COMPARISON BETWEEN Mg IIkAND Ca II H IMAGES RECORDED BY SUNRISE/SuFI

We present a comparison of high-resolution images of the solar surface taken in the Mg II k and Ca II H channels of the Filter Imager on the balloon-borne solar observatory SUNRISE. The Mg and Ca lines are sampled with 0.48 nm and 0.11 nm wide filters, respectively. The two channels show remarkable qualitative and quantitative similarities in the quiet Sun, in an active region plage and during a small flare. However, the Mg filtergrams display 1.4-1.7 times higher intensity contrast and appear more smeared and smoothed in the quiet Sun. In addition, the fibrils in a plage are wider. Although the exposure time is 100 times longer for Mg images, the evidence suggests that these differences ca…

FULLY RESOLVED QUIET-SUN MAGNETIC FLUX TUBE OBSERVED WITH THE SUNRISE/IMAX INSTRUMENT

Until today, the small size of magnetic elements in quiet Sun areas has required the application of indirect methods, such as the line-ratio technique or multi-component inversions, to infer their physical properties. A consistent match to the observed Stokes profiles could only be obtained by introducing a magnetic filling factor that specifies the fraction of the observed pixel filled with magnetic field. Here, we investigate the properties of a small magnetic patch in the quiet Sun observed with the IMaX magnetograph on board the balloon-borne telescope Sunrise with unprecedented spatial resolution and low instrumental stray light. We apply an inversion technique based on the numerical s…

Photospheric response to an ellerman bomb-like event—an analogy of Sunrise/IMaX observations and MHD simulations

S. Danilovic et. al.

Light availability and land‐use history drive biodiversity and functional changes in forest herb layer communities

International audience; A central challenge of today's ecological research is predicting how ecosystems will develop under future global change. Accurate predictions are complicated by (a) simultaneous effects of different drivers, such as climate change, nitrogen deposition and management changes; and (b) legacy effects from previous land use. We tested whether herb layer biodiversity (i.e. richness, Shannon diversity and evenness) and functional (i.e. herb cover, specific leaf area [SLA] and plant height) responses to environmental change drivers depended on land-use history. We used resurvey data from 192 plots across nineteen European temperate forest regions, with large spatial variabi…

Power spectrum of turbulent convection in the solar photosphere

The solar photosphere provides us with a laboratory for understanding turbulence in a layer where the fundamental processes of transport vary rapidly and a strongly superadiabatic region lies very closely to a subadiabatic layer. Our tools for probing the turbulence are high-resolution spectropolarimetric observations such as have recently been obtained with the two balloon-borne SUNRISE missions, and numerical simulations. Our aim is to study photospheric turbulence with the help of Fourier power spectra that we compute from observations and simulations. We also attempt to explain some properties of the photospheric overshooting flow with the help of its governing equations and simulations…

Combinatorial solid-phase synthesis using D-galactose as a chiral five-dimension-deversity scaffold

Abstract All five hydroxy groups of galactose as the scaffold are used for selective coupling of side chains in a combinatorial methodology by application of a set of orthogonally stable protecting groups in combination with a thioglycoside anchor.

The polarimetric and helioseismic imager on solar orbiter

This paper describes the Polarimetric and Helioseismic Imager on the Solar Orbiter mission (SO/PHI), the first magnetograph and helioseismology instrument to observe the Sun from outside the Sun-Earth line. It is the key instrument meant to address the top-level science question: How does the solar dynamo work and drive connections between the Sun and the heliosphere? SO/PHI will also play an important role in answering the other top-level science questions of Solar Orbiter, as well as hosting the potential of a rich return in further science. SO/PHI measures the Zeeman effect and the Doppler shift in the FeI 617.3nm spectral line. To this end, the instrument carries out narrow-band imaging…

Multiple Sialyl Lewisx N-Glycopeptides: Effective Ligands for E-Selectin

d-Glucose as a multivalent chiral scaffold for combinatorial chemistry

Due to their high density of functional groups and their availability in a variety of diastereomeric forms, monosaccharides are considered attractive scaffolds for combinatorial chemistry that allow the attachment and defined spatial alignment of up to five different pharmacophoric groups. For their application in combinatorial syntheses on solid phase, a set of selectively removable hydroxy protecting groups in combination with a cleavable anchor is required. Herein, we report on the construction and use of a versatile multivalent glucose building block for parallel synthesis on the solid phase.

