0000000000208049
AUTHOR
C. M. Sotomayor Torres
Nanoimprint lithography for organic electronics
Thin films made of organic semiconductors (α-sexithiophene, PDAS and PBAS) have been printed and the impact on morphology studied by optical, atomic force and electron microscopy. Surfaces in contact with the stamp during printing undergo a change towards smoother and more ordered material at the macromolecular scale. Interdigitated nanoelectrodes to be used as source and drain in TFTs have been made and printed down to 100 nm. PDAS and PBAS can be printed at room temperature and preserve their printed feature provided they are cross-linked afterwards.
Directionality of light emission in three-dimensional opal-based photonic crystals (Invited Paper)
Experimental and theoretical studies of the emission directionality diagrams of a perylene dye covering the inner surface of three-dimensional opal-based photonic crystals with incomplete photonic bandgap are reported. Directionality diagram of emission intensity is interpreted in terms of the spontaneous emission suppression by photonic band gap and the emission enhancement due to photon focusing phenomenon. A theoretical model is based on the classical analysis of an angular distribution of the radiated power of a point dipole.
Light scattering in opal heterojunctions
Light propagation in photonic hetero-crystals, consisting of two opal films with different lattice constants, has been investigated in the realistic regime of weak scattering, when the main light flux is transported by ballistic photons. The light scattering at the photonic bandgap interface is studied in combination with transmission data. The spectra and directionality diagrams of scattered light of single- and hetero-opal films are compared. The rate of decrease of the scattering intensity as a function of the scattering angle has been used to quantify the scattering strength. The anisotropy of the interface scattering is identified by deducing the trajectories of single scattered photon…
Exploring integration prospects of opal-based photonic crystals
Different methods of functionalisation of thin opal films are discussed, including synthesis of opals on pre-patterned substrates, post-synthesis electron beam lithography, preparation of opals with heterogeneous photonic band gap structure and integrating opals with light sources. These approaches have been tested experimentally and key technological problems have been identified.
Micromoulding of three-dimensional photonic crystals on silicon substrates
International audience; The growth of three-dimensional photonic crystals (PhCs) on patterned silicon substrates is reported. It is shown that deep trenches can be uniformly filled by a self-assembly of polymer microspheres, in a close-packed face-centred cubic lattice. The crystalline quality is compared for different channel widths. These observations are confirmed by optical reflectance measurements in the visible range, showing a bandwidth of enhanced reflection. The possibility to detach the PhC, i.e. to use the substrate as a mould, is also demonstrated. The potential of this approach for building PhC-based complex architectures is discussed.
Light Propagation in Heterogeneous Opal-Based Photonic Crystals
Ballistic light propagation in the heterogeneous photonic crystals based on the thin triple-film opal have been studied in the wavelength range of low order photonic bandgaps. Since the scattered light experiences the diffraction attenuation, the spectra and the angle diagrams of the transmitted and forward scattered light have been used to identify the effect of heterostructuring.
Towards Plastic Electronics: Patterning Semiconducting Polymers by Nanoimprint Lithography
The direct patterning of functional semiconducting polymers (see Figure) has been achieved with a nanoimprint lithography technique. The room‐temperature process described is time‐saving as repeated temperature cycling is not required. In addition, due to the direct patterning approach the need for further processing steps (plasma treatment) to pattern the underlying semiconducting material is eliminated.
Transmission anisotropy in triple-film opal photonic crystals
Summary form only given: For photonic crystals (PhCs) to have successful impact on advancement of optical circuits and realisation of various functionalities, the incorporation of artificial defects into 3D PhCs is necessary. Opal films represent a convenient approach to the realisation of 3D PhCs. Taking into account the limited flexibility of the self-assembly, the first steps can be studies of planar defects in opals and hetero-opals. Characterisation of heteroPhCs should include the investigation of the dispersion of photonic bandgaps (PBG). While the dispersion of low-order PBGs in opal films is well known, the high order PBGs were hardly studied so far owing to high requirements to th…
2D photonic defect layers in 3D inverted opals on Si platforms
Dielectric spheres synthesised for the fabrication of self-organized photonic crystals such as opals offer large opportunities for the design of novel nanophotonic devices. In this paper, we show a hexagonal superlattice monolayer of dielectric spheres inscribed on a 3D colloidal photonic crystal by e-beam lithography. The crystal is produced by a variation of the vertical drawing deposition method assisted by an acoustic field. The structures were chosen after simulations showed that a hexagonal super-lattice monolayer in air exhibits an even photonic band gap below the light cone if the refractive index of the spheres is higher than 1.93.
Photonic crystals based on two-layer opaline heterostructures
AbstractOptical properties of several heterostructures representing two-layer opaline photonic crystals have been examined. Two separate stop-bands have been observed both in transmission and emission spectra. The effect of the interface disorder on the optical spectra was not observed, probably, due to the insufficient degree of order of the opaline layers.
Enhanced thermoelectric properties of lightly Nb doped SrTiO3 thin films
Novel thermoelectric materials developed for operation at room temperature must have similar or better performance along with being as ecofriendly as those commercially used, e.g., BiTe, in terms of their toxicity and cost. In this work, we present an in-depth study of the thermoelectric properties of epitaxial Nb-doped strontium titanate (SrTiNbO) thin films as a function of (i) doping concentration, (ii) film thickness and (iii) substrate type. The excellent crystal quality was confirmed by high resolution transmission electron microscopy and X-ray diffraction analysis. The thermoelectric properties were measured by the three-omega method (thermal conductivity) and van der Pauw method (el…
Characterization of opal photonic hetero-crystals by light scattering
Spectra of the light scattered in the heterogeneous photonic crystal based on the thin triple-film opal, which was prepared by successive, convective force-assisted crystallisation of colloidal suspensions containing spheres of 374, 474 and again 374 nm in diameter, have been studied in the wavelength range of low order photonic bandgaps. If the ballistic regime of light propagation is preserved, the forward scattered light becomes the subject of the diffraction attenuation, whereas the backscattered light experiences both the diffraction enhancement and attenuation. A variety of possible configurations of scattered light measurements have been examined and corresponding spectra of scattere…
Light transport in hetero-opal photonic crystals
The effect of photonic bandgap interface upon the light scattering was studied in hetero-opals consisting of two opal thin films with different lattice constant. It is shown that the weak scattering regime is preserved in thin hetero-opal films. By comparing scattering spectra of single and hetero-opal films recorded under reversing angles of light incidence and detection it was demonstrated that the interface scatters stronger the light at oblique incident angles. Squeezing of the scattering diagram of hetero-opals compared to single opal films is also assigned to the interface scattering.
Towards Si-based photonic circuits: Integrating photonic crystals in silicon-on-insulator platforms
In the context of Si-based photonics, we report on a strategy to integrate two optical components, a 3D photonic crystal light emitter and a waveguide, in a silicon-on-insulator patterned substrate. Self-assembled colloidal photonic crystals are produced with high crystalline quality and spatial selectivity. Plane wave expansion and finite-difference time-domain have been used to find suitable configurations for positioning emitters and waveguides. The first steps toward the realisation of these configurations are presented.
Light propagation in triple-film hetero-opals
Spectra of transmitted and forward scattered light of single opal films and triple-film hetero-opals have been compared. The presence of an intermediate film in hetero-opal results in an anomalous increase of the scattered light intensity and in the change of the mainly ballistic light propagation regime to the mainly diffusive one in the frequency range of the photonic bandgap defect state.