polynuclear aromatic hydrocarbons (PAHs): Analytical method and evaluation of sources and air quality in Palermo (ITALY) area

Composition, distribution, and sources of polycyclic aromatic hydrocarbons in sediments of the gulf of Milazzo (Mediterranean Sea, Italy)

This article describes the characterization of Polycyclic Aromatic Hydrocarbons (PAHs) in sediments of Milazzo Gulf (Italy) located in front of an oil refinery and a power plant. The investigated area is characterized by urban and industrial activities. The sixteen PAHs identified by the USEPA, as requiring priority monitoring, and other non USEPA listed PAHs, namely perylene and some methyl derivatives, were investigated The total PAHs concentrations, expressed as ∑ 19 PAH ranges from 5.6–7402 μg/Kg d.w., with a mean value of 492 μg/Kg d.w. The concentrations of PAHs found in 64 out of 67 samples were lower than the effect range low (ERL = 2460 μg/Kg) concentration, while the remaining sam…

COMPLESSI POLINUCLEARI DI Pt(II)CON LEGANTI POLIPIRIDINICI. SINTESI, CARATTERIZZAZIONE STRUTTURALE E SPETTROSCOPICA, ATTIVITÀ CITOTOSSICA

Determination of selected polyaromatic hydrocarbons by gas chromatography–mass spectrometry for the analysis of wood to establish the cause of sinking of an old vessel (Scauri wreck) by fire

Abstract The aim of this paper was to establish the cause of sinking of an old wooden vessel by polycyclic aromatic hydrocarbon (PAH) analyses because wood combustion is a source of PAHs. In particular, the molecular PAH patterns generated by each source are like fingerprints and it is possible to determine the processes that generate PAHs by studying their distribution in wood samples. The relative abundance of high molecular weight PAHs, together with the PAH compound ratios and with total index (proposed by us) has demonstrated that samples owe their PAHs in wood archaeological material to a predominant single mode of origin, i.e. combustion processes, therefore we can say that the sinki…

Mono- and polynuclear complexes of Pt(II) with polypyridyl ligands. Synthesis, spectroscopic and structural characterization and cytotoxic activity.

Abstract An array of poly- and mononuclear complexes of Pt(II) with polypyridyl ligands is reported. The framework complexes [(PtCl 2 ) 2 (bpp) 2 (μ-PtCl 2 )](H 2 O) 2 [bpp = 2,3-bis(2-pyridyl)pyrazine], [PtCl 2 (μ-tptz)PtClNCPh]Cl [tptz = 2,4,6-tris(2-pyridyl)-1,3,5-triazine], and mononuclear PtCl 2 (NH 2 dpt) [NH 2 dpt = 4-amino-3,5-bis(2-pyridyl)-1,2,4-triazole] have been prepared and structurally characterized. Both neutral and ionic complexes are present, with bifunctional and monofunctional Pt(II) moieties, whose size and shape enable them to behave as novel scaffolds for DNA binding. Pt(II) complexes were tested for their biological activity. Cell viability assay and flow cytometric …

Profiles and Sources of PAHs in Sediments from an Open-Pit Mining Area in the Peruvian Andes

The Peruvian Andes are one of the most productive areas for mining and therefore also one of the most exposed to these sources of pollution. This article reports the characterization of Polycyclic Aromatic Hydrocarbons (PAHs) in sediments of Cerro de Pasco area (Peru) located close to a large open-pit mine and, in recent years, several reports have provided evidence of environmental contamination and related health problems. Investigations were carried out into the fifteen PAHs identified by the US-Environment Protection Agency (US-EPA) as requiring priority monitoring, other non US-EPA listed PAHs and perylene were also investigated in order to obtain further information on their origins. …

Synthetic, structural and biochemical studies of polynuclear platinum(II) complexes with heterocyclic ligands.