Oscillations on Width and Intensity of Slender Ca ii H Fibrils from Sunrise/SuFI

R. Gafeira et. al.

Supersonic Magnetic Upflows in Granular Cells Observed with Sunrise/IMaX

Using the IMaX instrument on-board the Sunrise stratospheric balloon-telescope we have detected extremely shifted polarization signals around the Fe I 5250.217 {\AA} spectral line within granules in the solar photosphere. We interpret the velocities associated with these events as corresponding to supersonic and magnetic upflows. In addition, they are also related to the appearance of opposite polarities and highly inclined magnetic fields. This suggests that they are produced by the reconnection of emerging magnetic loops through granular upflows. The events occupy an average area of 0.046 arcsec$^2$ and last for about 80 seconds, with larger events having longer lifetimes. These supersoni…

Oligosaccharide recognition by selectins: Synthesis and biological activity of multivalent sialyl lewis-X ligands

Abstract Trivalent sialyl Lewis-X ligands 6–8 anchored onto flexible templates have been synthesized and evaluated as inhibitors of E-selectin and P-selectin mediated cell adhesion in cell culture assays and in vivo. Biological activities in vitro correlated with spacer length and lead to ligands with 3-fold (E-selectin) and 5-fold (P-selectin) improved receptor binding avidity per single tetrasaccharide moiety.

Transverse component of the magnetic field in the solar photosphere observed by Sunrise

We present the first observations of the transverse component of photospheric magnetic field acquired by the imaging magnetograph Sunrise/IMaX. Using an automated detection method, we obtain statistical properties of 4536 features with significant linear polarization signal. Their rate of occurrence is 1-2 orders of magnitude larger than values reported by previous studies. We show that these features have no characteristic size or lifetime. They appear preferentially at granule boundaries with most of them being caught in downflow lanes at some point in their evolution. Only a small percentage are entirely and constantly embedded in upflows (16%) or downflows (8%).

Failure on voxilaprevir, velpatasvir, sofosbuvir and efficacy of rescue therapy

Background & Aims There are limited data on patients with chronic HCV infection in whom combination voxilaprevir (VOX), velpatasvir (VEL), sofosbuvir (SOF) retreatment fails. Thus, we aimed to assess treatment failure and rescue treatment options in these patients. Methods Samples from 40 patients with HCV genotypes (GT) 1-4 in whom VOX/VEL/SOF retreatment failed were collected within the European Resistance Study Group. Population-based resistance analyses were conducted and clinical parameters and retreatment efficacies were evaluated retrospectively in 22 patients. Results Most VOX/VEL/SOF failure patients were infected with HCV GT3a (n = 18, 45%) or GT1a (n = 11, 28%) and had cirrhosis …

Magnetic field emergence in mesogranular-sized exploding granules observed with SUNRISE/IMaX data

We report on magnetic field emergences covering significant areas of exploding granules. The balloon-borne mission SUNRISE provided high spatial and temporal resolution images of the solar photosphere. Continuum images, longitudinal and transverse magnetic field maps and Dopplergrams obtained by IMaX onboard SUNRISE are analyzed by Local Correlation Traking (LCT), divergence calculation and time slices, Stokes inversions and numerical simulations are also employed. We characterize two mesogranular-scale exploding granules where $\sim$ 10$^{18}$ Mx of magnetic flux emerges. The emergence of weak unipolar longitudinal fields ($\sim$100 G) start with a single visible magnetic polarity, occupyi…

Obeticholic acid for the treatment of non-alcoholic steatohepatitis: interim analysis from a multicentre, randomised, placebo-controlled phase 3 trial.

© 2019 Elsevier Ltd. All rights reserved.

The Second Flight of the Sunrise Balloon-borne Solar Observatory: Overview of Instrument Updates, the Flight, the Data, and First Results

S. K. Solanki et. al.

D-Glucose as a Pentavalent Chiral Scaffold

A novel carbohydrate-based scaffold for combinatorial chemistry has been developed. This scaffold allows the selective attachment of five different side chains, giving rise to products of enormous structural diversity. As a demonstration of its usefulness, a series of model compounds has been prepared in high purity and yield by multistep parallel synthesis on a solid phase. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

Transverse Oscillations in Slender Ca II H Fibrils Observed with Sunrise/SuFI

S. Jafarzadeh et. al.

Investigation on the Adsorption of N2 Ar, CO and CH4 on Aluminophosphates

Abstract Adsorption isotherms at different temperatures and isothermal micro-calorimetric curves were measured for N2 Ar, CO, and CH4 on various molecular sieves as VPI-5, MCM-9, AlPO4-8, AlPO4-H, AlPO4-5, SAPO-5, AlPO4-39, AlPO4-C. It was shown that the isosteric heats of adsorption correlated with the pore-sizes of the studied molecular sieves.