"Non-classical" di- and trinuclear Pt(II) complexes with polydentate nitrogen ligands; ionic [(PtCl(2))(2)(tptz)(2)(mu-PtClNCPh)]Cl (1) [tptz =2,4,6-tris(2-pyridyl)-1,3,5-triazine], [(PtCl(2))(2)(bptz)(2)(mu-Pt)]Cl(2) (2) [bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine] and neutral [(PtCl(2))(2)(tptz)(2)(mu-PtCl(2))](H(2)O)(4) (3), [(PtCl(2))(2)(mu-tppz)](CHCl(3)) (4) [tppz = 2,3,5,6-tetra(2-pyridyl)pyrazine] complexes, have been prepared and structurally characterized. The neutral tptz and tppz complexes present three and two separate PtCl(2) moieties, respectively, in a cis position, presumably acting in a bifunctional mode towards DNA; the cationic tptz and bptz complexes contain monofuncti…

The effect of montmorillonite clay in alginate gel beads for polychlorinated biphenyl adsorption: Isothermal and kinetic studies

Beads of alginate montmorillonite have been used as sorbent for polychlorinated biphenyls from aqueous solutions.The structure and the differences between the different beads were established by IR spectroscopy (FT-IR). The adsorption at 25 °C has been studied in a batch system, following its kinetics and assessing adsorbent dose, initial PCB concentrations, and pH effects. The results show that increasing the initial concentration of the PCBs and the adsorption time favored the adsorption. Adsorption isotherm data were modeled using Chapman, Freundlich and Langmuir adsorption isotherms and the appropriate parameters were calculated.Adsorption of trichlorobiphenyls on alginate–montmorilloni…

Il laboratorio di chimica

An analytical method for monitoring micro-traces of landfill leachate in groundwater using fluorescence excitation–emission matrix spectroscopy

In this study, we use three-dimensional excitation-emission matrix (EEM) fluorescence spectroscopy for the identification of contamination of natural water bodies by landfill leachate. In particular, EEM was applied to provide information about the presence and quantities of leachate in ground waters. A good linear relationship was found between the fluorescence intensity emission of groundwater spiked with landfill leachate and the volumes of the latter, suggesting that there was no intrinsic fluorescence in the concentration range of 0-1000 μL L-1. The obtained values of the LOD (10 μL L-1; TOC = 34 μg L-1) and LOQ (34 μL L-1; TOC = 114 μg L-1) allow us to detect the presence and the amou…

Polycyclic aromatic hydrocarbons (PAHs) in indoor dust matter of Palermo (Italy) area: Extraction, GC–MS analysis,distribution and sources

Abstract Studies on indoor pollution are important since people spend more than 80% of their time indoor environments. In this work the method for PAHs analysis in indoor dust (used as passive sampler) and the results relative to samples collected in the area of Palermo are reported. Dust samples for analysis were collected from 45 indoor environments. Total PAHs concentrations in indoor dusts ranged from 36 to 34 453 μg kg −1  d.w. To correlate indoor and outdoor pollution we analyze, also, the particulate matter and PAHs levels samples collected in four stations. The percentage measured in indoor dusts results more low than that found outside. The values of isomeric ratios for the differe…

Polycyclic Aromatic Hydrocarbons (PAH) in Volcano island (Aeolian archipelago) mud utilized for therapeutic purpose

This paper examines the possible presence, distribution, nature and sources of 18 Polycyclic Aromatic Hydrocarbons (PAH) as constituents of the mud pools collected in Vulcano Aeolian Island. PAH are important from environmental and toxicological point of view. Analysis was performed by gas chromatography/mass spectrometry (GC/MS) in selected ion monitoring (SIM). The total concentration of Polycyclic Aromatic Hydrocarbons ranged from 112 to 154 μ g/Kg of dry matrix. The volcanic mud, used for therapeutic purposes, are moderately contaminated.