Solar Coronal Loops Associated with Small-scale Mixed Polarity Surface Magnetic Fields

L. P. Chitta et. al.

Aspects of the characterization of cloverite by solid-state n.m.r. techniques

Abstract Microporous gallophosphate cloverite has been studied by multinuclear ( 13 C, 19 F, 31 P, 71 Ga) solid-state n.m.r. spectroscopy. An extraordinarily strong quadrupolar coupling is shown to be the reason for a misleading line shape in 71 Ga MAS n.m.r. spectra. Using static 71 Ga n.m.r. spectroscopy, an estimate of the size of this quadrupolar coupling can be obtained. The limitations of the MAS technique for the study of quadrupolar nuclei in sites with very large quadrupolar couplings are addressed.

Slender Ca II H fibrils mapping magnetic fields in the low solar chromosphere

S. Jafarzadeh et. al.

SUNRISE/IMaX observations of convectively driven vortex flows in the Sun

We characterize the observational properties of the convectively driven vortex flows recently discovered on the quiet Sun, using magnetograms, Dopplergrams and images obtained with the 1-m balloon-borne Sunrise telescope. By visual inspection of time series, we find some 3.1e-3 vortices/(Mm^2 min), which is a factor of 1.7 larger than previous estimates. The mean duration of the individual events turns out to be 7.9 min, with a standard deviation of 3.2 min. In addition, we find several events appearing at the same locations along the duration of the time series (31.6 min). Such recurrent vortices show up in the proper motion flow field map averaged over the time series. The typical vertica…

The synthesis of zeolites from dry powders

Summary ZSM-5 was synthesized by different methods with a gradually decreasing water content ending in a reaction mixture with absolutely dry reagents in form of a powder in the complete absence of a solution phase. Amorphous precursors obtained by drying SiO 2 * Al 2 O 3 gels at 650°C were transformed into zeolites in the presence of dried NH 4 F and TPABr. The reaction products were characterized by XRD, REM, TG/DTA, MAS NMR and Electron Micropobe. Pure ZSM-5 or Silicalite-1 was obtained in all cases. Some water is probably formed as a reaction product, but the maximum water pressure is appreciably below the saturation pressure at the given reaction conditions. To explain the formation of…

Kinematics of Magnetic Bright Features in the Solar Photosphere

S. Jafarzadeh et. al.

Synthesis and biological activity of novel sialyl-lewisX conjugates

Abstract Novel sialyl Lewis X conjugates have been synthesized and evaluated as inhibitors of E- and P-selectin mediated cell adhesion in cell culture assays. The most potent conjugate in the static inhibition assays exhibited a significant and dose-dependent pharmacological potency as inhibitor of the edotoxin-induced leukocyte adhesion to the endothelium of postcapillary venules in rats.

Evaluating structural and compositional canopy characteristics to predict the light-demand signature of the forest understorey in mixed, semi-natural temperate forests

Questions: Light availability at the forest floor affects many forest ecosystem processes, and is often quantified indirectly through easy-to-measure stand characteristics. We investigated how three such characteristics, basal area, canopy cover and canopy closure, were related to each other in structurally complex mixed forests. We also asked how well they can predict the light-demand signature of the forest understorey (estimated as the mean Ellenberg indicator value for light [“EIVLIGHT”] and the proportion of “forest specialists” [“%FS”] within the plots). Furthermore, we asked whether accounting for the shade-casting ability of individual canopy species could improve predictions of EIV…

CCDC 813647: Experimental Crystal Structure Determination

Related Article: Till Opatz, Christopher Kallus, Tobias Wunberg, Wolfgang Schmidt, Stefan Henke, Horst Kunz|2002|Carbohydr.Res.|337|2089|doi:10.1016/S0008-6215(02)00301-4