Polycyclic aromatic hydrocarbons (PAHs) in the polychaete Sabella spallanzanii, as a reliable bioindicator, by GCMS

Every year 230.000 tons of PAHs enter the marine environment, resulting ubiquitously distributed worldwide. These compounds are aromatic molecules of special concern because of their toxic and carcinogenic properties. As a consequence of their hydrophobic nature, in aquatic environments, PAHs rapidly tend to associate with particulate matter and sediments represent the most important reservoir. In the present study the level of PAHs in the sessile filter-feeder polychaete Sabella spallanzanii was assessed. In particular, the concentration of PAHs was determined in polychaetes (body and tube) collected from three Sicilian areas, subject to different anthropic pressure. A transplanting experi…

Platinum and rhodium in potato samples by using voltammetric techniques

Potato is a starchy, tuberous crop from the perennial Solanum tuberosum having high nutritional values. This paper is the first analytical approach to quantify Pt and Rh in vegetal food. In this study a total of 38 different potato samples produced in Europe and one in Australia were investigated. Determinations of Pt and Rh in potato samples were carried out by Differential pulse voltammetry (DPV/a) for platinum and by Adsorptive stripping voltammetry (AdSV) for Rh using standard addition procedure. Because no certified reference potatoes containing platinum and rhodium are available, we used addition standard method. The quantification limits for Pt and Rh are 0.007 and 0.0008 &mu

Voltammetric Analysis of Platinum in Environmental Matrices

This article will summarize measurement data for Pt in different environmental samples obtained by the authors using a recently developed approach by voltammetric analysis. A fast accumulation of platinum and rhodium in the environmental and biological matrices has been observed in the last few years and concern has arisen about potential environmental and health risks. Voltammetry was used for the determination of Pt and Rh in airborne particulate collected in Palermo, Italy. Possible interferences by other environmental metals have also been evaluated. All samples show concentrations of Pt and Rh above average upper crust values. The Pt and Rh concentrations in particulate samples collect…

A novel thermodynamic approach for the complexation study of toxic metal cations by a landfill leachate

Landfill leachates can contaminate nearby aquifers. The hazards deriving from this contamination also depend on the chemical speciation of various contaminants. A novel approach is proposed here to face this problem from a chemical thermodynamics point of view. The complexing ability of the soluble fraction of a landfill leachate (collected from Bellolampo, Palermo, Italy) towards Pb2+, Cd2+ and Cu2+ has been investigated at T = 298.15 K in NaClaq at I = 0.1 mol dm−3. The soluble fraction of the landfill leachate was first characterized by different analytical techniques. Then, its acid–base properties were studied by ISE-H+ potentiometric titrations and modelled by the so-called diprotic-l…

A Short Review of Simple Analytical Methods for the Evaluation of PAHs and PAEs as Indoor Pollutants in House Dust Samples

Studies on indoor air quality are indispensable when considering that people spend approximately 85% of their time in confined environments. This short review mostly takes into consideration research that uses passive samplers to evaluate the quality of indoor environments (houses, school, cars, etc.). This short review summarizes most analytical methods to detect and quantify PAHs and PAEs in house dust used as a passive sampler. The objective of house dust analysis is to identify the presence, amount and distribution of specific hazardous substances in confined spaces and, if possible, to identify their sources. Household dust and the compounds present in it can enter the human body by in…

Platinum and rhodium associated with the leaves of Nerium oleander L.; analytical method using voltammetry; assessment of air quality in the Palermo (Italy) area

Abstract A rapid accumulation of the catalytic active noble metals in the environmental and biological matrices was observed and concern arose about potential environmental and health risks. The development of reliable analytic methods to measure very low Pt and Rh concentrations is required. The main purpose of this work was to develop a reliable method for the determination of Pt and Rh in environmental matrices because of inherent difficulties in using conventional techniques used, in particular, the ICP-OES technique. A direct determination of Pt using ICP-MS, for instance, is problematic, due to interfering signals. In this work, differential pulse voltammetry (DPV/a) and adsorptive st…

Pollutants in indoor environments

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